Journal
ELECTROCHIMICA ACTA
Volume 337, Issue -, Pages -Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2020.135761
Keywords
P2-Na0.67Ni0.25Mn0.75O2 thin film; Preferred orientation; Cycling performance; Rate capability; Sodium-ion batteries
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Funding
- National Natural Science Foundation of China [11374114, 10974062, 21908170]
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As a desirable cathode material for microelectronic energy storage devices, high performance P2 - Na0.67Ni0.25Mn0.75O2 thin films were prepared on stainless substrates using pulse laser deposition. To unlock their cyclability and rate capability, the substrate temperature as well as post deposition annealing was varied from 350 to 750 degrees C. The crystal structure and surface morphology were measured as functions of temperature, showing an enhancement in crystallization and a formation of textured grains with the c-axis. The charge/discharge tests demonstrate that the thin-film deposited at 550 degrees C owns the highest reversible capacity of 166.3 mAh g(-1) after 130 cycles at 13 mA g(-)1, corresponding to the initial value of 90.6%. As compared with the datum reported before, the as-deposited film-type P2 - Na0.67Ni0.25Mn0.75O2 cathode material exhibits superior cycling performance and high reversible capacity in the wide operating range from 1.5 to 4.3 V, which should be due to the enhancement of a stable P2-O2 phase transition platform at around 42/4.1 V. These outstanding results would endow P2 - Na0.67Ni0.25Mn0.75O2 thin film cathode material with great potential for application in high power and energy density sodium-ion batteries. (C) 2020 Elsevier Ltd. All rights reserved.
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