Article
Materials Science, Multidisciplinary
Nikolay Busleev, Nikita Smirnov, Vladimir Kesaev, Sergey Kudryashov
Summary: This research focuses on investigating the darkening phenomenon in soda-lime glasses caused by the formation of color centers when exposed to infrared femtosecond laser radiation. The study examines the kinetics of color center generation and thermal relaxation, with a particular emphasis on the influence of storage temperature. Additionally, the changes in transmittance and refractive index values of darkened glass were measured based on different laser processing parameters. The study also discusses the application of darkened glass in creating halftone monochrome images for decorative purposes.
APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING
(2023)
Article
Materials Science, Ceramics
Nisha Sheth, Carl Greenley, Raul Bermejo, John C. Mauro, Carlo G. Pantano, Seong H. Kim
Summary: Water or acid soaking surface treatments have been shown to increase the mechanical strength of soda-lime silicate (SLS) glasses, especially in humid environments where acid-leached surfaces exhibit higher failure stress. This indicates that acid-leached surface chemistry can play a role in lowering the transport kinetics of water molecules to critical flaws.
JOURNAL OF THE AMERICAN CERAMIC SOCIETY
(2021)
Article
Materials Science, Ceramics
Rita Slilaty Pipes, James E. Shelby
Summary: The glass formation region has been determined for the soda lime germanate system, which includes both homogeneous and phase separated glasses. The homogeneous glasses exhibit behavior typical of the germanate anomaly, while the phase separated glasses' properties can be explained by considering the effect of morphology.
JOURNAL OF NON-CRYSTALLINE SOLIDS
(2021)
Article
Chemistry, Physical
Anis Ouchene, Guilhem Mollon, Maelig Ollivier, Xxx Sedao, Alina Pascale-Hamri, Guillaume Dumazer, Eric Serris
Summary: The study investigated the influence of laser texturing parameters and chemical curing environments on the wettability of flat soda-lime silica glass surfaces using contact angle measurements. The textured surfaces were created using femtosecond laser pulses with varying fluence, periodicity, and pulse number. Different chemical curing environments resulted in a range of hydrophilicity and hydrophobicity. Experimental characterizations of the surface roughness and contact angle hysteresis measurements revealed a transition from a Wenzel regime to a Cassie-Baxter regime induced by the chemical environment.
APPLIED SURFACE SCIENCE
(2023)
Article
Materials Science, Ceramics
Sean Locker, Jennifer A. Clark, S. K. Sundaram
Summary: Femtosecond pulse laser radiation on alkali and alkaline earth modified soda-lime silicate glasses leads to densification on the surface, with the degree of density changes depending on pulse energy and glass-network connectivity. Raman spectroscopy study confirms the role of modifier ions in affecting the structural rigidity and disorder degree of the glass.
INTERNATIONAL JOURNAL OF APPLIED GLASS SCIENCE
(2021)
Article
Chemistry, Multidisciplinary
Marcos Soldera, Sabri Alamri, Paul Alexander Suermann, Tim Kunze, Andres Fabian Lasagni
Summary: The study explores the direct patterning of soda lime substrates using ps-pulsed laser radiation in the visible spectrum through non-linear absorption, producing line- and dot-like patterns with spatial periods between 2.3 and 9.0 μm and aspect ratios up to 0.29. Laser-induced periodic surface structures with a feature size of approximately 300 nm are also observed within these microstructures. Treated surfaces exhibit significantly modified properties, with increased hydrophilic behavior and the ability to act as relief diffraction gratings splitting incident light into diffraction modes.
Article
Materials Science, Ceramics
Lorena R. Rodrigues, Alexander S. Abyzov, Vladimir M. Fokin, Edgar Dutra Zanotto
Summary: This article discusses the influence of structural relaxation on crystal nucleation process. It shows that structural relaxation has a significant impact on nucleation rate at low temperatures, leading to a continuous increase before reaching a steady state. The study also explains the alleged breakdown of CNT at low temperatures and reveals a significantly lower actual maximum nucleation temperature than previously reported values.
JOURNAL OF THE AMERICAN CERAMIC SOCIETY
(2021)
Article
Optics
Shengying Lai, Martin Ehrhardt, Pierre Lorenz, Joachim Zajadacz, Bing Han, Andriy Lotnyk, Klaus Zimmer
Summary: Experimental evidence shows that ultrashort pulsed laser irradiation of soda-lime glass near the surface results in the formation of micro- and nanoscopic bubbles. The composition deviation near the surface of the glass plays a key role in the formation of these bubbles.
OPTICS AND LASER TECHNOLOGY
(2022)
Article
Materials Science, Ceramics
Peter Fielitz, Daniel R. Cassar, Nikolay S. Yuritsyn, Alexander S. Abyzov, Vladimir M. Fokin, Guenter Borchardt, Joachim Deubener
Summary: Isolated Na2O dot 2CaO dot 3SiO(2) (NC2S3) single crystals were grown at temperatures above the glass transition. The enrichment of Na in the continuous solid solution upon crystallisation causes a depletion of soda in the growing interfacial diffusion zone, resulting in a change in viscosity.
JOURNAL OF NON-CRYSTALLINE SOLIDS
(2022)
Article
Materials Science, Multidisciplinary
Pratyush Srivastava, Koichi Tanaka, Brian Ramirez, Vijay Gupta
Summary: This study reports the nucleation of the Stishovite phase in shock-loaded soda-lime glass samples at a low compressive stress of 7 GPa. Experimental methods such as using a table-top setup and HRTEM imaging revealed 4 nm Stishovite crystals distributed within the amorphous SLG matrix.
Article
Engineering, Electrical & Electronic
Recep Kurtulus, Taner Kavas, K. A. Mahmoud, Iskender Akkurt, Kadir Gunoglu, M. I. Sayyed
Summary: By adding niobium oxide to waste soda-lime glass, the optical and physical properties can be improved, enhancing the radiation shielding effect, which shows potential value in gamma radiation applications.
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS
(2021)
Article
Materials Science, Ceramics
G. Gupta, T-Y Chen, P. Rautiyal, A. G. Williams, J. A. Johnson, C. E. Johnson, R. Edge, P. A. Bingham
Summary: The development of inexpensive radiation-resistant glass is crucial for potential applications in displays, optics, and nuclear or space environments. This study investigates the resistance to gamma-ray and X-ray induced damage of float-type glasses modified with Sb2O3 and finds that the addition of 0.5 mol% Sb2O3 leads to the highest visible-wavelength transparency and enhanced radiation resistance.
JOURNAL OF NON-CRYSTALLINE SOLIDS
(2022)
Article
Engineering, Mechanical
S. Dondeti, H. V. Tippur
Summary: Dynamic mixed-mode fracture of soda-lime glass (SLG) was investigated using Digital Gradient Sensing (DGS) and ultrahigh-speed photography. The fracture envelope for SLG, encompassing various mode-mixities, was developed for the first time and compared with prevailing approaches. The critical effective stress intensity factors for SLG show a decreasing trend as mode-II conditions become dominant.
THEORETICAL AND APPLIED FRACTURE MECHANICS
(2023)
Article
Optics
Jun Kim, Young Kyu Kim, Jonghyun Ju, Mohammad Ali Asgar, Taekyung Kim, Seok-min Kim
Summary: In this paper, a cost-effective and high-precision glass nanoimprinting method using a carbonized carbon mold on soda-lime glass is demonstrated. The proposed method is verified to be applicable for fabricating photonic crystal filters with good performance and thermal stability.
OPTICS AND LASER TECHNOLOGY
(2022)
Article
Materials Science, Ceramics
Andrea Bernasconi, Monica Dapiaggi, Chiara Milanese, Marco Alloni, Alessandro Pavese
Summary: The atomic structure of a soda-lime-aluminosilicate network glass that underwent two different thermal treatments has been investigated using in-situ Synchrotron Powder Diffraction experiments. The study revealed the volume variations, relaxation level, short range order characteristics, and structural features of the samples under different thermal treatments. The results describe the multiple over temperature phenomenology of the composition and show how the local range behaves independently from the sample's thermal history.
JOURNAL OF NON-CRYSTALLINE SOLIDS
(2021)
Article
Materials Science, Ceramics
Klaus Zimmer, Martin Ehrhardt, Pierre Lorenz, Xi Wang, Pingping Wang, Shufeng Sun
Summary: A gentle machining process for SiC-SiC material removal using laser-induced plasma was proposed and demonstrated, showing no mechanical damage to the composite structure. Different surface features were observed during the material removal process, suggesting that this method can be effective for various SiC-SiC applications.
CERAMICS INTERNATIONAL
(2022)
Article
Physics, Applied
Afaque M. Hossain, Martin Ehrhardt, Martin Rudolph, Dmitry Kalanov, Pierre Lorenz, Klaus Zimmer, Andre Anders
Summary: This study investigates the morphological development of plasma generated by focusing femtosecond laser in gases and explains it through quantification of temperature. Experimental analysis reveals that plasma produced in air undergoes stages of ellipsoidal to spherical to toroidal development, while plasma in argon experiences axial compression of an ellipsoidal shape. Simulation experiments and temperature measurements demonstrate the effects of pressure gradient and vorticity on plasma morphology in different gases.
JOURNAL OF PHYSICS D-APPLIED PHYSICS
(2022)
Article
Optics
Shengying Lai, Martin Ehrhardt, Pierre Lorenz, Joachim Zajadacz, Bing Han, Andriy Lotnyk, Klaus Zimmer
Summary: Experimental evidence shows that ultrashort pulsed laser irradiation of soda-lime glass near the surface results in the formation of micro- and nanoscopic bubbles. The composition deviation near the surface of the glass plays a key role in the formation of these bubbles.
OPTICS AND LASER TECHNOLOGY
(2022)
Article
Chemistry, Multidisciplinary
Ye Yu, Pierre Lorenz, Carsten Strobel, Joachim Zajadacz, Matthias Albert, Klaus Zimmer, Robert Kirchner
Summary: A fast self-folding technique using vacuum microforming was developed in this study, achieving the self-folding of microcubes within 30 ms. Additionally, a metal-insulator-metal plasmonic nanostructure with advanced optical properties was fabricated, and these properties were well preserved throughout the folding process in 3D architectures.
Article
Thermodynamics
Xi Wang, Martin Ehrhardt, Pierre Lorenz, Klaus Zimmer, Fengyun Zhang, Jin Wang, Pingping Wang, Yoshio Hayasaki, Harith Bin Ahmad, Jing Shao, Shufeng Sun
Summary: This paper establishes a prediction model for the threshold of melting, vaporization, and ablation starting and completion in silicon irradiated by laser with different pulse widths and wavelengths, based on the results of temperature field. The experimental measurement confirms the laser-induced ablation threshold in silicon. The study quantitatively analyzes the variation tendency of the threshold with laser pulse width and predicts the generation of periodic linear and circular ripples on the silicon surface.
EXPERIMENTAL HEAT TRANSFER
(2023)
Article
Chemistry, Physical
Stephen Hocker, Hansjoerg Lipp, Siegfried Schmauder, Alexander V. Bakulin, Svetlana E. Kulkova
Summary: The interfacial bonding of three different semi-coherent bcc-Fe(110)/graphene interfaces was investigated using density functional theory. The results showed that the interfacial adhesion can be understood from the electronic structure. The influence of single vacancies in graphene on the Fe(110) surfaces was also studied, and it was found that a single vacancy leads to a strong increase in interfacial adhesion.
APPLIED SURFACE SCIENCE
(2022)
Article
Chemistry, Physical
Robert Heinke, Martin Ehrhardt, Jens Bauer, Andriy Lotnyk, Pierre Lorenz, Roy Morgenstern, Thomas Lampke, Thomas Arnold, Klaus Zimmer
Summary: Precise surface machining of silicon using pulsed laser processing is challenging due to the modifications caused by laser ablation. In order to meet the increasing demand for precisely structured silicon surfaces in various fields, a new laser-based ultra-precise surface machining technique called laser-induced plasma etching process (LIPE) was studied. The LIPE process showed no melting or structural defects and minimal chemical contamination, making it a promising method for achieving ultra-precise surface machining of silicon.
APPLIED SURFACE SCIENCE
(2022)
Article
Physics, Applied
Elena Bez, Marcel Himmerlich, Pierre Lorenz, Martin Ehrhardt, Aidan Graham Gunn, Stephan Pfeiffer, Martino Rimoldi, Mauro Taborelli, Klaus Zimmer, Paolo Chiggiato, Andre Anders
Summary: Ultrashort-pulse laser processing of copper in air has been studied to reduce the secondary electron yield (SEY). The study investigates the influence of laser power, scanning speed, and scanning line distance on ablation depth, surface oxidation, topography, and SEY. Increasing laser fluence results in a transition from Cu2O to CuO-dominated surface, deeper trenches, higher particle density, and reduced SEY. Electron-induced surface conditioning at 250 eV can further reduce SEY.
JOURNAL OF APPLIED PHYSICS
(2023)
Article
Nanoscience & Nanotechnology
Afaque M. Hossain, Martin Ehrhardt, Martin Rudolph, Pierre Lorenz, Dmitry Kalanov, Klaus Zimmer, Andre Anders
Summary: Focusing femtosecond laser pulses in gases can lead to different breakdown phenomena in gases, ranging from simple optical breakdown to nonlinear optical breakdown. The dynamics of the plasma formed after the pulse exposure depends on the energy deposited by the laser in the breakdown volume. By using a breakdown model, researchers have estimated the breakdown volume and shown that the energy deposition in this volume determines the characteristics of laser-induced plasma. This study is important in preventing undesired self-focusing conditions during material processing.
Article
Chemistry, Physical
Pierre Lorenz, Joachim Zajadacz, Jens Bauer, Martin Ehrhardt, Gregor Hommes, Sebastian Peter, Klaus Zimmer
Summary: The fabrication of super hydrophobic surfaces with various potential applications is possible through the combined adjustment of topography and chemical surface composition of stainless-steel. The usability of these surfaces depends on their chemical stability. In this study, a two-step modification process involving laser nanostructuring and chemical modification was used to create modified stainless steel surfaces. The temporal stability of the super hydrophobic properties of the surface was found to be dependent on the laser-induced surface topography.
SURFACES AND INTERFACES
(2023)
Article
Materials Science, Multidisciplinary
Pierre Lorenz, Joachim Zajadacz, Andriy Lotnyk, Juergen W. Gerlach, Martin Ehrhardt, Robert Kirchner, Klaus Zimmer
Summary: The study investigates the fabrication of plasmonic 3D microstructures using gold-nanoparticle-filled acrylate-based micron-scale cuboids. UV and heat treatments result in the formation of polymerized acrylate and gold nanoparticles with specific plasmonic resonance wavelengths. Laser cutting allows the fabrication of adjustable micro-cuboids. The concept enables the easy fabrication of plasmonic microstructures with tunable properties and sizes.
PHYSICA STATUS SOLIDI A-APPLICATIONS AND MATERIALS SCIENCE
(2023)
Article
Materials Science, Multidisciplinary
Robert Heinke, Thomas Arnold, Martin Ehrhardt, Pierre Lorenz, Klaus Zimmer
Summary: The combination of beam-based technologies such as atmospheric pressure plasma jets (APPJ) and laser cleaning enables the removal of residual layers formed during plasma etching, facilitating ultraprecise manufacturing of optical glass.
PHYSICA STATUS SOLIDI A-APPLICATIONS AND MATERIALS SCIENCE
(2023)
Article
Chemistry, Physical
Visar Demiri, Martin Ehrhardt, Pierre Lorenz, Robert Heinke, Klaus Zimmer
Summary: Research was conducted on laser-induced plasma etching (LIPE) of polyimide film for the development of ultraprecise surface machining (UPSM) techniques. Experimental studies were carried out on key parameters to explore their impact on etching rate and surface morphology, achieving low LIPE rates and regular nanostructures.
APPLIED SURFACE SCIENCE ADVANCES
(2023)
Article
Chemistry, Physical
Qi-Wen Chen, Ze-Qing Guo, Jian-Ping Zhou
Summary: Multifunctional continuous solid solutions NFMTO-x were successfully synthesized via a one-step hydrothermal method by controlling the ratio of Mg and Fe. The NFMTO-x materials exhibited enhanced visible light response, effective adsorption and photocatalytic degradation of organic pollutants, CO2 methanation capability, and easy recyclability due to their magnetic properties. This research provides a significant multifunctional material for water purification.
APPLIED SURFACE SCIENCE
(2024)
Review
Chemistry, Physical
George E. Stan, Maziar Montazerian, Adam Shearer, Bryan W. Stuart, Francesco Baino, John C. Mauro, Jose M. F. Ferreira
Summary: Bioactive glasses have the ability to form strong bonds with tissues and release therapeutic ions. However, their biomechanical compatibility limits their use in load-bearing applications. The use of magnetron sputtering technology to fabricate BG coatings shows promise in improving their efficacy and potential for application.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Zhaoxuan Wang, Zhicheng Yan, Zhigang Qi, Yu Feng, Qi Chen, Ziqi Song, Meng Huang, Peng Jia, Ki Buem Kim, Weimin Wang
Summary: The corrosion behavior of Fe-60 and Fe-83 ribbons in 0.6 M NaCl was studied. Fe-60 exhibited a local corrosion mode and formed a stable passivation film with higher corrosion resistance, while Fe-83 showed a combination of local and global corrosion modes and had lower corrosion resistance. Controlling the precipitation of nanocrystalline phases and increasing the POx content in the passivation film significantly improved the corrosion resistance of Fe-based glassy alloys.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Hao-Kai Peng, Sheng-Yen Zheng, Wei-Ning Kao, Ting-Chieh Lai, Kai-Sheun Lee, Yung- Hsien Wu
Summary: This study investigates the effects of high energy/fluence proton radiation on the performance of HfZrOx-based FeFETs memory with different Zr content. The results show that the characteristics of FeFETs are influenced by proton radiation, and the extent of the influence depends on the Zr content. FeFETs with 50% Zr content exhibit minimal changes in memory window and demonstrate good endurance and retention performance.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Zongyi Yue, Guangyi Wang, Zengguang Huang, Sihua Zhong
Summary: In this study, AZO and ITO films were successfully tuned as excellent passivation layers for c-Si surfaces, achieving effective minority carrier lifetime and outstanding optical properties through the optimization of annealing temperature and interfacial silicon oxide.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Martin Hruska, Jan Kejzlar, Jaroslav Otta, Premysl Fitl, Michal Novotny, Jakub Cizek, Oksana Melikhova, Matej Micusik, Peter Machata, Martin Vrnata
Summary: This paper presents a detailed study on the hydrogen sensing capabilities of highly nanoporous black gold films. The films exhibit fast response and recovery times at low temperatures. Different levels of nanoporosity were prepared and tested to investigate the sensing properties, and it was found that nanoporous black gold is suitable for hydrogen sensing. The sensitivity of the film depends on its nanoporosity.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Yupu Wang, Gaofeng Teng, Chun To Yiu, Junyi Zhu
Summary: In the study of BM-SCO and HSCO thin films, it was found that H vacancies tend to prefer sites near the external surface or oxygen vacancy channels (OVCs), while H interstitials prefer sites of oxygen on a layer that contains six-fold coordinated Co. These findings not only enrich the understanding of complex surface phenomena of defect formation but also provide an explanation for the reversibility during phase transformation.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Jiafeng Lu, Linping Teng, Qinxiao Zhai, Chunhua Wang, Matthieu Lancry, Ye Dai, Xianglong Zeng
Summary: In this study, we achieved full control of fiber nanograting orientation by manipulating laser polarization, and tailored space variant fiber nanogratings, which expanded the diversity in fiber nanograting engineering.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Yibo Liu, Yujie Tao, Yue Liu, Qi Sun, Qinrong Lin, Kexin Kang, Qinghua Zhang, Qingjie Sun
Summary: This study investigates the wettability of the Ti-Cu-Fe multi-metal system, specifically the wetting behaviors of CuSi3 droplets on TC4 and 304SS plates. The results show that the CO2 + Ar gas atmosphere significantly affects interfacial mass transfer, thus influencing the wettability of the systems.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Jimei Liu, Fei Wang, Rong Guo, Yuqi Liu, Mengyu Zhang, Jaka Sunarso, Dong Liu
Summary: This study developed Co/MXene composites with anti-corrosion properties by varying the cobalt content. These composites exhibited remarkable electromagnetic absorption performance and high resistance to corrosion under various corrosive conditions. The study also revealed the mechanism of electron transfer from cobalt to MXene and the electromagnetic dissipation behavior originated from polarization loss alone.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Moujie Huang, Yongsong Ma, Jingbo Yang, Lingyun Xu, Hangqi Yang, Miao Wang, Xin Ma, Xin Xia, Junhao Yang, Deli Wang, Chuang Peng
Summary: Strong metal-support interactions (SMSIs) are important for enhancing catalytic activities and stability in thermal catalysis. This study demonstrates a method to create SMSIs in electrocatalysis using carbon nanotubes and Ru nanoparticles, resulting in excellent catalytic activity and stability.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Ravi Trivedi, Brinti Mondal, Nandini Garg, Brahmananda Chakraborty
Summary: This study explores the potential of biphenylene as a nanocarrier for the delivery of the anticancer drug cisplatin. It is found that biphenylene offers physical stability, rapid release rate, solubility, and bio-compatibilities compared to other nanocarriers. The adsorption of cisplatin on the surface of biphenylene involves charge transfer from cisplatin to biphenylene. The drug is shown to be released at body temperature in an acidic environment. Biphenylene also exhibits excellent cytotoxicity activity and cellular uptake of the drug. Overall, biphenylene shows promise as a potential nanocarrier for cisplatin delivery.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Hyun Jeong, Hyeong Chan Suh, Ga Hyun Cho, Rafael Salas-Montiel, Hayoung Ko, Ki Kang Kim, Mun Seok Jeong
Summary: In this study, a potential platform to enhance Raman scattering and increase the number of observable Raman modes in monolayer transition metal dichalcogenides (TMDs) was proposed. The platform consisted of large-scale arrays of gold micropillars (MPs), which were able to enhance the Raman intensity of TMDs and make difficult-to-detect Raman modes observable. The platform showed great industrial advantages and wide applicability due to its low cost, simple process, large controllable area, and short process time.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Yasir Abbas, Shafqat Ali, Sajjad Ali, Waqar Azeem, Zareen Zuhra, Haoliang Wang, Mohamed Bououdina, Zhenzhong Sun
Summary: In this study, FeOx@SPNO-C core-shell nanospheres as a catalyst for degradation of sulfamethoxazole (SMX) were successfully synthesized. The synergistic interaction between FeOx and SPNO-C, high carbon charge density, and the presence of C = O groups and N/Fe-Nx sites were found to be key factors for the enhanced degradation of SMX.
APPLIED SURFACE SCIENCE
(2024)
Article
Chemistry, Physical
Qiaoting Yang, Yuxiao Gong, Yan Qian, Zhou-Qing Xiao, Serge Cosnier, Xue-Ji Zhang, Robert S. Marks, Dan Shan
Summary: This study proposes a hierarchical confinement strategy to design Prussian blue nanoparticles (PB NPs) with satisfactory electrocatalytic ability and stability. The catalytic synthesis of PB NPs is achieved through a hydrothermal process, and the as-prepared PB@NH2MIL exhibits efficient electronic transmission and enhanced electrocatalytic properties.
APPLIED SURFACE SCIENCE
(2024)