Journal
ACS APPLIED MATERIALS & INTERFACES
Volume 12, Issue 1, Pages 609-618Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acsami.9b16913
Keywords
cobalt-salen; porous ionic polymer; CO2 conversion; valence; nucleophilicity
Funding
- American Chemical Society Petroleum Research Fund [55570-DNI10]
- NSF [CBET-1603264]
- Jiangsu Provincial Science Foundation for Youths [BK20160976]
- SICAM Fellowship by Jiangsu National Synergetic Innovation Center for Advanced Materials
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Cobalt-salen-based porous ionic polymers, which are composed of cobalt and halogen anions decorated on the framework, effectively catalyze the CO2 cycloaddition reaction of epoxides to cyclic carbonates under ambient conditions. The cooperative effect of bifunctional active sites of cobalt as the Lewis acidic site and the halogen anion as the nucleophile responds to the high catalytic performance. Moreover, density functional theory results indicate that the cobalt valence state and the corresponding coordination group influence the rate-determining step of the CO2 cycloaddition reaction and the nucleophilicity of halogen anions.
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