Article
Chemistry, Multidisciplinary
Katarzyna Kolodziejak, Jaroslaw Sar, Konrad Wysmulek, Krzysztof Orlinski, Piotr Piotrowski, Michal Gajewski, Dorota Anna Pawlak
Summary: The idea of using sunlight for various chemical reactions or generating electrical current is extensively researched. This study presents a method for testing the stability of photoanodes using a SrTiO3-TiO2 composite as an example. The results show that the photocurrent density increased almost four times after stability cycles, although the surface roughness of the photoanode increased and the reflectance decreased.
Article
Engineering, Environmental
Yichun Lou, Dong Qiu, Shengpeng Chen, Haoyu Chen, Linrui Wang, Zixiang Hao, Chengli He, Yang Chen, Xiaoli Cui
Summary: In this study, a Bi2MoO6/TiO2 heterojunction was constructed to broaden light absorption and accelerate oxidation kinetics, leading to highly effective water splitting. The Bi2MoO6/TiO2 heterojunction exhibited significantly higher photocurrent density and better electron transfer properties compared to pristine TiO2, promoting the separation of electron-hole pairs. This work provides a novel strategy for TiO2-based heterojunction with great potential for photoelectrochemical water splitting applications.
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
(2023)
Article
Chemistry, Multidisciplinary
Piangjai Peerakiatkhajohn, Jung-Ho Yun, Teera Butburee, Waraporn Nisspa, Supphasin Thaweesak
Summary: A silver/titanium dioxide nanoplate photoelectrode was fabricated by decorating vertically aligned titanium dioxide nanoplates with silver nanoparticles. The optimal deposition time of silver nanoparticles significantly enhanced the photoelectrochemical water splitting performance, resulting in a remarkably high photocurrent density compared to pristine titanium dioxide nanoplates.
Article
Chemistry, Physical
Qinghua Yi, Shan Cong, Hao Wang, Xinjie Zhou, Jianmei Chen, Ke Li, Yushen Liu, Jong-Min Lee
Summary: A composite catalyst of NiTiO3-coated TiO2 nanorod arrays was reported to enhance photoelectrochemical performance by enlarging absorption range and enhancing electron-hole separation efficiency. This heterostructure engineering strategy demonstrated significant improvement in photocurrent density when used as an electrode in photoelectrochemical water splitting, showing potential for optimizing various semiconductor photocatalysts.
ACS APPLIED ENERGY MATERIALS
(2021)
Article
Chemistry, Physical
Xin Sun, Min Wang, Qi Geng, Shuailin Chen, Xiaojun Lv, Xunlei Ding, Meicheng Li
Summary: This study demonstrates the use of aluminum ferrite (AFO) as a stable solar absorber in photoelectrochemical cells, showcasing its attractive performance. AFO thin-film photoelectrodes composed of vertically oriented nanosheets exhibit a photocurrent density of +0.78 mA.cm(-2) at 1.23 V vs. RHE, with a U-onset close to the flat band potential of 0.5 V vs. RHE in the presence of hole scavengers. AFO also exhibits rare coincidence between U-onset and flat band potential for solar water splitting, along with other favorable optoelectronic properties and carrier lifetimes, suggesting its great potential for photoelectrochemical cell applications.
Article
Chemistry, Multidisciplinary
Yanfei Li, Ruikang Zhang, Jianming Li, Jingchao Liu, Yucong Miao, Jian Guo, Mingfei Shao
Summary: A ternary photoanode TiO2/CuPc/NiFe-LDH is reported in this study, which shows enhanced light absorption and water oxidation efficiency. The synergistic effect of CuPc and NiFe-LDH significantly improves the photocurrent density and stability of the photoanode.
CHINESE CHEMICAL LETTERS
(2021)
Article
Chemistry, Multidisciplinary
Lei Ran, Shi Qiu, Panlong Zhai, Zhuwei Li, Junfeng Gao, Xiaomeng Zhang, Bo Zhang, Chen Wang, Licheng Sun, Jungang Hou
Summary: By utilizing a three-dimensional ordered macroporous inverse opal array and an ultrathin carbon-nitride-based layer intercalated technology, significant improvements were achieved in the performance of photoelectrochemical water splitting. The conformal heterojunction photoanode exhibited high current density and incident photon-to-current efficiency under simulated sunlight illumination, showcasing a promising approach for sustainable energy conversion systems.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2021)
Article
Chemistry, Physical
Shrinath Dattatray Ghadge, Moni K. Datta, Oleg Velikokhatnyi, Prashant N. Kumta
Summary: This study presents a simple and effective Mo doping approach for generating high-performance photoanodes for PEC water splitting. Mo doping can enhance light absorption ability, reduce band gap, increase carrier density and photocurrent density, while also decreasing charge transfer resistance and improving PEC stability.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2022)
Article
Chemistry, Physical
Dan Yin, Xingming Ning, Qi Zhang, Peiyao Du, Xiaoquan Lu
Summary: Researchers successfully constructed an integrated photoanode by modifying BiVO4 with In2O3 layer and further decorating amorphous FeNi hydroxides, improving its performance significantly. The BV/In/FeNi photoanode showed a remarkable increase in photocurrent density and water oxidation reaction kinetics. This improvement was attributed to the formation of BV/In heterojunction inhibiting charge recombination and the decoration of FeNi facilitating the water oxidation reaction kinetics and hole transfer.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2023)
Article
Chemistry, Multidisciplinary
Lina Wang, Zejun Liu, Jinming Zhang, Yuefa Jia, Jingwei Huang, Qiong Mei, Qizhao Wang
Summary: Water splitting by photoelectrochemical (PEC) processes using semiconductors is considered an ideal method for converting solar energy into hydrogen energy. Co-based metal-organic framework (CoMOF) nanosheets were deposited on the surface of BiVO4 films through hydrothermal method (Co-MOF/BiVO4). The Co-MOF/BiVO4 electrode exhibited a 4-fold higher photocurrent than bare BiVO4, with a charge separation efficiency of 96%.
CHINESE CHEMICAL LETTERS
(2023)
Article
Chemistry, Multidisciplinary
Jin Zhang, Jie Zhang, Changxue Dong, Yu Xia, Lan Jiang, Gang Wang, Ruilin Wang, Jinwei Chen
Summary: A general method is developed for synthesizing highly homogeneous and dense polymerized carbon nitride (PCN) nanosheet films directly on F: SnO2 (FTO). Detailed photoelectrochemical (PEC) water-splitting studies demonstrate that the as-synthesized PCN films exhibit outstanding performance as photoanodes for PEC water-splitting. The optimal PCN photoanode shows excellent photocurrent density, monochromatic incident photon-to-electron conversion efficiency (IPCE) values, and hole extraction efficiency, making it a new benchmark for PCN photoanode materials.
Article
Materials Science, Ceramics
Hemalatha Parangusan, Jolly Bhadra, Zubair Ahmad, K. Karuppasamy, Shoaib Mallick, Farid Touati, Noora Al-Thani
Summary: In this study, a new hierarchical hetero nanostructured electrode BaTiO3/NiFe2O4 composite was designed and prepared by a facile hydrothermal process. The composite showed excellent photocatalytic activity and enhanced absorption in the visible region, making it a promising electrode for efficient oxygen evolution reaction.
CERAMICS INTERNATIONAL
(2022)
Article
Chemistry, Physical
Minmin Han, Zhengyang Zhang, Bo Li, Xun Hu, Zhonghao Wang
Summary: Constructing heterostructures, such as the intercrossed heterostructure of Bi2S3 nanosheets on hydrogen-treated TiO2 nanorods, plays a critical role in improving the photoelectrochemical performance. Hydrogen treatment enhances charge separation and narrow the band gap, resulting in a higher PEC performance in H-TiO2 compared to bare TiO2. The intercrossed heterostructure of Bi2S3/H-TiO2 achieves a significantly higher photocurrent density under visible light irradiation and benefits from efficient electron transfer and charge separation.
APPLIED SURFACE SCIENCE
(2022)
Article
Chemistry, Physical
Lina Wang, Jinming Zhang, Yi Li, Yanbiao Shi, Jingwei Huang, Qiong Mei, Lei Wang, Fei Ding, Bo Bai, Qizhao Wang
Summary: PEC water splitting can convert solar energy into green and storable H2. BiVO4, as a photoanode material, has superior visible light absorption but suffers from charge carrier recombination and slow interfacial water oxidation kinetics. A heterostructured CoFe1.5Cr0.5S3O/COFs/BiVO4 photoanode was fabricated to address these issues and achieved an impressive water oxidation photocurrent under AM 1.5 G irradiation.
APPLIED CATALYSIS B-ENVIRONMENTAL
(2023)
Article
Chemistry, Applied
Wen Zhang, Meng Tian, Haimiao Jiao, Hai-Ying Jiang, Junwang Tang
Summary: In this work, a highly-matched BiVO4/WO3 nanobowl photoanode was constructed and further modified to enhance its photocurrent density and photoelectrochemical performance. The photocurrent density was increased by about 5-fold compared to pristine BiVO4, achieving a faradaic efficiency of approximately 95%.
CHINESE JOURNAL OF CATALYSIS
(2022)
Article
Electrochemistry
Halimeh-Sadat Sajjadizadeh, Hossein Ahmadzadeh, Elaheh K. Goharshadi, Mohammad Aziznezhad
ELECTROCHIMICA ACTA
(2020)
Article
Multidisciplinary Sciences
Maryam Davardoostmanesh, Hossein Ahmadzadeh
Summary: The preparation of superhydrophobic rock wool for efficient clean-up of oil and organic solvents has shown excellent oil-water separation capabilities and the ability to be recycled, making it a suitable choice for large-scale applications due to its low cost and versatility.
Article
Environmental Sciences
S. Ziaei, H. Ahmadzadeh, Z. Es'haghi
Summary: This study proposes Artemia cysts as a dynamic and efficient biosorbent for the elimination of lead ion contaminants. The surface properties and adsorption performance of the cysts were evaluated using various techniques. The results showed rapid and robust biosorption of lead ions under different conditions. The maximum uptake of lead ions was achieved in a short time, and the equilibrium adsorption fitted well with Langmuir isotherm. The efficient, simple and straightforward performance of Artemia cysts in purifying contaminated water from lead ions was confirmed.
INTERNATIONAL JOURNAL OF ENVIRONMENTAL SCIENCE AND TECHNOLOGY
(2022)
Article
Chemistry, Multidisciplinary
Zainab Zahid Ahmed, Hossein Ahmadzadeh, Gholam Hossein Zohuri
Summary: In this study, the dinuclearity effect of alpha-diimine Ni-based catalysts on copolymerization of methyl methacrylate/1-hexene was investigated, and the microstructures of copolymers were characterized using FT-IR and NMR. The monomer reactivity ratio was calculated, showing high reactivity for MM and low reactivity for 1H. Thermal properties of the copolymers were studied, with higher MM content in the backbone and higher T-g values observed. The electrical conductivity of graphene-poly(MM-1H) nanocomposite was significantly enhanced compared to poly(MM-1H).
Article
Rehabilitation
Fereshteh Korehpaz-Mashhadi, Hossein Ahmadzadeh, Amir Rashidlamir, Nahid Saffari
Summary: This study examined the effect of aerobic exercise on dopamine metabolites in adolescent boys with internet addiction. The results showed that aerobic exercise could improve the disrupted dopamine system caused by internet addiction.
JOURNAL OF BODYWORK AND MOVEMENT THERAPIES
(2022)
Article
Chemistry, Physical
Mahdi Karimi-Nazarabad, Elaheh K. Goharshadi, Halimeh-Sadat Sajjadizadeh
Summary: By combining Cu-azolate framework and g-C3N4 into a core-shell nano-composite, the photoconversion efficiency of the photoanode is improved, and recombination of electrons and holes is reduced. The photoanode loaded with Ni(OH)(2) cocatalyst also facilitates water molecule splitting.
JOURNAL OF PHYSICAL CHEMISTRY C
(2022)
Article
Chemistry, Analytical
Maryam Nasiri, Hossein Ahmadzadeh, Amirhassan Amiri
Summary: An effective magnetic solid-phase extraction method utilizing magnetic graphene oxide coated with poly(2-aminoterephthalic acid-co-aniline) as a sorbent for the preconcentration and extraction of organophosphorus pesticides has been proposed. The method has a wide linear dynamic range, low limits of detection and quantification, and shows good potential and sensitivity for pesticide determination.
JOURNAL OF SEPARATION SCIENCE
(2022)
Article
Environmental Sciences
M. Nasiri, H. Ahmadzadeh, A. H. Amiri
Summary: This study investigated the potential of Dunaliella salina microalgae to remove four organophosphorus pesticides from well water. The results showed that at certain concentrations, Dunaliella salina was able to remove significant amounts of the pesticides.
INTERNATIONAL JOURNAL OF ENVIRONMENTAL SCIENCE AND TECHNOLOGY
(2023)
Article
Engineering, Chemical
Maryam Davardoostmanesh, Hossein Ahmadzadeh
Summary: The petrochemical industry generates a large amount of oily wastewater which needs effective treatment methods. Membrane filtration techniques, due to their easy operation and low energy consumption, have been receiving more attention. A dual-function membrane for the purification of saline oily wastewater was prepared using microalgae coated on steel mesh inspired by fish scales. This membrane demonstrated high efficiency for oil-water separation and water desalination, making it suitable for commercial applications.
JOURNAL OF MEMBRANE SCIENCE
(2023)
Article
Energy & Fuels
Azar Rezaei, Monireh Cheniany, Hossein Ahmadzadeh, Jamil Vaezi
Summary: Cold climate ecosystems provide opportunities for the discovery of native cold-adapted strains that can tolerate temperature fluctuations for the production of lipids. In this study, three strains (Scenedesmus sp., Ankistrodesmus sp., and Chlorella sp.) were identified from Cheshmeh-Sabz Lake in Iran. The growth parameters and lipid productivity of these strains were investigated at different temperatures. Scenedesmus sp. showed the highest biomass productivity and lipid productivity at 25 degrees C, making it a suitable choice for outdoor cultivation in different seasons.
BIOENERGY RESEARCH
(2023)
Article
Environmental Sciences
Somayyeh Ziaei, Hossein Ahmadzadeh, Zarrin Es'haghi
Summary: The main aim of this study was to model and optimize a continuous biosorption system for the removal of Pb(II) ions using live Dunaliella salina microalgae. The effects of different parameters on biosorption efficiency were investigated, and Dunaliella salina showed high efficiency in Pb(II) removal. The selectivity of Pb(II) uptake in the presence of other heavy metal ions was also examined, and the Langmuir and Freundlich isotherm models were suitable for describing the multicomponent systems.
ENVIRONMENTAL MONITORING AND ASSESSMENT
(2023)
Article
Chemistry, Multidisciplinary
Roya Mehrkhah, Kimiya Goharshadi, Elaheh K. Goharshadi, Halimeh-Sadat Sajjadizadeh
Summary: Interfacial solar steam generation (ISSG) is a green and sustainable technology for seawater desalination and wastewater purification. A photoabsorber, consisting of wood coated with Pd nanoparticles and reduced graphene oxide, achieved a high evaporation flux of 5.25 kg m(-2) h(-1) under 3 kW m(-2). The device also exhibited excellent performance in wastewater treatment, effectively removing dyes and reducing the concentration of heavy metals.
Article
Chemistry, Analytical
Sayyed Hashem Sajjadi, Hossein Ahmadzadeh, Elaheh K. Goharshadi