Journal
APPLIED CATALYSIS A-GENERAL
Volume 590, Issue -, Pages -Publisher
ELSEVIER
DOI: 10.1016/j.apcata.2019.117339
Keywords
Ceria-praseodymia; NO oxidation; Soot combustion; Active oxygen
Categories
Funding
- Generalitat Valenciana [PROMETEO/2018/076]
- Spanish Ministry of Economy and Competitiveness [CTQ2015-64801-R]
- UE-FEDER funding
- Spanish Ministry of Science, Innovation and Universities through a FPU grant [FPU17/00603]
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The effect of Ce/Pr ratio on ceria-praseodymia on structural and surface properties is studied. The catalytic activity towards soot combustion under NOx/O-2 and O-2/N-2 atmospheres is also evaluated, together with the NO oxidation activity to NO2. CexPr1-xO2-delta compositions (x = 0.8, 0.5 and 0.2) have been prepared along with ceria and praseodymia. Catalysts were prepared by co-precipitation. The Ce0.5Pr0.5O2-delta composition, was also prepared by nitrate calcination. Ceria-praseodymia mixed oxides yield reduction profiles shifted to lower temperatures, higher NO oxidation activities to NO2 and improved catalytic activities for soot combustion with respect to pure ceria. Ce0.5Pr0.5O2-delta was the most active one. Under NOx/O-2, it has greater soot combustion activity if it is prepared by nitrate calcination. However, under O-2/N-2, the co-precipitation method is more favorable because of the better dopant insertion achieved in the ceria lattice, which seems to lead better oxygen mobility on the surface and in the bulk oxide.
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