Journal
EUROPEAN POLYMER JOURNAL
Volume 124, Issue -, Pages -Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.eurpolymj.2019.109457
Keywords
Quasi-block copolymers; Quaternization; DMAEMA; Thermo-induced self-assembly; Thermoresponsive polymers
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Funding
- Consejo Nacional de Ciencia y Tecnologia (CONACYT, Mexico)
- Deutscher Akademischer Austauschdienst (DAAD, Germany)
- Centro de Investigacian en Quimica Aplicada (CIQA, Mexico) [N 6529/2019]
- Center for Excellence PolyTarget of the Deutsche Forschungsgemeinschaft (DFG, Germany) [SFB 1278]
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We describe the sequential incorporation of the quaternized monomer N-(2-(Methacryloyloxy)ethyl)-N,N-dimethylheptan-l-ammonium (QDM) (from 1 up to 5 mol %) into 2-((dimethylamino)ethyl methacrylate) polymer chains (PDMAEMA), via reversible addition-fragmentation chain transfer (RAFT) technique, to yield quasi-block copolymers (PDMAEMA-qb-P(DMAEMA-co-QDM)) with modified hydrophilic nature and thermo-induced self-assembly properties in aqueous solutions. This chemical modification promotes the formation of metastable nanostructures in aqueous medium. The morphological transitions were investigated by means of atomic force microscopy (AFM), dynamic light scattering (DLS), rheology and turbidimetry. The results indicated that the obtained nanostructures were stabilized by associative and cationic interactions conveyed by the quaternized moieties within the polymer chains. The size of these nanostructures could be modified as a function of molar mass, copolymer composition and temperature. The method described denotes an interesting alternative to modify the thermo-induced self-assembly behavior of PDMAEMA based copolymers employing low amounts of quaternized moieties.
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