Catalysis of a Single Transition Metal Site for Water Oxidation: From Mononuclear Molecules to Single Atoms

Engineering an Earth-Abundant Element-Based Bifunctional Electrocatalyst for Highly Efficient and Durable Overall Water Splitting

(2019) Zhuo Kang et al.   ADVANCED FUNCTIONAL MATERIALS

Cascade anchoring strategy for general mass production of high-loading single-atomic metal-nitrogen catalysts

(2019) Lu Zhao et al.   Nature Communications

Seven Coordinated Molecular Ruthenium–Water Oxidation Catalysts: A Coordination Chemistry Journey

(2019) Roc Matheu et al.   CHEMICAL REVIEWS

Framework‐Porphyrin‐Derived Single‐Atom Bifunctional Oxygen Electrocatalysts and their Applications in Zn–Air Batteries

(2019) Bo‐Quan Li et al.   ADVANCED MATERIALS

Support and Interface Effects in Water-Splitting Electrocatalysts

(2019) Jian Zhang et al.   ADVANCED MATERIALS

Transition-Metal-Doped RuIr Bifunctional Nanocrystals for Overall Water Splitting in Acidic Environments

(2019) Jieqiong Shan et al.   ADVANCED MATERIALS

Elaborately Modified BiVO4 Photoanodes for Solar Water Splitting

(2019) Jin Hyun Kim et al.   ADVANCED MATERIALS

Structure Effects of Metal Corroles on Energy-Related Small Molecule Activation Reactions

(2019) Haitao Lei et al.   ACS Catalysis

The development of molecular water oxidation catalysts

(2019) Roc Matheu et al.   Nature Reviews Chemistry

Nanoparticle Characterization: What to Measure?

(2019) Mario M. Modena et al.   ADVANCED MATERIALS

Atomically Dispersed Transition Metals on Carbon Nanotubes with Ultrahigh Loading for Selective Electrochemical Carbon Dioxide Reduction

(2018) Yi Cheng et al.   ADVANCED MATERIALS

Iron Vacancies Induced Bifunctionality in Ultrathin Feroxyhyte Nanosheets for Overall Water Splitting

(2018) Bin Liu et al.   ADVANCED MATERIALS

A Durable Nickel Single-Atom Catalyst for Hydrogenation Reactions and Cellulose Valorization under Harsh Conditions

(2018) Wengang Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Bimetallic Zn/Fe Polyphthalocyanine-Derived Single-Atom Fe-N4 Catalytic Site:A Superior Trifunctional Catalyst for Overall Water Splitting and Zn-Air Batteries

(2018) Yuan Pan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Mimicking Natural Photosynthesis: Solar to Renewable H2 Fuel Synthesis by Z-Scheme Water Splitting Systems

(2018) Yiou Wang et al.   CHEMICAL REVIEWS

Photoelectrochemical Performance for Water Oxidation Improved by Molecular Nickel Porphyrin-Integrated WO3 /TiO2 Photoanode

(2018) Peicheng Wei et al.   ChemSusChem

Immobilization of an Amphiphilic Molecular Cobalt Catalyst on Carbon Black for Ligand-Assisted Water Oxidation

(2018) Habib Baydoun et al.   INORGANIC CHEMISTRY

Rate-Limiting O–O Bond Formation Pathways for Water Oxidation on Hematite Photoanode

(2018) Yuchao Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mimicking the Key Functions of Photosystem II in Artificial Photosynthesis for Photoelectrocatalytic Water Splitting

(2018) Sheng Ye et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Sub-3 nm Ultrafine Monolayer Layered Double Hydroxide Nanosheets for Electrochemical Water Oxidation

(2018) Yufei Zhao et al.   Advanced Energy Materials

Understanding the activity and selectivity of single atom catalysts for hydrogen and oxygen evolution via ab initial study

(2018) Guoping Gao et al.   Catalysis Science & Technology

Molecular cobalt salophen catalyst-integrated BiVO4 as stable and robust photoanodes for photoelectrochemical water splitting

(2018) Yidan Liu et al.   Journal of Materials Chemistry A

Transition metal anchored C2N monolayers as efficient bifunctional electrocatalysts for hydrogen and oxygen evolution reactions

(2018) Xu Zhang et al.   Journal of Materials Chemistry A

Synergistic effect of an atomically dual-metal doped catalyst for highly efficient oxygen evolution

(2018) Daobin Liu et al.   Journal of Materials Chemistry A

Single-Atom Catalysts for Electrochemical Water Splitting

(2018) Chengzhou Zhu et al.   ACS Energy Letters

Graphene Defects Trap Atomic Ni Species for Hydrogen and Oxygen Evolution Reactions

(2018) Longzhou Zhang et al.   Chem

Low-dimensional catalysts for hydrogen evolution and CO2 reduction

(2018) Damien Voiry et al.   Nature Reviews Chemistry

Heterogeneous single-atom catalysis

(2018) Aiqin Wang et al.   Nature Reviews Chemistry

Carbon-Supported Single Atom Catalysts for Electrochemical Energy Conversion and Storage

(2018) Yi Peng et al.   ADVANCED MATERIALS

Molecular Engineering of Carbon Nanotubes with Cobalt Corroles for Hydrogen and Oxygen Evolution in pH 0−14 Solutions

(2018) Xialiang Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Interfacing nature’s catalytic machinery with synthetic materials for semi-artificial photosynthesis

(2018) Nikolay Kornienko et al.   Nature Nanotechnology

Convenient Immobilization of Cobalt Corroles on Carbon Nanotubes through Covalent Bonds for Electrocatalytic Hydrogen and Oxygen Evolution Reactions

(2018) Hua Li et al.   ChemSusChem

Ligand Substituent Effects in Manganese Pyridinophane Complexes: Implications for Oxygen-Evolving Catalysis

(2017) Song Xu et al.   INORGANIC CHEMISTRY

Intramolecular Oxyl Radical Coupling Promotes O–O Bond Formation in a Homogeneous Mononuclear Mn-based Water Oxidation Catalyst: A Computational Mechanistic Investigation

(2017) Douglas W. Crandell et al.   INORGANIC CHEMISTRY

Electrocatalytic Water Oxidation by a Water-Soluble Copper(II) Complex with a Copper-Bound Carbonate Group Acting as a Potential Proton Shuttle

(2017) Fangfang Chen et al.   INORGANIC CHEMISTRY

Electronic π-Delocalization Boosts Catalytic Water Oxidation by Cu(II) Molecular Catalysts Heterogenized on Graphene Sheets

(2017) Pablo Garrido-Barros et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Heterogeneous Electrocatalyst with Molecular Cobalt Ions Serving as the Center of Active Sites

(2017) Jiong Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Hollow N-Doped Carbon Spheres with Isolated Cobalt Single Atomic Sites: Superior Electrocatalysts for Oxygen Reduction

(2017) Yunhu Han et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Discriminating Catalytically Active FeNx Species of Atomically Dispersed Fe–N–C Catalyst for Selective Oxidation of the C–H Bond

(2017) Wengang Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

{Co4O4} and {CoxNi4–xO4} Cubane Water Oxidation Catalysts as Surface Cut-Outs of Cobalt Oxides

(2017) Fangyuan Song et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Molecule-Level g-C3N4 Coordinated Transition Metals as a New Class of Electrocatalysts for Oxygen Electrode Reactions

(2017) Yao Zheng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Earth-abundant catalysts for electrochemical and photoelectrochemical water splitting

(2017) Isolda Roger et al.   Nature Reviews Chemistry

Visible-light-absorbing semiconductor/molecular catalyst hybrid photoelectrodes for H2 or O2 evolution: recent advances and challenges

(2017) Mei Wang et al.   Sustainable Energy & Fuels

Catalysis by Design: Well-Defined Single-Site Heterogeneous Catalysts

(2016) Jérémie D. A. Pelletier et al.   ACCOUNTS OF CHEMICAL RESEARCH

Improved Photoelectrocatalytic Performance for Water Oxidation by Earth-Abundant Cobalt Molecular Porphyrin Complex-Integrated BiVO4 Photoanode

(2016) Bin Liu et al.   ACS Applied Materials & Interfaces

Heterogeneous Molecular Systems for Photocatalytic CO2Reduction with Water Oxidation

(2016) Xiao Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Bifunctional Electrocatalyst for Oxygen Evolution and Oxygen Reduction Reactions in Water

(2016) Wolfgang Schöfberger et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Atomically Dispersed Iron-Nitrogen Species as Electrocatalysts for Bifunctional Oxygen Evolution and Reduction Reactions

(2016) Pengzuo Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Graphitic carbon nitride supported single-atom catalysts for efficient oxygen evolution reaction

(2016) Xiyu Li et al.   CHEMICAL COMMUNICATIONS

Surface Organometallic and Coordination Chemistry toward Single-Site Heterogeneous Catalysts: Strategies, Methods, Structures, and Activities

(2016) Christophe Copéret et al.   CHEMICAL REVIEWS

Comparison of heterogenized molecular and heterogeneous oxide catalysts for photoelectrochemical water oxidation

(2016) Wei Li et al.   Energy & Environmental Science

Driving the Oxygen Evolution Reaction by Nonlinear Cooperativity in Bimetallic Coordination Catalysts

(2016) Benjamin Wurster et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Intermediate identification

(2016) Alexander J. Cowan   Nature Chemistry

Visible light-driven water oxidation using a covalently-linked molecular catalyst–sensitizer dyad assembled on a TiO2 electrode

(2016) Masanori Yamamoto et al.   Chemical Science

Single-atom dispersed Co–N–C catalyst: structure identification and performance for hydrogenative coupling of nitroarenes

(2016) Wengang Liu et al.   Chemical Science

Tuning selectivity of electrochemical reactions by atomically dispersed platinum catalyst

(2016) Chang Hyuck Choi et al.   Nature Communications

Noncovalent Immobilization of a Pyrene-Modified Cobalt Corrole on Carbon Supports for Enhanced Electrocatalytic Oxygen Reduction and Oxygen Evolution in Aqueous Solutions

(2016) Haitao Lei et al.   ACS Catalysis

Reinvestigation of Water Oxidation Catalyzed by a Dinuclear Cobalt Polypyridine Complex: Identification of CoOx as a Real Heterogeneous Catalyst

(2016) Jia-Wei Wang et al.   ACS Catalysis

Photoanode-immobilized molecular cobalt-based oxygen-evolving complexes with enhanced solar-to-fuel efficiency

(2016) Zhaoyu Jin et al.   Journal of Materials Chemistry A

Elongated Silicon–Carbon Bonds at Graphene Edges

(2015) Qu Chen et al.   ACS Nano

Immobilization of a molecular cobalt electrocatalyst by hydrophobic interaction with a hematite photoanode for highly stable oxygen evolution

(2015) Khurram S. Joya et al.   CHEMICAL COMMUNICATIONS

Water oxidation catalysed by a mononuclear CoII polypyridine complex; possible reaction intermediates and the role of the chloride ligand

(2015) Biswanath Das et al.   CHEMICAL COMMUNICATIONS

Molecular Catalysts for Water Oxidation

(2015) James D. Blakemore et al.   CHEMICAL REVIEWS

Covalent Cobalt Porphyrin Framework on Multiwalled Carbon Nanotubes for Efficient Water Oxidation at Low Overpotential

(2015) Hongxing Jia et al.   CHEMISTRY OF MATERIALS

Improving Singlet Oxygen Resistance during Photochemical Water Oxidation by Cobalt Porphyrin Catalysts

(2015) Takashi Nakazono et al.   CHEMISTRY-A EUROPEAN JOURNAL

Electrocatalytic Water Oxidation by a Water-Soluble Nickel Porphyrin Complex at Neutral pH with Low Overpotential

(2015) Yongzhen Han et al.   INORGANIC CHEMISTRY

Structure–Function Relationships for Electrocatalytic Water Oxidation by Molecular [Mn12O12] Clusters

(2015) Yong Yan et al.   INORGANIC CHEMISTRY

Graphite-Conjugated Pyrazines as Molecularly Tunable Heterogeneous Electrocatalysts

(2015) Tomohiro Fukushima et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Gold and silver anchored cobalt porphyrins used for catalytic water splitting

(2015) Miguel A. Morales Vásquez et al.   MATERIALS CHEMISTRY AND PHYSICS

A synthetic Mn4Ca-cluster mimicking the oxygen-evolving center of photosynthesis

(2015) C. Zhang et al.   SCIENCE

Water oxidation catalysed by iron complex of N,N′-dimethyl-2,11-diaza[3,3](2,6)pyridinophane. Spectroscopy of iron–oxo intermediates and density functional theory calculations

(2015) Wai-Pong To et al.   Chemical Science

A biosynthetic model of cytochrome c oxidase as an electrocatalyst for oxygen reduction

(2015) Sohini Mukherjee et al.   Nature Communications

Phase and composition controllable synthesis of cobalt manganese spinel nanoparticles towards efficient oxygen electrocatalysis

(2015) Chun Li et al.   Nature Communications

Co–N–C Catalyst for C–C Coupling Reactions: On the Catalytic Performance and Active Sites

(2015) Leilei Zhang et al.   ACS Catalysis

Photocatalytic Water Oxidation by a Mixed-Valent MnIII3MnIVO3Manganese Oxo Core that Mimics the Natural Oxygen-Evolving Center

(2014) Rami Al-Oweini et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ligand Modification Transforms a Catalase Mimic into a Water Oxidation Catalyst

(2014) Wei-Tsung Lee et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Artificial Photosynthesis: Molecular Systems for Catalytic Water Oxidation

(2014) Markus D. Kärkäs et al.   CHEMICAL REVIEWS

Spectroscopic and electrochemical studies of high-valent water soluble manganese porphyrine. Electrocatalytic water oxidation

(2014) Maria Alejandra Luna et al.   ELECTROCHIMICA ACTA

How to Chemically Tailor Metal-Porphyrin-Like Active Sites on Carbon Nanotubes and Graphene for Minimal Overpotential in the Electrochemical Oxygen Evolution and Oxygen Reduction Reactions

(2014) Mu-Jeng Cheng et al.   Journal of Physical Chemistry C

Anchoring a Molecular Iron Catalyst to Solar-Responsive WO3 Improves the Rate and Selectivity of Photoelectrochemical Water Oxidation

(2014) Benjamin M. Klepser et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Homogeneous Photochemical Water Oxidation by Biuret-Modified Fe-TAML: Evidence of FeV(O) Intermediate

(2014) Chakadola Panda et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Single-Atom Catalysts: A New Frontier in Heterogeneous Catalysis

(2013) Xiao-Feng Yang et al.   ACCOUNTS OF CHEMICAL RESEARCH

Chemical and Visible-Light-Driven Water Oxidation by Iron Complexes at pH 7-9: Evidence for Dual-Active Intermediates in Iron-Catalyzed Water Oxidation

(2013) Gui Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cobalt porphyrins as homogeneous catalysts for water oxidation

(2013) Takashi Nakazono et al.   CHEMICAL COMMUNICATIONS

Light driven water oxidation by a single site cobalt salophen catalyst

(2013) Erica Pizzolato et al.   CHEMICAL COMMUNICATIONS

Photocatalytic water oxidation by very small cobalt domains on a silica surface

(2013) Hyun S. Ahn et al.   Energy & Environmental Science

Effects of structures of pyrolyzed corrin, corrole and porphyrin on oxygen reduction reaction

(2013) Sun-Tang Chang et al.   INTERNATIONAL JOURNAL OF HYDROGEN ENERGY

Differentiating Homogeneous and Heterogeneous Water Oxidation Catalysis: Confirmation that [Co4(H2O)2(α-PW9O34)2]10– Is a Molecular Water Oxidation Catalyst

(2013) James W. Vickers et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Analysis of Porphyrines as Catalysts for Electrochemical Reduction of O2 and Oxidation of H2O

(2013) Jakub D. Baran et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Water Oxidation Catalysis Beginning with 2.5 μM [Co4(H2O)2(PW9O34)2]10–: Investigation of the True Electrochemically Driven Catalyst at ≥600 mV Overpotential at a Glassy Carbon Electrode

(2013) Jordan J. Stracke et al.   ACS Catalysis

One-pot synthesis of a mesoporous NiCo2O4 nanoplatelet and graphene hybrid and its oxygen reduction and evolution activities as an efficient bi-functional electrocatalyst

(2013) Dong Un Lee et al.   Journal of Materials Chemistry A

Pyrolyzed Cobalt Corrole as a Potential Non-Precious Catalyst for Fuel Cells

(2012) Hsin-Chih Huang et al.   ADVANCED FUNCTIONAL MATERIALS

Mononuclear Water Oxidation Catalysts

(2012) Dennis G. H. Hetterscheid et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Homogeneous water oxidation catalysts containing a single metal site

(2012) Derek J. Wasylenko et al.   CHEMICAL COMMUNICATIONS

Why Is Cobalt the Best Transition Metal in Transition-Metal Hangman Corroles for O–O Bond Formation during Water Oxidation?

(2012) Wenzhen Lai et al.   Journal of Physical Chemistry Letters

Highly Efficient Oxidation of Water by a Molecular Catalyst Immobilized on Carbon Nanotubes

(2011) Fei Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Visible light-driven water oxidation—from molecular catalysts to photoelectrochemical cells

(2011) Lele Duan et al.   Energy & Environmental Science

Electrocatalytic Water Oxidation Beginning with the Cobalt Polyoxometalate [Co4(H2O)2(PW9O34)2]10–: Identification of Heterogeneous CoOxas the Dominant Catalyst

(2011) Jordan J. Stracke et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Electocatalytic Water Oxidation by Cobalt(III) Hangman β-Octafluoro Corroles

(2011) Dilek K. Dogutan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Crystal structure of oxygen-evolving photosystem II at a resolution of 1.9 Å

(2011) Yasufumi Umena et al.   NATURE

Efficient water oxidation catalysts based on readily available iron coordination complexes

(2011) Julio Lloret Fillol et al.   Nature Chemistry

Single-atom catalysis of CO oxidation using Pt1/FeO x

(2011) Botao Qiao et al.   Nature Chemistry

Fast Water Oxidation Using Iron

(2010) W. Chadwick Ellis et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Development of Bioinspired Mn4O4−Cubane Water Oxidation Catalysts: Lessons from Photosynthesis

(2009) G. Charles Dismukes et al.   ACCOUNTS OF CHEMICAL RESEARCH

Nucleophilic Attack of Hydroxide on a MnVOxo Complex: A Model of the O−O Bond Formation in the Oxygen Evolving Complex of Photosystem II

(2009) Yan Gao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanisms of Water Oxidation from the Blue Dimer to Photosystem II

(2008) Feng Liu et al.   INORGANIC CHEMISTRY

Covalent Heterogenization of a Discrete Mn(II) Bis-Phen Complex by a Metal-Template/Metal-Exchange Method:  An Epoxidation Catalyst with Enhanced Reactivity

(2008) Tracy J. Terry et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cyclometalated Iridium(III) Aquo Complexes:  Efficient and Tunable Catalysts for the Homogeneous Oxidation of Water

(2007) Neal D. McDaniel et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY