4.7 Review

Niobium/tantalum-based materials: Synthesis and applications in electrochemical energy storage

Journal

CHEMICAL ENGINEERING JOURNAL
Volume 380, Issue -, Pages -

Publisher

ELSEVIER SCIENCE SA
DOI: 10.1016/j.cej.2019.122428

Keywords

Nb/Ta-based material; Electrochemical energy storage; Supercapacitor; Battery

Funding

  1. National Natural Science Foundation of China [NSFC- 21671170, 21673203, 21201010]
  2. Top-notch Academic Programs Project of Jiangsu Higher Education Institutions (TAPP)
  3. Program for New Century Excellent Talents of the University in China [NCET-13-0645]
  4. Six Talent Plan [2015-XCL-030]
  5. Qinglan Project

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As transition metals, Nb and Ta share similar physical and chemical properties, exhibiting high melting and boiling points. Materials coexisting with Nb and Ta have attracted much attention in electrochemical energy storage, which are attributed to their unique crystal structures. However, Nb2O5 has the drawback of having a low electronic conductivity, which results in poor rate capability. Thus, Nb-based materials, including Nb-based oxides, Nb-based oxides/carbon and Nb-based carbides/nitrides, have been explored. This review discusses the use of Nb/Ta-based materials in electrochemical energy storage applications, including rechargeable batteries (e.g., lithium-ion batteries and sodium-ion batteries), supercapacitors and hybrid supercapacitors. In addition, the bottlenecks and challenges of using these materials are briefly discussed.

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