Journal
BIORESOURCE TECHNOLOGY
Volume 195, Issue -, Pages 31-36Publisher
ELSEVIER SCI LTD
DOI: 10.1016/j.biortech.2015.06.076
Keywords
Hydrogen peroxide; Cathode potential; Gas diffusion; Microbial electrochemical cell; Microbial fuel cell
Funding
- Nautral Sciences and Engineering Research Council of Canada (NSERC) [402045-2011]
- Ministry of Economic Development and Innovation
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Cathode potential and O-2 supply methods were investigated to improve H2O2 synthesis in an electrochemical cell, and optimal cathode conditions were applied for microbial electrochemical cells (MECs). Using aqueous O-2 for the cathode significantly improved current density, but H2O2 conversion efficiency was negligible at 0.3-12%. Current density decreased for passive O-2 diffusion to the cathode, but H2O2 conversion efficiency increased by 65%. An MEC equipped with a gas diffusion cathode was operated with acetate medium and domestic wastewater, which presented relatively high H2O2 conversion efficiency from 36% to 47%, although cathode overpotential was fluctuated. Due to different current densities, the maximum H2O2 production rate was 141 mg H2O2/L-h in the MEC fed with acetate medium, but it became low at 6 mg H2O2/L-h in the MEC fed with the wastewater. Our study clearly indicates that improving anodic current density and mitigating membrane fouling would be key parameters for large-scale H2O2-MECs. (C) 2015 Elsevier Ltd. All rights reserved.
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