Hydroxylation of Aromatics by H 2 O 2 Catalyzed by Mononuclear Non‐heme Iron Complexes: Role of Triazole Hemilability in Substrate‐Induced Bifurcation of the H 2 O 2 Activation Mechanism

Characterized cis-FeV(O)(OH) intermediate mimics enzymatic oxidations in the gas phase

(2019) Margarida Borrell et al.   Nature Communications

Acid pKa Dependence in O–O Bond Heterolysis of a Nonheme FeIII–OOH Intermediate To Form a Potent FeV═O Oxidant with Heme Compound I-Like Reactivity

(2019) Shuangning Xu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Detection of a transient FeV(O)(OH) species involved in olefin oxidation by a bio-inspired non-haem iron catalyst

(2018) Shuangning Xu et al.   CHEMICAL COMMUNICATIONS

Acid-Triggered O−O Bond Heterolysis of a Nonheme FeIII (OOH) Species for the Stereospecific Hydroxylation of Strong C−H Bonds

(2018) Joan Serrano-Plana et al.   CHEMISTRY-A EUROPEAN JOURNAL

Spectroscopic and DFT Characterization of a Highly Reactive Nonheme FeV–Oxo Intermediate

(2018) Ruixi Fan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

H2O2 Oxidation by FeIII–OOH Intermediates and Its Effect on Catalytic Efficiency

(2018) Juan Chen et al.   ACS Catalysis

Equilibrating (L)FeIII–OOAc and (L)FeV(O) Species in Hydrocarbon Oxidations by Bio-Inspired Nonheme Iron Catalysts Using H2O2 and AcOH

(2017) Williamson N. Oloo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct hydroxylation of benzene and aromatics with H2O2 catalyzed by a self-assembled iron complex: evidence for a metal-based mechanism

(2017) Giorgio Capocasa et al.   Catalysis Science & Technology

Arene activation by a nonheme iron(III)–hydroperoxo complex: pathways leading to phenol and ketone products

(2016) Abayomi S. Faponle et al.   JOURNAL OF BIOLOGICAL INORGANIC CHEMISTRY

Bioinspired Nonheme Iron Catalysts for C–H and C═C Bond Oxidation: Insights into the Nature of the Metal-Based Oxidants

(2015) Williamson N. Oloo et al.   ACCOUNTS OF CHEMICAL RESEARCH

Biologically inspired non-heme iron-catalysts for asymmetric epoxidation; design principles and perspectives

(2015) Olaf Cussó et al.   CHEMICAL COMMUNICATIONS

Trapping a Highly Reactive Nonheme Iron Intermediate That Oxygenates Strong C—H Bonds with Stereoretention

(2015) Joan Serrano-Plana et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Differences and Comparisons of the Properties and Reactivities of Iron(III)-hydroperoxo Complexes with Saturated Coordination Sphere

(2014) Abayomi S. Faponle et al.   CHEMISTRY-A EUROPEAN JOURNAL

Kinetic Analysis of the Formation and Decay of a Non-Heme Ferric Hydroperoxide Species Susceptible to O–O Bond Homolysis

(2014) Qiao Zhang et al.   INORGANIC CHEMISTRY

Identification of a low-spin acylperoxoiron(III) intermediate in bio-inspired non-heme iron-catalysed oxidations

(2014) Williamson N. Oloo et al.   Nature Communications

H2O2activation with biomimetic non-haem iron complexes and AcOH: connecting the g = 2.7 EPR signal with a visible chromophore

(2013) Olga V. Makhlynets et al.   CHEMICAL COMMUNICATIONS

The Mechanism of Stereospecific CH Oxidation by Fe(Pytacn) Complexes: Bioinspired Non-Heme Iron Catalysts Containingcis-Labile Exchangeable Sites

(2013) Irene Prat et al.   CHEMISTRY-A EUROPEAN JOURNAL

Iron Coordination Chemistry with New Ligands Containing Triazole and Pyridine Moieties. Comparison of the Coordination Ability of the N-Donors

(2013) Nathalie Ségaud et al.   INORGANIC CHEMISTRY

Comparison of High-Spin and Low-Spin Nonheme FeIII–OOH Complexes in O–O Bond Homolysis and H-Atom Abstraction Reactivities

(2013) Lei V. Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rate-Determining Water-Assisted O–O Bond Cleavage of an FeIII-OOH Intermediate in a Bio-inspired Nonheme Iron-Catalyzed Oxidation

(2013) Williamson N. Oloo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Mononuclear Non-Heme High-Spin Iron(III)–Hydroperoxo Complex as an Active Oxidant in Sulfoxidation Reactions

(2013) Yun Mi Kim et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Hydroxylation of Aromatics with the Help of a Non-Haem FeOOH: A Mechanistic Study under Single-Turnover and Catalytic Conditions

(2012) Aurore Thibon et al.   CHEMISTRY-A EUROPEAN JOURNAL

Characterization of a High-Spin Non-Heme FeIII–OOH Intermediate and Its Quantitative Conversion to an FeIV═O Complex

(2011) Feifei Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Structure and reactivity of a mononuclear non-haem iron(III)–peroxo complex

(2011) Jaeheung Cho et al.   NATURE

Observation of Fe(V)=O using variable-temperature mass spectrometry and its enzyme-like C–H and C=C oxidation reactions

(2011) Irene Prat et al.   Nature Chemistry

Aromatic Hydroxylation at a Non-Heme Iron Center: Observed Intermediates and Insights into the Nature of the Active Species

(2010) Olga V. Makhlynets et al.   CHEMISTRY-A EUROPEAN JOURNAL

Transient Inverted Metastable Iron Hydroperoxides in Fenton Chemistry. A Nonenzymatic Model for Cytochrome P450 Hydroxylation

(2010) Robert D. Bach et al.   JOURNAL OF ORGANIC CHEMISTRY

Olefin-Dependent Discrimination between Two Nonheme HOFeVO Tautomeric Species in Catalytic H2O2Epoxidations

(2009) Anna Company et al.   CHEMISTRY-A EUROPEAN JOURNAL

Activation of dioxygen by a mononuclear non-heme iron complex: characterization of a FeIII(OOH) intermediate

(2009) Marlène Martinho et al.   DALTON TRANSACTIONS

A Novel Platform for Modeling Oxidative Catalysis in Non‐Heme Iron Oxygenases with Unprecedented Efficiency

(2008) Anna Company et al.   CHEMISTRY-A EUROPEAN JOURNAL

Preparation and Characterization of a Microcrystalline Non-Heme FeIII(OOH) Complex Powder: EPR Reinvestigation of FeIII(OOH) Complexes—Improvement of the Perturbation Equations for theg Tensor of Low-Spin FeIII

(2008) Marlène Martinho et al.   CHEMISTRY-A EUROPEAN JOURNAL

Non-heme iron polyazadentate complexes as catalysts for aromatic hydroxylation by H2O2: Particular efficiency of tetrakis(2-pyridylmethyl)ethylenediamine–iron(II) complexes

(2008) Aurore Thibon et al.   JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL