Article
Chemistry, Physical
Min Jiang, Yunfeng Zhu, Yana Liu, Jiguang Zhang, Yao Zhang, Yicheng Sun, Peng Zeng, Jie Hou, Yuke Ren, Zhixin Ba, Liquan Li
Summary: Ni-Co LDHs were synthesized with different Ni/Co molar ratios and used as cathode materials for Ni-MH batteries. Compared with Ni(OH)2, Ni-Co LDHs electrodes exhibited higher discharge capacity and cycling stability. The NC 2 electrode with a Ni/Co molar ratio of 4:1 showed the highest discharge capacity and capacity retention after 200 cycles. The unique morphology and enlarged interlayer spacing of Ni-Co LDHs promoted ion transmission and charge transfer, while their structural stability and synergies with Co-Co LDHs were important for electrochemical performances.
JOURNAL OF ALLOYS AND COMPOUNDS
(2023)
Article
Chemistry, Physical
Chuhong Wang, Tim Mueller, Rajeev S. Assary
Summary: Multivalent-ion batteries have high theoretical energy density and potential to outperform Li-ion batteries. Research has discovered that in a novel Mg anode coating, BiOCl, the diffusion mechanism of Mg cations is facilitated by synchronous rotation of anions, which may enhance multivalent-ion diffusion in layered materials.
CHEMISTRY OF MATERIALS
(2022)
Article
Chemistry, Multidisciplinary
Dun Lin, Dewei Rao, Samuel Chiovoloni, Shanwen Wang, Jennifer Q. Lu, Yat Li
Summary: By utilizing a double-layered cathode structure, the undesired shuttling of triiodide ions has been successfully suppressed, resulting in outstanding Coulombic efficiency and voltage efficiency for ZIBs. These findings offer new insights for the design and fabrication of ZIBs and other batteries based on conversion reactions.
Article
Chemistry, Physical
Shiman He, Dian Zhang, Xu Zhang, Shiqi Liu, Weiqin Chu, Haijun Yu
Summary: Aluminum-ion batteries are considered as an alternative for energy storage due to their high theoretical capacity, low cost, and abundant aluminum resources. However, challenges such as slow reaction kinetics and poor cycling stability in Al-SSTs batteries still need to be addressed with various strategies.
ADVANCED ENERGY MATERIALS
(2021)
Article
Materials Science, Multidisciplinary
Huan Liu, Xu Zhang, Shiman He, Di He, Yang Shang, Haijun Yu
Summary: This review investigates the application of molten salt methodology in the synthesis of high-performance electrodes and electrolytes. The molten salt synthesis methods show unique advantages in adjusting the crystal structure and performance of electrode materials, and are expected to promote the development of rechargeable batteries.
Article
Chemistry, Physical
Sadegh Askari, Davide Mariotti, Paul Brunet, Alexander Vahl, Jan Benedikt
Summary: The hybrid Zn-air and Zn-M battery with Fe-doped Ni double hydroxide nanoflakes and activated carbon cathode material shows superior performance, high energy density, exceptional energy conversion efficiency, and outstanding power density. It also enables high-rate charging due to rapid redox reaction kinetics and excellent cathode materials catalytic activity.
MATERIALS TODAY ENERGY
(2021)
Article
Chemistry, Physical
Chuhong Wang, Tim Mueller, Rajeev S. Assary
Summary: This study investigates the diffusion mechanisms of divalent ions in a novel Mg anode coating, BiOCl, using first-principles informed learning-on-the-fly molecular dynamics. The findings suggest that the diffusion of Mg cations is facilitated by synchronous anion rotational motion. Furthermore, similar cooperative cation-anion motion is likely a common phenomenon in layered oxyhalide structures.
CHEMISTRY OF MATERIALS
(2022)
Article
Engineering, Environmental
Ting-Ting Lv, Xin Luo, Guo-Qiang Yuan, Sheng-Yang Yang, Huan Pang
Summary: A facile calcination process was used to prepare VO2 and N-doped carbon composite with more active sites, higher conductivity, and less structural change during ion diffusion, resulting in excellent electrochemical performance for rechargeable aqueous zinc-ion batteries. This work could offer a new and efficient avenue for designing cathodes with superior performance in AZIBs.
CHEMICAL ENGINEERING JOURNAL
(2022)
Article
Chemistry, Physical
Yana Liu, Juanzhe Yu, Min Jiang, Jie Hou, Yunfeng Zhu, Jiguang Zhang, Zhixin Ba, Liquan Li
Summary: A series of flower-like Ni-Fe layered double hydroxides (LDHs) were successfully synthesized and used as cathode materials for nickel-metal hydride batteries (Ni-MH batteries). The 4Ni-Fe LDH electrode displayed the highest high-rate discharge property and the most excellent cycling performance. The improvement can be attributed to the formation of LDHs, as well as their unique morphology and enlarged interlayer spacing.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2022)
Article
Chemistry, Physical
Yudong Zhang, Jiuding Liu, Wence Xu, Yong Lu, Hua Ma, Fangyi Cheng, Jun Chen
Summary: This study reports a concentration-gradient Mg and Al doped cathode material, which exhibits stability, high capacity, outstanding cyclability, and remarkable rate capability. The gradient co-doping boosts the electrochemical performance and enhances Li-ion diffusion and thermal stability.
JOURNAL OF POWER SOURCES
(2022)
Article
Chemistry, Physical
Michael Yi, Zehao Cui, Hugo Celio, Arumugam Manthiram
Summary: High-nickel layered oxides are widely used as cathode materials for high-energy density lithium-based batteries. However, their surface air instabilities hinder mass production. This study finds that the average oxidation state of nickel is the critical parameter influencing the air stability, which is greatly affected by the contents of manganese and cobalt.
CHEMISTRY OF MATERIALS
(2023)
Article
Nanoscience & Nanotechnology
Gaohong Wu, Wenrong Lv, Xiaoxiao Li, Wenming Zhang, Zhanyu Li
Summary: Rechargeable aluminum-ion batteries have garnered increasing attention due to their high theoretical energy density, safety, and affordability. However, the development of aluminum batteries has been limited by the lack of suitable cathode materials. This study successfully addressed the poor cycling stability and low specific capacity of aluminum batteries through the creation of YSNT@Se hybrids.
ACS APPLIED MATERIALS & INTERFACES
(2021)
Review
Chemistry, Physical
Kok Long Ng, Brohath Amrithraj, Gisele Azimi
Summary: This review focuses on summarizing reported cathode materials and their charge storage mechanisms in nonaqueous rechargeable Al batteries (RABs). It critically discusses the implications of overall cell chemistries on actual battery performance metrics, outlines the fundamental and practical limitations of existing RAB chemistries, and emphasizes the importance of accurately elucidating the underlying charge storage mechanism. The ion migration kinetics in existing electrodes are discussed, and design guidelines for enhancing their performance are provided.
Article
Chemistry, Multidisciplinary
Yixin Li, Luojia Liu, Yong Lu, Ruijuan Shi, Yilin Ma, Zhenhua Yan, Kai Zhang, Jun Chen
Summary: This study reports on the optimization of macrocyclic calix[4]quinone as excellent cathode materials for high-energy-density AABs, showing high capacity, rate capability, and low-temperature performance. Experimental and theoretical calculations prove that Al(OTF)(2+) cations coordinate with the carbonyl groups of C4Q during the discharge process, reducing desolvation penalty.
ADVANCED FUNCTIONAL MATERIALS
(2021)
Article
Chemistry, Multidisciplinary
Jingliang Xu, Xinhang Hu, Md Asraful Alam, Gul Muhammad, Yongkun Lv, Minghai Wang, Chenjie Zhu, Wenlong Xiong
Summary: The structural stability of alpha-MnO2 is enhanced by simultaneous Al3+ doping and lignin coating, leading to improved conductivity and increased surface area. This results in superior performance in terms of reversible capacity and cycle stability compared to the reference alpha-MnO2 cathode.
Article
Materials Science, Multidisciplinary
Hao Liu, Ruikai Yang, Wen Yang, Changjiang Bai, Yong-Chun Li, Gongke Wang, Yuxia Liu, Wei Xiang, Zhenguo Wu, Xiaodong Guo
Summary: In this study, a novel strategy was proposed to modify the Ni-rich cathode LiNi(0.8)Co(0.1)Mn(0.1)O(2) with uniform Al and Ti cations co-doping, which effectively stabilized the vulnerable structure and mitigated voltage/capacity attenuation. The modified cathode showed significantly enhanced electrochemical performance, with improved discharge capacity and voltage retention after 200 cycles, even at elevated voltages.
JOURNAL OF MATERIALS SCIENCE
(2021)
Article
Engineering, Environmental
Chunliu Xu, Wei Xiang, Zhenguo Wu, Lang Qiu, Yong Ming, Wen Yang, Luchao Yue, Jun Zhang, Benhe Zhong, Xiaodong Guo, Gongke Wang, Yuxia Liu
Summary: The dual-site doping of Zn2+ in Ni-rich cathode materials successfully enhances the cationic ordering and suppresses cationic mixing, leading to high capacity and stable cyclability in lithium-ion batteries.
CHEMICAL ENGINEERING JOURNAL
(2021)
Article
Chemistry, Applied
Daqiang Wang, Zhenguo Wu, Wei Xiang, Yuxia Liu, Gongke Wang, Kanghui Hu, Qi Xu, Yang Song, Xiaodong Guo
Summary: The introduction of spinel phase to form the layered-spinel structure has been shown to improve the electrochemical performance of Li- and Mn-rich layered oxides, with high capacity and retention achieved in low-Ni systems but reduced capacity retention in high-Ni systems. The study provides guidance for optimizing element proportions and structure design for these materials.
JOURNAL OF ENERGY CHEMISTRY
(2022)
Article
Materials Science, Multidisciplinary
Li-Min Zhu, Guo-Chun Ding, Qing Han, Yong-Xia Miao, Xin Li, Xin-Li Yang, Lei Chen, Gong-Ke Wang, Ling-Ling Xie, Xiao-Yu Cao
Summary: Salinization of tetrahydroxyquinone (THBQ) to ortho-disodium salt (o-Na(2)THBQ) improves its electrochemical properties by reducing dissolution and enhancing stability. In various electrolytes, o-Na(2)THBQ cathodes exhibit good reversible discharge capacities and stability, showing promise for application in sodium-ion and lithium-ion batteries.
Article
Chemistry, Multidisciplinary
Zhiwei Yang, Chen Wu, Shi Li, Lang Qiu, Zuguang Yang, Yanjun Zhong, Benhe Zhong, Yang Song, Gongke Wang, Yuxia Liu, Zhenguo Wu, Xiaodong Guo
Summary: Stress failure and continued growth of the solid electrolyte interface are the main factors contributing to the failure of lithium-ion batteries with silicon (Si) anode. A core-shell gradient porous structure with a high-strength core and a high-porosity shell is proposed to address these issues, improving the stability and cycling performance of Si-based anode materials.
ADVANCED FUNCTIONAL MATERIALS
(2022)
Review
Chemistry, Physical
Tao Zhou, Limin Zhu, Lingling Xie, Qing Han, Xinli Yang, Lei Chen, Gongke Wang, Xiaoyu Cao
Summary: Despite the advantages of LIBs, ZIBs are attracting attention as a promising alternative due to their low cost, high safety, and high synergistic efficiency. However, current cathode materials for ZIBs have shortcomings, necessitating the search for materials to improve battery performance.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2022)
Article
Chemistry, Physical
Lang Qiu, Yang Song, Mengke Zhang, Yihua Liu, Zhiwei Yang, Zhenguo Wu, Heng Zhang, Wei Xiang, Yuxia Liu, Gongke Wang, Yan Sun, Jun Zhang, Bin Zhang, Xiaodong Guo
Summary: This study systematically investigates the structure reconstruction induced by the migration of Li, O, and transition metal (TM) ions during high-temperature lithiation, charging, and long-term storage. By characterizing Li-free/Li-containing phases and conducting detailed analyses, the structural reconstruction induced by the interaction of Li, O, and TM ions is revealed.
ADVANCED ENERGY MATERIALS
(2022)
Article
Chemistry, Physical
Jinjun Tian, Zhenghai Shi, Gongke Wang
Summary: In this study, the binding interaction between silver nanoparticles and human serum albumin was investigated. The results showed that the interaction is driven by entropy, leading to conformational changes in the protein and a decrease in alpha-helix content. Additionally, the binding followed pseudo-second-order kinetics and fit the Freundlich model for multilayer adsorption.
Article
Energy & Fuels
Xiangjian Meng, Jiaxin Liu, Gongke Wang, Jingyang Fang
Summary: This paper proposes a three-input central capacitor dc/dc converter for high-voltage PV systems, which achieves maximum power point tracking and balanced DC voltage by cascaded buck-boost converters and energy transfer regulation, thereby improving the energy yield and efficiency of PV plants.
FRONTIERS IN ENERGY RESEARCH
(2022)
Article
Chemistry, Physical
Jiuli Chang, Wenfang Liang, Wenyu Wang, Dapeng Wu, Kai Jiang, Gongke Wang, Fang Xu, Zhiyong Gao
Summary: In this study, oxygen vacancy-enriched Bi2O3 was prepared as the negative material for aqueous alkaline batteries, improving the energy and power densities of the batteries and demonstrating the potential of oxygen vacancy-enriched Bi2O3 in battery-type energy storage.
APPLIED SURFACE SCIENCE
(2022)
Article
Biochemistry & Molecular Biology
Gongke Wang, Yumeng Chen, Shaohui Yuan, Peng Ge
Summary: This study designs hollow spheres with suitable thickness shell as hosting materials for Na-S systems, filled with active S4 molecules through vacuum tube sealing technology. The results show that this design effectively avoids the generation of intermediate products, improving the cycle life and capacity of the battery.
Article
Chemistry, Physical
Hua Lv, Yuanfang Kong, Zhiyuan Gong, JinZe Zheng, Yumin Liu, Gongke Wang
Summary: This study developed a Mn0.5Cd0.5S catalyst with dual cocatalysts, which improved the photocatalytic water splitting performance by reducing the reaction energy barrier and suppressing charge recombination. The results showed that the Mn0.5Cd0.5S/CB/CuS hierarchical multiheterojunction catalyst exhibited excellent hydrogen generation efficiency and stability under simulated solar light irradiation.
APPLIED SURFACE SCIENCE
(2022)
Article
Chemistry, Applied
Gongke Wang, Yumeng Chen, Yu Han, Lixue Yang, Wenqing Zhao, Changrui Chen, Zihao Zeng, Shuya Lei, Shaohui Yuan, Peng Ge
Summary: Na-Se batteries with Se electrodes have been studied for their high energy density and conductivity. However, their sluggish kinetic behaviors and S-electrode-like shuttling effects remain challenges. This study proposes a strategy to address these issues by loading Se material onto uniform hollow carbon spheres, resulting in optimized pore distribution, enhanced electron-moving behaviors, and activated Se electrodes. The resulting cathodes demonstrate promising capacity performance and stability, with potential implications for advanced Na-Se batteries.
JOURNAL OF ENERGY CHEMISTRY
(2023)
Article
Spectroscopy
Yonghui Xuan, Xiang Li, Changling Yan, Gongke Wang
Summary: Due to the complexity and cost of traditional methods for detecting heavy metal pollution in water, there is a need for rapid and simple methods. In this study, a nanobiosensor based on molybdenum disulphide (MoS2) nanosheets and fluorophore labeled oligonucleotides was proposed for detecting Hg2+ or Ag+ ions in water using fluorescence spectroscopy. The sensor works by forming stable double-stranded DNA (dsDNA) structures through the mismatching of single-stranded DNA (ssDNA) rich in thymine (T) or cytosine (C) with Hg2+ or Ag+. The sensor showed high sensitivity and selectivity, with minimum detection limits of 6.8 nM and 8.9 nM for Hg2+ and Ag+ ions, respectively.
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
(2023)
Article
Chemistry, Multidisciplinary
Qi Xu, Qianwen Wang, Dequan Chen, Yanjun Zhong, Zhenguo Wu, Yang Song, Gongke Wang, Yuxia Liu, Benhe Zhong, Xiaodong Guo
Summary: This study successfully prepared a Si/spent graphite composite through recycling of spent graphite, achieving uniform dispersion of Si nanoparticles in the graphite matrix and suppressing volume strain by tuning the Zeta potential. The composite electrode showed high initial discharge capacity and stable cycle life after 400 cycles. Defect-enriched spent graphite and oxygen-containing functional groups also positively influenced the electrode performance.
Article
Electrochemistry
Abdul Qayoom Mugheri, Shaista Khan, Ali Asghar Sangah, Aijaz Ahmed Bhutto, Muhammad Younis Laghari, Nadeem Ahmed Mugheri, Asif Ali Jamali, Arsalan Ahmed Mugheri, Nagji Sodho, Abdul Waheed Mastoi, Aftab Kandhro
Summary: Green hydrogen has the potential to transition to a pollution-free energy infrastructure. This study proposes a solution to produce hydrogen during the photoelectrochemical process, offering greater stability and control over chemical reactions. Techno-economic assessments show the efficiency and economic feasibility of co-producing value-added chemicals to enhance green hydrogen production.
ELECTROCHIMICA ACTA
(2024)
Article
Electrochemistry
Danpeng Cheng, Wuxin Sha, Qigao Han, Shun Tang, Jun Zhong, Jinqiao Du, Jie Tian, Yuan-Cheng Cao
Summary: LiNixCoyMn1-x-yO2 (NCM) is a critical cathode material for lithium-ion batteries in electric vehicles. The aging of cathode/electrolyte interfaces leads to capacity degradation and long-term cycle instability. A novel neural network model called ACGNet is developed to predict electrochemical stability windows of crystals, allowing for high-throughput screening of coating materials. LiPO3 is identified as a promising coating material with high oxidation voltage and low cost, which significantly improves the cycle stability of NCM batteries. This study demonstrates the accuracy and potential of machine learning in battery materials.
ELECTROCHIMICA ACTA
(2024)
Article
Electrochemistry
P. Mohana, R. Yuvakkumar, G. Ravi, S. Arunmetha
Summary: This study successfully fabricates a non-noble CuO/NiO/rGO nanocomposite and investigates its electrocatalytic performance for oxygen evolution reaction in alkaline environment. The experimental results demonstrate that the electrocatalyst exhibits high activity and good stability, offering a new synthetic approach for sustainable energy production.
ELECTROCHIMICA ACTA
(2024)
Article
Electrochemistry
Qiong Qu, Jing Guo, Hongyu Wang, Kai Zhang, Jingde Li
Summary: In this study, a bifunctional electrode host design consisting of carbon nanofibers implanted ordered porous Co-decorated Al2O3 supported on carbon nanotube film (CNTF) was proposed to address the shuttling effect of lithium polysulfides (LiPSs) and dendrite formation of metal lithium anode in lithium-sulfur (Li-S) batteries. The electrode exhibited excellent conductivity, efficient confinement of LiPSs, and catalytic conversion performance, resulting in high initial capacity and good capacity retention during cycling. As an anode, the electrode showed excellent Li+ diffusion performance and uniform lithium growth behavior, achieving a dendrite-free lithium electrode. The flexible pack cell assembled from these electrodes delivered a specific capacity of 972 mAh g(-1) with good capacity retention.
ELECTROCHIMICA ACTA
(2024)
Article
Electrochemistry
Hong Zhang, Jin-Peng Yu, Chen Chen, Cheng-Yong Shu, Guang-Yu Xu, Jie Ren, Kai Cui, Wen-Fang Cai, Yun-Hai Wang, Kun Guo
Summary: Spray coating of acetylene black nanoparticles onto stainless steel mesh can enhance its biofilm formation ability and current density, making it a promising electrode material for microbial electrochemical systems. The spray coating method is simple, cost-effective, and suitable for large-size stainless steel electrodes.
ELECTROCHIMICA ACTA
(2024)
Article
Electrochemistry
Binpeng Hou, Jingjin Chen, Li-Hong Zhang, Xiaowen Shi, Zizhong Zhu
Summary: The electrochemical performance of Li1.20Mn0.44Ni0.32Co0.04O2 and its oxygen-deficient phase Li1.20Mn0.44Ni0.32Co0.04O1.83 was studied through first-principles calculations. The results show that the oxygen-deficient phase has a higher theoretical capacity but lower voltage platform and higher chemical activity compared to the pristine phase.
ELECTROCHIMICA ACTA
(2024)
Article
Electrochemistry
Yating Du, Sayoko Shironita, Daisuke Asakura, Eiji Hosono, Yoshitsugu Sone, Yugo Miseki, Eiichi Kobayashi, Minoru Umeda
Summary: This study investigates the effect of high- and low-temperature environments on the charge-discharge performance of a Li-ion battery. The deterioration mechanisms of the battery at different temperatures are analyzed through various characterization techniques. The results indicate that the battery performance deteriorates more significantly at a low-temperature environment of 5 degrees C compared to higher temperatures. The understanding of the deterioration mechanisms can contribute to the development of safer battery usage methods.
ELECTROCHIMICA ACTA
(2024)
Article
Electrochemistry
Si-Si Shi, Zhi-Xiang Yuan, Fei Zhang, Ping Chen
Summary: In this study, a new nano-electrocatalyst was prepared, which exhibited superior electrocatalytic activity for the reduction of NO2- to ammonia in a neutral electrolyte, potentially due to the synergistic enhancement between Co3O4-x and Co.
ELECTROCHIMICA ACTA
(2024)
Article
Electrochemistry
Berna Dalkiran, Havva Bekirog
Summary: This study reports the use of deep eutectic solvents (DES) based on ethylene glycol and urea as low-cost and green electrolytes for enhancing electrochemical detection of natural antioxidants. The study successfully developed a disposable and effective electrochemical sensing platform for simultaneous determination of ascorbic acid (AA) and gallic acid (GA) using NaOH nanorods on a pencil graphite electrode. The proposed electrode showed improved analytical performance, with higher peak currents and shifted oxidation potentials in DES compared to BR buffer medium.
ELECTROCHIMICA ACTA
(2024)
Article
Electrochemistry
Sijun Ren, Jianguo Huang
Summary: In this study, a novel bio-inspired nanofibrous WO3/carbon composite was synthesized using a facile hydrothermal method. The three-dimensional network structure of the composite alleviated the volume expansion of WO3 nanorods and enhanced the charge-transport kinetics. The optimized composite exhibited superior lithium storage properties.
ELECTROCHIMICA ACTA
(2024)
Article
Electrochemistry
Zhilong Zheng, Yu Chen, Hongxia Yin, Hengbo Xiao, Xiangji Zhou, Zhiwen Li, Ximin Li, Jin Chen, Songliu Yuan, Junjie Guo, Haibin Yu, Zhen Zhang, Lihua Qian
Summary: This study found that interstitial Zn cations in CoMoO4 can modulate the dissolution kinetics of Mo cations and improve the OER performance. The interstitial Zn cations can prevent the dissolution of Co cations at high potential, enhancing the durability of the catalyst.
ELECTROCHIMICA ACTA
(2024)
Article
Electrochemistry
Xiaobo Lin, Shern R. Tee, Debra J. Searles, Peter T. Cummings
Summary: Molecular dynamics simulations using the constant potential method were used to investigate the charging dynamics and charge storage of supercapacitors. The simulations revealed that the water-in-salt electrolyte exhibited the highest charge storage and significantly higher capacitance on the negative electrode. The varying contributions of different electrode regions to supercapacitor performance were also demonstrated.
ELECTROCHIMICA ACTA
(2024)
Article
Electrochemistry
Wiktoria Lipinska, Vita Saska, Katarzyna Siuzdak, Jakub Karczewski, Karol Zaleski, Emerson Coy, Anne de Poulpiquet, Ievgen Mazurenko, Elisabeth Lojou
Summary: The spatial distribution of enzymes on electrodes is important for bioelectrocatalysis. In this study, controlled spatial distribution of gold nanoparticles on Ti nanodimples was achieved. The efficiency of enzymatic O2 reduction was found to be influenced by the size of the gold nanoparticles and their colocalization with TiO2. The highest stability of enzymatic current was observed with the largest gold nanoparticles.
ELECTROCHIMICA ACTA
(2024)
Article
Electrochemistry
Tariq M. Al-Hejri, Zeenat A. Shaikh, Ahmed H. Al-Naggar, Siddheshwar D. Raut, Tabassum Siddiqui, Hamdan M. Danamah, Vijaykumar V. Jadhav, Abdullah M. Al-Enizi, Rajaram S. Mane
Summary: This study explores a promising self-growth approach for the synthesis of nickel hydroxide (Ni(OH)2) nanosponge-balls on the surface of a nickel-foam (NiF) electrode. The modified NiF electrode, named Ni(OH)2@NiF, shows distinctive nanosponge-ball morphology and demonstrates excellent energy storage capability and electrocatalytic performance in both hydrogen and oxygen evolution reactions.
ELECTROCHIMICA ACTA
(2024)
Article
Electrochemistry
Rafael Del Olmo, Gregorio Guzman-Gonzalez, Oihane Sanz, Maria Forsyth, Nerea Casado
Summary: The use of Lithium-Ion Batteries (LIBs) is becoming increasingly extensive, and it is important to optimize the devices to achieve their maximum practical specific capacity. In this study, mixed ionic-electronic conducting (MIEC) binders based on PEDOT:PSS and PEDOT: PDADMA-TFSI were developed for Li-ion cathodes, and their performance was compared with conventional formulations. The influence of electrode formulations, including the addition of conducting carbon and an Organic Ionic Plastic Cristal (OIPC), was also analyzed. The proposed binders showed improved performance compared to conventional formulations with different electrolyte types and active materials.
ELECTROCHIMICA ACTA
(2024)