Journal
CATALYSIS COMMUNICATIONS
Volume 133, Issue -, Pages -Publisher
ELSEVIER
DOI: 10.1016/j.catcom.2019.105833
Keywords
2D materials; Mxene nano-sheets; Carbides; HDO; Guaiacol
Categories
Funding
- CONICYT Chile [3170072, 1180982, 11180121, PIA CCTE AFB170007, Fondequip N EQM160070]
- VID of Universidad de Chile [UI013/2018]
- Millennium Science Initiative of the Chilean Ministry of Economy, Development, and Tourism
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2D Mxene nano-sheets (Ti3C2Tx) were investigated for the hydrodeoxygenation of guaiacol as a lignin-derived model compound. The catalyst was characterized by TEM, XPS, Raman spectroscopy and TPR. The acid-base properties were measured by TPD-NH3 and TPRe-MeOH. Phenol was the main product obtained, and methylanisole was observed as the second main product. The study of Anisole conversion shows that methylanisole was likely obtained by a bimolecular transalkylation. Such formation, which has only been reported over acid catalysts, was associated to the combined action of acid-base pairs identified.
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