4.7 Article

Designer 3D CoAl-layered double hydroxide@N, S doped graphene hollow architecture decorated with Pd nanoparticles for Sonogashira couplings

Journal

APPLIED SURFACE SCIENCE
Volume 496, Issue -, Pages -

Publisher

ELSEVIER
DOI: 10.1016/j.apsusc.2019.143599

Keywords

Hierarchical CoAl-LDH; Pd nanoparticles; Hollow spheres; N,S doped graphene; Sonogashira reaction

Funding

  1. Alzahra University
  2. University of Tehran

Ask authors/readers for more resources

Hierarchical hollow flower-like CoAl-LDH assembled by N and S dual-doped graphene (N,S-G) was fabricated without any template for uniformly distribution of Pd nanoparticles. The resultant CoAl-LDH/N,S-G/Pd exhibited excellent activity in Sonogashira cross-coupling reactions. This hollow structure with large surface area exposes more accessible sites for anchoring metal species. Additionally, the synergistic doping of N and S can not only provide more defect sites by tuning the electronic properties, but also increase the electron density of Pd and enhance the unique interactions between metal particles and support. Moreover, the existence of reductive Co (II) sites within the support can capture and re-produce leached Pd particles, giving the composite long-term stability.

Authors

I am an author on this paper
Click your name to claim this paper and add it to your profile.

Reviews

Primary Rating

4.7
Not enough ratings

Secondary Ratings

Novelty
-
Significance
-
Scientific rigor
-
Rate this paper

Recommended

Article Chemistry, Applied

The synthesis of Fe3O4@SiO2@Pr-N (CH2CH2OH)3 and Fe3O4@SiO2@Pr-N (CH2CH2- OBuSO3H)3 as nanomagnetic catalysts and their application in the synthesis of tetrahydroacenaphtho[1,2-b]indolones and docking studies

Zohreh Kheilkordi, Ghodsi Mohammadi Ziarani, Fatemeh Mohajer, Alireza Badiei, Sunil Gaikwad, Rafael Luque

Summary: In this study, a magnetic nanocatalyst Fe3O4@SiO2@Pr-N (CH2CH2-OBuSO3H)(3) was synthesized and used in the one-pot synthesis of tetrah ydroacenaphtho[1,2-b]indolones under solvent-free conditions at 80℃. Fe3O4@SiO2@Pr-N (CH2CH2-OBuSO3H)(3) has a core-shell structure with high magnetic and nontoxic properties. Molecular docking studies also revealed its potential therapeutic effects against cancer targets.

APPLIED ORGANOMETALLIC CHEMISTRY (2023)

Article Chemistry, Multidisciplinary

Fe3O4@SiO2@Pr-Oxime-(BuSO3H)3 synthesis and its application as magnetic nanocatalyst in the synthesis of heterocyclic [3.3.3] propellanes

Zohreh Kheilkordi, Ghodsi Mohammadi Ziarani, Alireza Badiei, Fatemeh Mohajer, Rafael Luque

Summary: The modification of Fe3O4 nanomagnetic particles and the synthesis of Fe3O4@ SiO2@Pr-Oxime-(BuSO3H)(3) as a magnetic catalyst were successfully achieved. The magnetic catalyst was employed in the domino reaction without solvent, exhibiting advantages such as short reaction time, eco-friendly nature, and easy separation.

JOURNAL OF THE IRANIAN CHEMICAL SOCIETY (2023)

Article Chemistry, Applied

Artificial metalloenzyme with peroxidase-like activity based on periodic mesoporous organosilica with ionic-liquid framework

Sedigheh Abedanzadeh, Babak Karimi, Zainab Moosavi-Movahedi, Omid Pourshiani, Alireza Badiei, Ali A. Moosavi-Movahedi

Summary: Artificial enzymes resembling natural enzymes were developed using a rational design approach to simulate the coordination sphere around the iron active center. Periodic mesoporous organosilica (PMO) materials were used as supports due to their unique properties, and a new peroxidase-like nanozyme was fabricated. The biomimetic pathways used in this study showed potential for the development of nanozymes with excellent thermal stability and long-term storage stability.

MICROPOROUS AND MESOPOROUS MATERIALS (2023)

Article Chemistry, Multidisciplinary

Green synthesis and application of spiro[indoline-3,4'-pyrano[2,3-c]pyrazoles] as selective Hg (II) fluorescence sensor

Razieh Moradi, Ghodsi Mohammadi Ziarani, Alireza Badiei

Summary: This study focuses on the one-pot synthesis of spiro[indoline- 3,4'-pyrano[2,3-c] pyrazole] derivatives using isatins, pyrazolones, and malononitrile in aqueous media. The methodology offers mild and neutral reaction conditions, short reaction times, high yields, and operational simplicity.

RESEARCH ON CHEMICAL INTERMEDIATES (2023)

Article Chemistry, Inorganic & Nuclear

Architecture of a functionalized SBA-15 (SBA-Pr-N-BFE) chemosensor for the detection of Fe3+ions in aqueous media

Ghodsi Mohammadi Ziarani, Shadi Tahmasebi Ashtiani, Fatemeh Mohajer, Alireza Badiei, Rajender Varma

Summary: SBA-Pr-N-BFE is a chemosensor designed from mesoporous silica SBA-15, (3-aminopropyl)trimethoxysilane, and 1,2-bis(2-formylphenoxy)ethane (BFE), characterized and applied as a selective fluorescent chemosensor. Photoluminescence spectroscopy confirms its ability to selectively detect Fe3+ ions in H2O, with notable quenching in fluorescence intensity. The fluorescence studies establish a linear correlation between the fluorescence intensity of SBA-Pr-N-BFE and the concentration of Fe3+ ions, with a detection limit of 1.209 x 10-6 M.

INORGANIC CHEMISTRY COMMUNICATIONS (2023)

Article Polymer Science

Synthesis and Application of Novel Nanomagnetic Catalyst Fe3O4@SiO2@Pr-Gu-Cr-COOH in the Green Multi-component Synthesis of 1-(Benzothiazolylamino)methyl-2-naphthol

Zohreh Kheilkordi, Ghodsi Mohammadi Ziarani, Fatemeh Mohajer, Alireza Badiei, Rajender S. S. Varma

Summary: A novel magnetic nanocatalyst, Fe3O4@SiO2@Pr-Gu-Cr-COOH, was obtained by functionalizing the nanomagnetic core Fe3O4 with organic and inorganic entities. The catalyst activity of this nanocatalyst was evaluated in the multi-component synthesis of 1-(benzothiazolylamino)methyl-2-naphthols.

JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS (2023)

Article Spectroscopy

Selective detection of aspartic acid in human serum by a fluorescent probe based on CuInS2@ZnS quantum dots

Sara Safari, Ahmad Amiri, Alireza Badiei

Summary: In this work, an efficient core-shell fluorescent quantum dots (QDs) probe based on CuInS2 (CIS) core and ZnS shell with the formula of CIS@ZnS QDs was synthesized and characterized. The probe shows a remarkable fluorescence response toward Aspartic Acid (Asp).

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY (2023)

Article Biochemical Research Methods

Fumed-Si-Pr-PNS as a Photoluminescence sensor for the Detection of Hg2+ in Aqueous Media

Sepideh Saberi Afshar, Ghodsi Mohammadi Ziarani, Fatemeh Mohajer, Alireza Badiei

Summary: In this study, fumed silica was functionalized by piperazine and 2-naphthalenesulfonyl chloride to prepare Fumed-Si-Pr-Piperazine-Naphthalenesulfonyl chloride (Fumed-Si-Pr-PNS), which showed effective attachment on the surface of fumed silica. The optical sensing ability of Fumed-Si-Pr-PNS was studied and it was found to selectively detect Hg2+ ions in water solution.

JOURNAL OF FLUORESCENCE (2023)

Article Materials Science, Ceramics

Black TiO2-g-C3N4 heterojunction coupled with MOF (ZIF-67)-derived Co3S4/ nitrogen-doped carbon hollow nanobox

Mojtaba Rostami, Milad Jourshabani, Fatemeh Davar, Ghodsi Mohammadi Ziarani, Alireza Badiei

Summary: In this study, a facile synthesis method using ultrasound technique and solvothermal synthesis route was utilized to prepare a smart nanoheteroarchitecture photocatalyst with black TiO2-g-C3N4 type II heterojunction. The black TiCN-x wt% CoS/NC nanoheteroarchitecture exhibited high photocatalytic activity due to the efficient separation and charge transfer of electron-hole pairs on Co3S4/NC HNB and g-C3N4 surfaces.

JOURNAL OF THE AMERICAN CERAMIC SOCIETY (2023)

Article Chemistry, Multidisciplinary

Enhanced photocatalytic activity of modified black phosphorus-incorporated PANi/PAN nanofibers

Shadi Asgari, Ghodsi Mohammadi Ziarani, Alireza Badiei, Rajender S. Varma, Siavash Iravani, Fatemeh Mohajer

Summary: By incorporating modified black phosphorus nanosheets (BPNs) into conductive polymeric nanofibers (NFs), the photocatalytic activity of BPNs can be enhanced, while overcoming their drawbacks in powdered form.

RSC ADVANCES (2023)

Review Chemistry, Multidisciplinary

Recent advances in covalent organic frameworks (COFs) for wound healing and antimicrobial applications

Fatemeh Mohajer, Ghodsi Mohammadi Ziarani, Alireza Badiei, Siavash Iravani, Rajender S. S. Varma

Summary: Covalent organic frameworks (COFs) are crystal-like organic structures that can be prepared from pre-designed construction block precursors, and they have been widely studied for various applications such as sensing/imaging, cancer theranostics, drug delivery, tissue engineering, wound healing, and antimicrobials. COFs have desirable properties such as harmonious pore size, enduring porosity, thermal stability, and low density, and they can be functionalized with various groups to provide desired constituents. Recent advancements in the applications of COF-based systems against bacterial infections and for wound healing are discussed, focusing on challenges and future guidelines.

RSC ADVANCES (2023)

Article Environmental Sciences

ZnO/black phosphorus/C3N4 composite: An effective photocatalyst for Cr (VI) reduction and degradation of rhodamine B

Sahar Moradian, Ghodsi Mohammadi Ziarani, Alireza Badiei, Siavash Iravani

Summary: The use of photocatalysts is a promising method for the removal of Cr (VI) and rhodamine dyes in wastewater treatment. This study synthesized a composite of carbon nitride (C3N4), zinc oxide (ZnO), and black phosphorus (BP) and investigated its photocatalytic ability for the degradation of rhodamine B (RhB) and detoxification of hexavalent chromium ion. The composite showed high efficiency in removing RhB and reducing hexavalent chromium, and the active species involved in the photocatalysis process were identified. The composite also exhibited impressive charge separation and low recombination, resulting in higher photocurrent density compared to the individual semiconductors. The band gap values and the double Z-scheme mechanism of the composite were determined through various experiments and analysis. The results highlight the potential of this composite as an efficient and environmentally friendly photocatalyst for wastewater treatment.

ENVIRONMENTAL RESEARCH (2023)

Article Biochemical Research Methods

Nitrogen-contained Nanoporous Hyper-cross-linked Polymer: A New Turn-on Fluorescence Probe for Detection of Ag+ Ions in Aqueous Media

Fariba Nasimpour, Mohammadreza Mansournia, Alireza Badiei

Summary: In this study, a new fluorescence probe was designed using NH2-HCP material for the selective detection of silver ions. The fluorescence signal exhibited a linear enhancement with increasing concentration of silver ions. The probe's response to various other ions and halogen anions was also investigated. Under optimal conditions, the probe showed a wide linear range and a low detection limit.

JOURNAL OF FLUORESCENCE (2023)

Article Chemistry, Physical

Multifunctional continuous solid solution Na0.9Mg0.45Ti3.55O8-Na2Fe2Ti6O16: Preparation, characterization, magnetism, dual absorption, adsorption, and photocatalysis

Qi-Wen Chen, Ze-Qing Guo, Jian-Ping Zhou

Summary: Multifunctional continuous solid solutions NFMTO-x were successfully synthesized via a one-step hydrothermal method by controlling the ratio of Mg and Fe. The NFMTO-x materials exhibited enhanced visible light response, effective adsorption and photocatalytic degradation of organic pollutants, CO2 methanation capability, and easy recyclability due to their magnetic properties. This research provides a significant multifunctional material for water purification.

APPLIED SURFACE SCIENCE (2024)

Review Chemistry, Physical

Critical advances in the field of magnetron sputtered bioactive glass thin-films: An analytical review

George E. Stan, Maziar Montazerian, Adam Shearer, Bryan W. Stuart, Francesco Baino, John C. Mauro, Jose M. F. Ferreira

Summary: Bioactive glasses have the ability to form strong bonds with tissues and release therapeutic ions. However, their biomechanical compatibility limits their use in load-bearing applications. The use of magnetron sputtering technology to fabricate BG coatings shows promise in improving their efficacy and potential for application.

APPLIED SURFACE SCIENCE (2024)

Article Chemistry, Physical

Corrosion mode evaluation of Fe-based glassy alloys with metalloid elements by electrochemical noise (EN)

Zhaoxuan Wang, Zhicheng Yan, Zhigang Qi, Yu Feng, Qi Chen, Ziqi Song, Meng Huang, Peng Jia, Ki Buem Kim, Weimin Wang

Summary: The corrosion behavior of Fe-60 and Fe-83 ribbons in 0.6 M NaCl was studied. Fe-60 exhibited a local corrosion mode and formed a stable passivation film with higher corrosion resistance, while Fe-83 showed a combination of local and global corrosion modes and had lower corrosion resistance. Controlling the precipitation of nanocrystalline phases and increasing the POx content in the passivation film significantly improved the corrosion resistance of Fe-based glassy alloys.

APPLIED SURFACE SCIENCE (2024)

Article Chemistry, Physical

Impacts of Zr content of HfZrOx-Based FeFET memory on resilience towards proton radiation

Hao-Kai Peng, Sheng-Yen Zheng, Wei-Ning Kao, Ting-Chieh Lai, Kai-Sheun Lee, Yung- Hsien Wu

Summary: This study investigates the effects of high energy/fluence proton radiation on the performance of HfZrOx-based FeFETs memory with different Zr content. The results show that the characteristics of FeFETs are influenced by proton radiation, and the extent of the influence depends on the Zr content. FeFETs with 50% Zr content exhibit minimal changes in memory window and demonstrate good endurance and retention performance.

APPLIED SURFACE SCIENCE (2024)

Article Chemistry, Physical

Excellent crystalline silicon surface passivation by transparent conductive Al-doped ZnO/ITO stack

Zongyi Yue, Guangyi Wang, Zengguang Huang, Sihua Zhong

Summary: In this study, AZO and ITO films were successfully tuned as excellent passivation layers for c-Si surfaces, achieving effective minority carrier lifetime and outstanding optical properties through the optimization of annealing temperature and interfacial silicon oxide.

APPLIED SURFACE SCIENCE (2024)

Article Chemistry, Physical

Hydrogen sensing capabilities of highly nanoporous black gold films

Martin Hruska, Jan Kejzlar, Jaroslav Otta, Premysl Fitl, Michal Novotny, Jakub Cizek, Oksana Melikhova, Matej Micusik, Peter Machata, Martin Vrnata

Summary: This paper presents a detailed study on the hydrogen sensing capabilities of highly nanoporous black gold films. The films exhibit fast response and recovery times at low temperatures. Different levels of nanoporosity were prepared and tested to investigate the sensing properties, and it was found that nanoporous black gold is suitable for hydrogen sensing. The sensitivity of the film depends on its nanoporosity.

APPLIED SURFACE SCIENCE (2024)

Article Chemistry, Physical

Abnormal stability of hydrogenic defects and magnetism near the HSrCoO2.5(001) surface

Yupu Wang, Gaofeng Teng, Chun To Yiu, Junyi Zhu

Summary: In the study of BM-SCO and HSCO thin films, it was found that H vacancies tend to prefer sites near the external surface or oxygen vacancy channels (OVCs), while H interstitials prefer sites of oxygen on a layer that contains six-fold coordinated Co. These findings not only enrich the understanding of complex surface phenomena of defect formation but also provide an explanation for the reversibility during phase transformation.

APPLIED SURFACE SCIENCE (2024)

Article Chemistry, Physical

Space variant fiber nanogratings induced by femtosecond laser direct writing

Jiafeng Lu, Linping Teng, Qinxiao Zhai, Chunhua Wang, Matthieu Lancry, Ye Dai, Xianglong Zeng

Summary: In this study, we achieved full control of fiber nanograting orientation by manipulating laser polarization, and tailored space variant fiber nanogratings, which expanded the diversity in fiber nanograting engineering.

APPLIED SURFACE SCIENCE (2024)

Article Chemistry, Physical

Wetting mechanisms in the mass transfer process of CuSi3 droplets on the TC4 and 304SS multi-metal system controlled by the hybrid shielding gas atmosphere

Yibo Liu, Yujie Tao, Yue Liu, Qi Sun, Qinrong Lin, Kexin Kang, Qinghua Zhang, Qingjie Sun

Summary: This study investigates the wettability of the Ti-Cu-Fe multi-metal system, specifically the wetting behaviors of CuSi3 droplets on TC4 and 304SS plates. The results show that the CO2 + Ar gas atmosphere significantly affects interfacial mass transfer, thus influencing the wettability of the systems.

APPLIED SURFACE SCIENCE (2024)

Article Chemistry, Physical

Size-regulated Co-doped hetero-interfaced 3D honeycomb MXene as high performance electromagnetic absorber with anti-corrosion performance

Jimei Liu, Fei Wang, Rong Guo, Yuqi Liu, Mengyu Zhang, Jaka Sunarso, Dong Liu

Summary: This study developed Co/MXene composites with anti-corrosion properties by varying the cobalt content. These composites exhibited remarkable electromagnetic absorption performance and high resistance to corrosion under various corrosive conditions. The study also revealed the mechanism of electron transfer from cobalt to MXene and the electromagnetic dissipation behavior originated from polarization loss alone.

APPLIED SURFACE SCIENCE (2024)

Article Chemistry, Physical

Ultrafine Ru nanoparticles on nitrogen-doped CNT arrays for HER: A CVD-based protocol achieving microstructure design and strong catalyst-support interaction

Moujie Huang, Yongsong Ma, Jingbo Yang, Lingyun Xu, Hangqi Yang, Miao Wang, Xin Ma, Xin Xia, Junhao Yang, Deli Wang, Chuang Peng

Summary: Strong metal-support interactions (SMSIs) are important for enhancing catalytic activities and stability in thermal catalysis. This study demonstrates a method to create SMSIs in electrocatalysis using carbon nanotubes and Ru nanoparticles, resulting in excellent catalytic activity and stability.

APPLIED SURFACE SCIENCE (2024)

Article Chemistry, Physical

Novel biphenylene as cisplatin anticancer drug delivery carrier; insight from theoretical perspective

Ravi Trivedi, Brinti Mondal, Nandini Garg, Brahmananda Chakraborty

Summary: This study explores the potential of biphenylene as a nanocarrier for the delivery of the anticancer drug cisplatin. It is found that biphenylene offers physical stability, rapid release rate, solubility, and bio-compatibilities compared to other nanocarriers. The adsorption of cisplatin on the surface of biphenylene involves charge transfer from cisplatin to biphenylene. The drug is shown to be released at body temperature in an acidic environment. Biphenylene also exhibits excellent cytotoxicity activity and cellular uptake of the drug. Overall, biphenylene shows promise as a potential nanocarrier for cisplatin delivery.

APPLIED SURFACE SCIENCE (2024)

Article Chemistry, Physical

Platform for surface-enhanced Raman scattering in layered quantum materials

Hyun Jeong, Hyeong Chan Suh, Ga Hyun Cho, Rafael Salas-Montiel, Hayoung Ko, Ki Kang Kim, Mun Seok Jeong

Summary: In this study, a potential platform to enhance Raman scattering and increase the number of observable Raman modes in monolayer transition metal dichalcogenides (TMDs) was proposed. The platform consisted of large-scale arrays of gold micropillars (MPs), which were able to enhance the Raman intensity of TMDs and make difficult-to-detect Raman modes observable. The platform showed great industrial advantages and wide applicability due to its low cost, simple process, large controllable area, and short process time.

APPLIED SURFACE SCIENCE (2024)

Article Chemistry, Physical

Cyclotriphosphazene (P3N3) derived FeOx@SPNO-C core-shell nanospheres as peroxymonosulfate activator for degradation via non-radical pathway

Yasir Abbas, Shafqat Ali, Sajjad Ali, Waqar Azeem, Zareen Zuhra, Haoliang Wang, Mohamed Bououdina, Zhenzhong Sun

Summary: In this study, FeOx@SPNO-C core-shell nanospheres as a catalyst for degradation of sulfamethoxazole (SMX) were successfully synthesized. The synergistic interaction between FeOx and SPNO-C, high carbon charge density, and the presence of C = O groups and N/Fe-Nx sites were found to be key factors for the enhanced degradation of SMX.

APPLIED SURFACE SCIENCE (2024)

Article Chemistry, Physical

Hierarchical confinement of Prussian blue nanoparticles via NH2-MIL-88B (Fe): Rational design and electrocatalytic application

Qiaoting Yang, Yuxiao Gong, Yan Qian, Zhou-Qing Xiao, Serge Cosnier, Xue-Ji Zhang, Robert S. Marks, Dan Shan

Summary: This study proposes a hierarchical confinement strategy to design Prussian blue nanoparticles (PB NPs) with satisfactory electrocatalytic ability and stability. The catalytic synthesis of PB NPs is achieved through a hydrothermal process, and the as-prepared PB@NH2MIL exhibits efficient electronic transmission and enhanced electrocatalytic properties.

APPLIED SURFACE SCIENCE (2024)