Journal
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
Volume 59, Issue 4, Pages 1568-1577Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.iecr.9b06023
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Funding
- National Natural Science Foundation of China [21805198, 21878195, 21805018]
- Distinguished Young Scholars of Sichuan University [2017SCU04A08]
- Huohua Ku project of Sichuan University [2018SCUH0094]
- Research Foundation for the Postdoctoral Program of Sichuan University [2017SCU12018, 2018SCU12045]
- Research Foundation for the Sichuan University
- Zigong City Joint research project [2018CDZG-16]
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As one of the promising anode candidates of sodium-ion batteries, the development of transition metal sulfides (TMSs) was severely limited by the large volume variation and sluggish kinetics during sodiation/desodiation processes. Integrated optimizations including preparation method, structure design, electrolyte, etc. are highly in demand. Herein, a general synthesis method of MxS (M = Co, Cu) hollow spheres is developed. After a combined modification of the cut-off voltages and electrolytes, the as-prepared MxS samples exhibit improved sodium-ion storage properties. A high capacity of 470 mAh g(-1) with 88% capacity retention at 100 mA g(-1) after 100 cycles is delivered by CoS. As to Cu1.765S, a reversible capacity of 317.6 mAh g(-1) with no obvious capacity decay could be found at 100 mA g(-1) after 100 cycles. The selected NaCF3SO3/diethylene glycol dimethyl ether electrolyte plays a crucial role in promoting the electrochemical property of the MxS samples. This general synthesis method and electrolyte optimization strategy is expected to be applicable to other TMS anodes.
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