Journal
BIOMASS & BIOENERGY
Volume 131, Issue -, Pages -Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.biombioe.2019.105417
Keywords
Catalytic hydrothermal liquefaction; Spirulina platensis; Central composite design; Response surface methodology; Bio-oil; recovery
Funding
- National Natural Science Foundation of China [51876083, 51776088]
- Priority Academic Program Development of Jiangsu High Education Institutions
- High-tech Research Key laboratory of Zhenjiang [SS2018002]
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The aim of the present work was focused on optimizing the hydrothermal liquefaction (HTL) of Spirulina platensis catalyzed by Fe3O4 nanostructures to enhance the bio-oil yield and quality of bio-oil using response surface methodology (RSM). The structural morphology and crystalline nature of the synthesized catalyst was determined using a scanning electron microscope (SEM), high resolution transmission electron microscopy (HR-TEM) and X-ray powder diffraction (XRD). Three of the vital reaction parameters such as temperature, holding time and catalyst dosage were optimized through central composite design. A maximum bio-oil yield of 32.33% was observed for the high temperature at 320 degrees C, 0.75 g of catalyst dosage and 37 min of resident time. The maximum conversion was found at a lower temperature of 272 degrees C, the bio-oil yield of 27.66% was obtained with 0.45 g of catalyst dosage and 24 min of holding time which is an energy efficient optimum condition. The maximum bio-oil yield was influenced at a lower temperature due to the high catalytic activity. While compared to higher temperatures were not much influence was observed. It clearly states that the catalyst dosage playing a critical role in the lower temperature HTL reaction. GC-MS and FT-IR analysis of the produced bio-oil exhibits significant characteristics for biofuel applications. The Fe3O4 catalyst was recyclable for up to eight repeated cycles and constant bio-oil yield for the last four cycles. It shows the excellent reproduction ability towards HTL of Spirulina sp.
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