Journal
APPLIED SURFACE SCIENCE
Volume 497, Issue -, Pages -Publisher
ELSEVIER
DOI: 10.1016/j.apsusc.2019.143776
Keywords
Aluminium oxide; Hollow microsphere; Binary metal oxides; Catalytic oxidation; Anti-sintering ability
Categories
Funding
- National Natural Science Foundation of China [21607163]
- China Postdoctoral Science Foundation [2017M622139, 2018M630754]
- Postdoctoral Application Research Program of Qingdao
- Thousand Talents Plan
- World-Class Discipline Program of Shandong Province
- Taishan Scholar's Advantageous and Distinctive Discipline Program of Shandong Province
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Alumina hollow microspheres (Al2O3-hms) were synthesized and used to support metal oxide and binary metal oxide particles to prepare three catalysts, designated as RuOx/Al2O3-hms, CoOx/Al2O3-hms and RuCoOx/Al2O3-hms. Their catalytic properties in vinyl chloride oxidation were investigated and found to follow this order: RuCoOx/Al2O3-hms > RuOx/Al2O3-hms > CoOx/Al2O3-hms. In comparison with a commercial Al2O3 support, the Al2O3-hms provide a higher specific surface area and unique hollow spherical morphology, benefiting for uniform distribution of catalyst particles. It was also found that the strong metal-support interaction between metal nanoparticles and Al2O3-hms has significant effects on the low-temperature reducibility, the surface oxygen abundance and mobility, giving rise to different oxidation activities. The Al2O3-hms supported metal catalysts remained relatively high catalytic activity after consecutive catalytic runs and high-temperature annealing. The anti-sintering ability enhancement of metal particles was attributed to the stabilization and metalsupport interaction effects with Al2O3-hms.
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