Review
Chemistry, Multidisciplinary
Man-Bo Li, Jan-E Backvall
Summary: Palladium-catalyzed oxidations involving cascade processes have challenges in achieving high palladium efficiency and selectivity, but using heterogeneous palladium catalysts immobilized on amino-functionalized support materials has shown promising results in addressing these issues. The catalysts exhibit high activity, selectivity, and efficient recycling ability, and have been applied in various oxidative cascade reactions to access important compounds for medicinal chemistry and functional materials.
ACCOUNTS OF CHEMICAL RESEARCH
(2021)
Article
Chemistry, Multidisciplinary
Dongsheng Zhang, Ren Su
Summary: Heterogeneous photocatalysis is a promising method for hydrogenative reactions due to its mild reaction conditions and the use of liquid hydrogen donors. The current focus is on developing high-performance photocatalyst materials and expanding the range of reactions. However, there is a lack of overview on the mechanistic understanding of light-induced hydrogenative reactions from the perspective of hydrogen donors. In this study, we categorized photocatalytic hydrogenative reactions based on the type of liquid hydrogen donors (hydrocarbons and water), discussed the criteria for hydrogen abstraction from these donors, and elaborated on the design strategy of photocatalyst materials.
CHEMISTRY-A EUROPEAN JOURNAL
(2023)
Article
Chemistry, Analytical
Jun Wang, Yuhan Pan, Jiaxing Song, Qunxing Huang
Summary: This article introduces an innovative method to convert waste plastic into high-purity hydrogen through microwave-induced reactions and also generate high-value carbon nanotubes.
JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS
(2022)
Article
Energy & Fuels
Harsh Dadhania, Dipak Raval, Abhishek Dadhania
Summary: The study synthesized a magnetically separable ionic liquid catalyst and evaluated its catalytic activity in biodiesel production by assessing the impact of different experimental parameters. The research also explored the effects of various alcohols and fatty acids on the esterification reaction. Additionally, the catalyst showed good reusability by being able to be used for up to six reaction cycles.
Article
Chemistry, Multidisciplinary
Hassan Keypour, Jamal Kouhdareh, Rahman Karimi-Nami, Idris Karakaya, Molood Abdollahi-Moghadam, Khadijeh Rabiei, Sedigheh Alavinia
Summary: This study presents the development and application of an environmentally compatible and recyclable heterogeneous catalyst for C-C coupling reactions. The catalyst demonstrated excellent catalytic performance with high yields of up to 98%. The synthetic method showed advantages such as simple set-up, improved yields, short reaction times, non-toxic solvents, catalyst durability, and high turnover frequency.
Article
Chemistry, Multidisciplinary
Fatemeh Pakpour, Elham Safaei, S. Mohammad Azami, Andrzej Wojtczak, Karolina Kaldunska
Summary: A novel mononuclear palladium complex with a non-innocent ligand was synthesized and characterized. The complex exhibited strong absorptions in the NIR region and showed high catalytic activity for C-C coupling reactions and the Suzuki reaction. It demonstrated interesting applications of redox non-innocent ligands and acted as an electron reservoir without requiring additional reagents.
Article
Chemistry, Physical
Xuan Zhang, Yanqin Xue, Xianzhi Yin, Lian Shen, Kai Zhu, Xiaomei Huang, Dianxue Cao, Jiaxin Yao, Guiling Wang, Qing Yan
Summary: This study successfully fabricated Mn oxides-Fe-Ni sulfide composite materials as HER electrodes in alkaline media using a two-step hydrothermal process. The electrode shows low working potential and good stability.
JOURNAL OF POWER SOURCES
(2022)
Article
Chemistry, Inorganic & Nuclear
Nadia Fattahi, Muhammad Kashif, Ali Ramazani
Summary: The Cs2CO3 functionalized Fe3O4@SiO2 magnetic nanoparticle proved to be a highly efficient, magnetically separable, recyclable, and green heterogeneous catalyst. Various analyses, including XRD, FT-IR, EDX, SEM, TEM, and VSM, were used to characterize the nanocatalyst. The catalyst showed good performance in the aldol reaction of acetone with different aldehydes in water. The use of simple and mild reaction conditions, short reaction time, green and safe solvent, high catalytic performance, easy purification, and simple magnetically work-up make this approach an interesting and effective option in the aldol reaction.
INORGANIC CHEMISTRY COMMUNICATIONS
(2023)
Review
Chemistry, Multidisciplinary
Ana Sousa-Castillo, Andrea Marino-Lopez, Begona Puertolas, Miguel A. Correa-Duarte
Summary: Bioorthogonal chemistry has provided a powerful tool for performing biocompatible chemospecific reactions in living systems, particularly in the areas of genetic encoding systems, bioimaging, and cancer therapy. This Minireview focuses on recent advances in the use of heterogeneous catalysts for bioorthogonal reactions, discussing the synthetic strategies of Pd-, Au-, and Cu-based materials, their applications in activating caged fluorophores and prodrugs, and the potential of using external stimuli for targeted drug release in diseased tissues. The review also highlights future directions and challenges in this emerging field.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2023)
Article
Chemistry, Multidisciplinary
S. Fatemeh Mohammadi Metkazini, Akbar Heydari
Summary: In this study, a novel nanocatalyst with a bifunctional ligand was successfully prepared, showing excellent efficiency in Aldol and aza-Michael reactions under green and mild reaction conditions. The introduced catalytic system was also successfully applied in the large-scale synthesis of derivatives of dihydroquinolines, offering advantages such as simple work-up, high yield, and short reaction times.
Article
Chemistry, Multidisciplinary
Safoora Sheikh, Mohammad Ali Nasseri, Mohammad Chahkandi, Oliver Reiser, Ali Allahresani
Summary: A recyclable nanomagnetic catalyst PAMAM G(0)-Pd@gamma-Fe2O3 is reported for catalytic C-C cross-coupling reactions of challenging substrates. The catalyst exhibits good solubility and catalytic activity for a variety of aryl chloride substrates under mild reaction conditions in aqueous media. The immobilization of the catalyst on a magnetic platform allows for effective recovery and reuse.
Article
Chemistry, Inorganic & Nuclear
Manuel R. Rodriguez, Francisco Molina, Pablo Etayo, Miquel A. Pericas, Pedro J. Perez, M. Mar Diaz-Requejo
Summary: Efficient olefin aziridination was achieved using a tris(triazolyl)methane copper catalyst supported onto polystyrene, producing N-tosylaziridines in good yields. The solid catalyst can be easily separated and recycled with no significant loss of catalytic activity.
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
(2021)
Article
Chemistry, Analytical
Yongcheng Dai, Kexin Zhang, Xiaohan Yuan, Xiaobo Xie, Zixuan Zhan, Yi Lv
Summary: A novel iridium-based chemiluminescence probe (NIRIr-CL-1) with direct near-infrared (NIR) emission was reported, which was achieved through hypochlorous acid-initiated oxidative deoximation. To improve its biocompatibility and extend the imaging time, NIRIr-CL-1 was prepared as a nanoparticle probe (NIRIr-CL-1 dots) encapsulated in an amphiphilic polymer Pluronic F127. The results demonstrated that NIRIr-CL-1 dots showed good selectivity and sensitivity for visualizing hypochlorous acid even at a depth of 1.2 cm. The imaging of exogenous and endogenous hypochlorous acid in mice was successfully achieved, suggesting potential applications in biomedical imaging.
ANALYTICAL CHEMISTRY
(2023)
Article
Chemistry, Multidisciplinary
Mahdieh Ghabdian, Mohammad Ali Nasseri, Ali Allahresani, Alireza Motavallizadehkakhky
Summary: A Pd(II) Schiff base complex supported on graphene oxide nanosheets (Pd(II) salen@CPGO) has been synthesized and characterized, showing excellent catalytic efficiency for Suzuki-Miyaura and Heck-Mizoroki coupling reactions. The solid sheet-supported Pd catalyst can be easily separated and recycled multiple times without significant loss of catalytic activity, making it a promising system for heterogeneous catalytic reactions.
RESEARCH ON CHEMICAL INTERMEDIATES
(2021)
Article
Chemistry, Multidisciplinary
Masoomeh Norouzi, Nasim Noormoradi, Masoud Mohammadi
Summary: A novel nanomagnetic tetra-azamacrocyclic Schiff base complex of copper(II) was obtained via a post-synthetic surface modification, and it showed excellent catalytic properties and recyclability.
NANOSCALE ADVANCES
(2023)
Article
Chemistry, Applied
M. Afradi, N. Foroughifar, H. Pasdar, H. Moghanian, N. Foroughifar
APPLIED ORGANOMETALLIC CHEMISTRY
(2017)
Article
Polymer Science
Akbar Mobinikhaledi, Hassan Moghanian, Parvin Safari, Elnaz Firuzian
JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS
(2018)
Article
Chemistry, Applied
Akbar Mobinikhaledi, Hassan Moghanian, Seyed Mohammad Bagher Hosseini Ghazvini, Azam Dalvand
JOURNAL OF POROUS MATERIALS
(2018)
Article
Polymer Science
Khalil Faghihi, Hassan Moghanian, Fatemeh Mozafari, Meisam Shabanian
CHINESE JOURNAL OF POLYMER SCIENCE
(2018)
Article
Polymer Science
Zahra Mobaraki, Hassan Moghanian, Khalil Faghihi, Meisam Shabanian
JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS
(2018)
Article
Polymer Science
Shirin Faridi, Hassan Moghanian, Meisam Shabanian
Article
Chemistry, Multidisciplinary
Hassan Moghanian, Mohammad Ali Bodaghi Fard, Akbar Mobinikhaledi, Najmieh Ahadi
RESEARCH ON CHEMICAL INTERMEDIATES
(2018)
Article
Spectroscopy
Seyed Mohammad Bagher Hosseini Ghazvini, Parvin Safari, Akbar Mobinikhaledi, Hassan Moghanian, Hassan Rasouli
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
(2018)
Article
Materials Science, Composites
Hassan Moghanian, Akbar Mobinikhaledi, Fatemeh Hossein-Abadi, Shirin Faridi
Summary: The new magnetic and heat-resistant nanocomposites of polyamide ether (PAE)/graphene oxide (GO) were successfully prepared by blending PAE with modified GO. The incorporation of bulky aryl pendant groups and flexible ether linkage into the backbones of polyamide enhanced the solubility. Additionally, GO was modified with tetraethylenepentamine (GO-TEPA) and magnetized with Fe(3)O(4) nanoparticles to obtain GO-TEPA@Fe3O4 nanocomposites. The synthesized PAE/GO-TEPA@Fe3O4 films exhibited high heat resistance and superparamagnetic properties.
JOURNAL OF THERMOPLASTIC COMPOSITE MATERIALS
(2022)
Article
Chemistry, Multidisciplinary
Razieh Rahimizadeh, Akbar Mobinikhaledi, Hassan Moghanian, Seyedeh Sara Kashaninejad
Summary: The functionalized silica-coated Fe3O4 nanoparticles Fe3O4@SiO2-TETA-SO3H were synthesized by stabilizing the sulfonic group on the surface. The nanoparticles exhibited excellent catalytic activity for the synthesis of amidoalkyl naphthols using fatty acids as resources, with high yields and easy work-up. Additionally, the synthesized products showed biological activity against Staphylococcus aureus and Escherichia coli.
RESEARCH ON CHEMICAL INTERMEDIATES
(2022)
Article
Chemistry, Multidisciplinary
Mehdi Kalhor, Mansour Bigdeli, Hassan Moghanian
Summary: In this research, an ionic liquid grafted on nanoporous Ni/zeolite-Y was prepared and a multi-functional and magnetically responsive nanosystem was developed. The nanosystem showed excellent catalytic performance in the synthesis of 4-arylidene-2-phenyl-5(4H) oxazolones, with the advantages of easy separation, high yields, fast reaction rate, recyclability, low cost, and non-toxicity.
RESEARCH ON CHEMICAL INTERMEDIATES
(2023)
Article
Multidisciplinary Sciences
Shirin Faridi, Akbar Mobinikhaledi, Hassan Moghanian, Meisam Shabanian
Summary: This study focuses on the synthesis and characterization of three water-soluble copolymers with potential for separating minerals in water-based drilling fluids. The high molecular weight copolymers were found to offer better thermal stability and flocculation characteristics.
SCIENTIFIC REPORTS
(2023)
Article
Chemistry, Multidisciplinary
Shirin Faridi, Akbar Mobinikhaledi, Hassan Moghanian, Meisam Shabanian
Summary: This study investigated the treatment of water-based drilling fluid using modified acrylamide copolymers as flocculants, aiming to improve drilling performance and reduce environmental contamination. The prepared copolymers were characterized in terms of their chemical structure, thermal stability, and interaction with clay particles. The results showed that the anionic copolymer with the highest molecular weight exhibited the best performance as a coagulant. Other factors such as molecular chain were also found to affect the interaction between the copolymers and clay particles.
Article
Chemistry, Applied
Akbar Mobinikhaledi, Hassan Moghanian, Masoumeh Ghanbari
APPLIED ORGANOMETALLIC CHEMISTRY
(2018)
