Control of metal-support interactions in heterogeneous catalysts to enhance activity and selectivity

Wet-Chemistry Strong Metal–Support Interactions in Titania-Supported Au Catalysts

(2019) Jian Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The Concept of “Noble, Heteroatom-Doped Carbons,” Their Directed Synthesis by Electronic Band Control of Carbonization, and Applications in Catalysis and Energy Materials

(2018) Markus Antonietti et al.   ADVANCED MATERIALS

Template- and Metal-free Synthesis of Nitrogen-rich Nanoporous Noble Carbon Materials by Direct Pyrolysis of a Preorganized Hexaazatriphenylene Precursor

(2018) Ralf Walczak et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Reconstruction of Supported Metal Nanoparticles in Reaction Conditions

(2018) Manyi Duan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A sinter resistant Co Fischer-Tropsch catalyst promoted with Ru and supported on titania encapsulated by mesoporous silica

(2018) Tumelo N. Phaahlamohlaka et al.   APPLIED CATALYSIS A-GENERAL

Nitrogen-doped graphene supported copper catalysts for methanol oxidative carbonylation: Enhancement of catalytic activity and stability by nitrogen species

(2018) Ruina Shi et al.   CARBON

Replication of SMSI via ALD: TiO2 Overcoats Increase Pt-Catalyzed Acrolein Hydrogenation Selectivity

(2018) Robert M. Kennedy et al.   CATALYSIS LETTERS

Direct Synthesis of Hydrogen and Dimethoxylmethane from Methanol on Copper/Silica Catalysts with Optimal Cu+ /Cu0 Sites

(2018) Liubi Wu et al.   ChemCatChem

Metal Catalysts for Heterogeneous Catalysis: From Single Atoms to Nanoclusters and Nanoparticles

(2018) Lichen Liu et al.   CHEMICAL REVIEWS

Controlling the charge state of supported nanoparticles in catalysis: lessons from model systems

(2018) Gianfranco Pacchioni et al.   CHEMICAL SOCIETY REVIEWS

Influence of the Crystal Structure of Titanium Oxide on the Catalytic Activity of Rh/TiO2 in Steam Reforming of Propane at Low Temperature

(2018) Lin Yu et al.   CHEMISTRY-A EUROPEAN JOURNAL

Modelling free and oxide-supported nanoalloy catalysts: comparison of bulk-immiscible Pd–Ir and Au–Rh systems and influence of a TiO2 support

(2018) Ilker Demiroglu et al.   FARADAY DISCUSSIONS

CO Oxidation Kinetics over Au/TiO2 and Au/Al2O3 Catalysts: Evidence for a Common Water-Assisted Mechanism

(2018) Johnny Saavedra et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Evaluating differences in the active-site electronics of supported Au nanoparticle catalysts using Hammett and DFT studies

(2018) Gaurav Kumar et al.   Nature Chemistry

The Impact of La Doping on Dry Reforming Ni-Based Catalysts Loaded on FSP-Alumina

(2018) Jonathan Horlyck et al.   TOPICS IN CATALYSIS

Synthesis and applications of nanoporous perovskite metal oxides

(2018) Xiubing Huang et al.   Chemical Science

Oxidative strong metal–support interactions (OMSI) of supported platinum-group metal catalysts

(2018) Hailian Tang et al.   Chemical Science

Identifying Dynamic Structural Changes of Active Sites in Pt–Ni Bimetallic Catalysts Using Multimodal Approaches

(2018) Deyu Liu et al.   ACS Catalysis

Specific Metal–Support Interactions between Nanoparticle Layers for Catalysts with Enhanced Methanol Oxidation Activity

(2018) Sinmyung Yoon et al.   ACS Catalysis

Defective Mesocrystal ZnO-Supported Gold Catalysts: Facilitating CO Oxidation via Vacancy Defects in ZnO

(2018) Ming-Han Liu et al.   ACS Catalysis

Fe-Containing Magnesium Aluminate Support for Stability and Carbon Control during Methane Reforming

(2018) Stavros Alexandros Theofanidis et al.   ACS Catalysis

Low-Temperature CO2 Methanation over CeO2-Supported Ru Single Atoms, Nanoclusters, and Nanoparticles Competitively Tuned by Strong Metal–Support Interactions and H-Spillover Effect

(2018) Yu Guo et al.   ACS Catalysis

Approaches for Understanding and Controlling Interfacial Effects in Oxide-Supported Metal Catalysts

(2018) Insoo Ro et al.   ACS Catalysis

Tuning the Pt/CeO2 Interface by in Situ Variation of the Pt Particle Size

(2018) Andreas M. Gänzler et al.   ACS Catalysis

The Crucial Role of the Support in the Transformations of Bimetallic Nanoparticles and Catalytic Performance

(2018) Priscila Destro et al.   ACS Catalysis

Visible-Light-Mediated Methane Activation for Steam Methane Reforming under Mild Conditions: A Case Study of Rh/TiO2 Catalysts

(2018) Hui Song et al.   ACS Catalysis

Iron-doped ZnO as a support for Pt-based catalysts to improve activity and stability: enhancement of metal–support interaction by the doping effect

(2018) Si Bui Trung Tran et al.   RSC Advances

Modelling free and oxide-supported nanoalloy catalysts: comparison of bulk-immiscible Pd–Ir and Au–Rh systems and influence of a TiO2 support

(2018) Ilker Demiroglu et al.   FARADAY DISCUSSIONS

A synergistic interaction between isolated Au nanoparticles and oxygen vacancies in an amorphous black TiO2 nanoporous film: toward enhanced photoelectrochemical water splitting

(2018) Li Shi et al.   Journal of Materials Chemistry A

Intermetallic nickel silicide nanocatalyst—A non-noble metal–based general hydrogenation catalyst

(2018) Pavel Ryabchuk et al.   Science Advances

Improving the direct synthesis of hydrogen peroxide from hydrogen and oxygen over Au-Pd/SBA-15 catalysts by selective functionalization

(2018) A. Rodríguez-Gómez et al.   Molecular Catalysis

Ru/Al2O3 catalyzed CO2 hydrogenation: Oxygen-exchange on metal-support interfaces

(2018) Yong Yan et al.   JOURNAL OF CATALYSIS

Interfacing with silica boosts the catalysis of copper

(2018) Chaofa Xu et al.   Nature Communications

Sub-Monolayer Control of Mixed-Oxide Support Composition in Catalysts via Atomic Layer Deposition: Selective Hydrogenation of Cinnamaldehyde Promoted by (SiO2-ALD)-Pt/Al2O3

(2018) Zhihuan Weng et al.   ACS Catalysis

Interface tailoring of heterogeneous catalysts by atomic layer deposition

(2018) Bin Zhang et al.   ACS Catalysis

Evidence of encapsulation model for strong metal-support interaction under oxidized conditions: A case study on TiOx/Pt(111) for CO oxidation by in situ wide spectral range IRAS

(2018) Huan Li et al.   ACS Catalysis

Stable niobia-supported nickel catalysts for the hydrogenation of carbon monoxide to hydrocarbons

(2018) C. Hernández Mejía et al.   CATALYSIS TODAY

Structure-activity relationship in water-gas shift reaction over gold catalysts supported on Y-doped ceria

(2018) Tatyana Tabakova et al.   JOURNAL OF RARE EARTHS

Activity enhancement of cobalt catalysts by tuning metal-support interactions

(2018) Carlos Hernández Mejía et al.   Nature Communications

Catalytic CO Oxidation over Au Nanoparticles Supported on CeO2 Nanocrystals: Effect of the Au–CeO2 Interface

(2018) Hyunwoo Ha et al.   ACS Catalysis

Preparation of Cobalt Nanocrystals Supported on Metal Oxides To Study Particle Growth in Fischer–Tropsch Catalysts

(2018) Tom W. van Deelen et al.   ACS Catalysis

Electron transfer dependent catalysis of Pt on N-doped carbon nanotubes: Effects of synthesis method on metal-support interaction

(2017) Xiaomei Ning et al.   JOURNAL OF CATALYSIS

Investigation of inherent differences between oxide supports in heterogeneous catalysis in the absence of structural variations

(2017) Nuoya Yang et al.   JOURNAL OF CATALYSIS

The role of electronic metal-support interactions and its temperature dependence: CO adsorption and CO oxidation on Au/TiO 2 catalysts in the presence of TiO 2 bulk defects

(2017) Y. Wang et al.   JOURNAL OF CATALYSIS

Molecularly Tailored Nickel Precursor and Support Yield a Stable Methane Dry Reforming Catalyst with Superior Metal Utilization

(2017) Tigran Margossian et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Photocatalytic CO2 Reduction by Carbon-Coated Indium-Oxide Nanobelts

(2017) Yun-Xiang Pan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Tuning/exploiting Strong Metal-Support Interaction (SMSI) in Heterogeneous Catalysis

(2017) Chun-Jern Pan et al.   Journal of the Taiwan Institute of Chemical Engineers

Catalyst support effects on hydrogen spillover

(2017) Waiz Karim et al.   NATURE

Variation of SMSI with the Au:Pd Ratio of Bimetallic Nanoparticles on TiO2(110)

(2017) Richard Gubó et al.   TOPICS IN CATALYSIS

Electronic metal-support interaction enhanced oxygen reduction activity and stability of boron carbide supported platinum

(2017) Colleen Jackson et al.   Nature Communications

Influence of TiO2 Bulk Defects on CO Adsorption and CO Oxidation on Au/TiO2: Electronic Metal–Support Interactions (EMSIs) in Supported Au Catalysts

(2017) Yuchen Wang et al.   ACS Catalysis

Support Induced Control of Surface Composition in Cu–Ni/TiO2 Catalysts Enables High Yield Co-Conversion of HMF and Furfural to Methylated Furans

(2017) Bhogeswararao Seemala et al.   ACS Catalysis

Strong Metal–Support Interactions Achieved by Hydroxide-to-Oxide Support Transformation for Preparation of Sinter-Resistant Gold Nanoparticle Catalysts

(2017) Liang Wang et al.   ACS Catalysis

TiO2–x-Modified Ni Nanocatalyst with Tunable Metal–Support Interaction for Water–Gas Shift Reaction

(2017) Ming Xu et al.   ACS Catalysis

Experimental and Theoretical Understanding of Nitrogen-Doping-Induced Strong Metal–Support Interactions in Pd/TiO2 Catalysts for Nitrobenzene Hydrogenation

(2017) Peirong Chen et al.   ACS Catalysis

Carbon Support Surface Effects in the Gold-Catalyzed Oxidation of 5-Hydroxymethylfurfural

(2017) Baira Donoeva et al.   ACS Catalysis

Increasing Oxide Reducibility: The Role of Metal/Oxide Interfaces in the Formation of Oxygen Vacancies

(2017) Antonio Ruiz Puigdollers et al.   ACS Catalysis

New insights into the support morphology-dependent ammonia synthesis activity of Ru/CeO2 catalysts

(2017) Zhanwei Ma et al.   Catalysis Science & Technology

In situ growth of Pt3Ni nanoparticles on an A-site deficient perovskite with enhanced activity for the oxygen reduction reaction

(2017) Yang Gao et al.   Journal of Materials Chemistry A

Metal–support interactions in catalysts for environmental remediation

(2017) Kakeru Fujiwara et al.   Environmental Science-Nano

Classical strong metal–support interactions between gold nanoparticles and titanium dioxide

(2017) Hailian Tang et al.   Science Advances

Synthesis, Characterization, and Application of Metal Nanoparticles Supported on Nitrogen-Doped Carbon: Catalysis beyond Electrochemistry

(2016) Lin He et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Co catalysts supported on oxidized CNTs: Evolution of structure during preparation, reduction and catalytic test in Fischer-Tropsch synthesis

(2016) S.A. Chernyak et al.   APPLIED CATALYSIS A-GENERAL

Palladium nanoparticles supported on amine-functionalized SiO 2 for the catalytic hexavalent chromium reduction

(2016) Metin Celebi et al.   APPLIED CATALYSIS B-ENVIRONMENTAL

Effect of Co crystallinity on Co/CNT catalytic activity in CO/CO 2 hydrogenation and CO disproportionation

(2016) Sergei A. Chernyak et al.   APPLIED SURFACE SCIENCE

Tailoring metal–oxide interfaces of oxide-encapsulated Pt/silica hybrid nanocatalysts with enhanced thermal stability

(2016) Song Yi Moon et al.   CATALYSIS TODAY

Tailoring the Catalytic Properties of Metal Nanoparticles via Support Interactions

(2016) M. Ahmadi et al.   Journal of Physical Chemistry Letters

Catalytic Proton Dynamics at the Water/Solid Interface of Ceria-Supported Pt Clusters

(2016) Matteo Farnesi Camellone et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Sacrificial Coating Strategy Toward Enhancement of Metal–Support Interaction for Ultrastable Au Nanocatalysts

(2016) Wangcheng Zhan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Dynamical Observation and Detailed Description of Catalysts under Strong Metal–Support Interaction

(2016) Shuyi Zhang et al.   NANO LETTERS

Size-dependent adhesion energy of shape-selected Pd and Pt nanoparticles

(2016) M. Ahmadi et al.   Nanoscale

Adsorbate-mediated strong metal–support interactions in oxide-supported Rh catalysts

(2016) John C. Matsubu et al.   Nature Chemistry

Palladium-tin catalysts for the direct synthesis of H2O2 with high selectivity

(2016) S. J. Freakley et al.   SCIENCE

Intermetallic Compounds: Promising Inorganic Materials for Well-Structured and Electronically Modified Reaction Environments for Efficient Catalysis

(2016) Shinya Furukawa et al.   ACS Catalysis

Enhanced Chemoselective Hydrogenation through Tuning the Interaction between Pt Nanoparticles and Carbon Supports: Insights from Identical Location Transmission Electron Microscopy and X-ray Photoelectron Spectroscopy

(2016) Wen Shi et al.   ACS Catalysis

Role of the Cu-ZrO2 Interfacial Sites for Conversion of Ethanol to Ethyl Acetate and Synthesis of Methanol from CO2 and H2

(2016) Insoo Ro et al.   ACS Catalysis

Understanding and controlling the structure and segregation behaviour of AuRh nanocatalysts

(2016) Laurent Piccolo et al.   Scientific Reports

Anti-Coking Ni/SiO2Catalyst for Dry Reforming of Methane: Role of Oleylamine/Oleic Acid Organic Pair

(2015) Xingyuan Gao et al.   ChemCatChem

Effect of support surface treatment on the synthesis, structure, and performance of Co/CNT Fischer–Tropsch catalysts

(2015) Thomas O. Eschemann et al.   JOURNAL OF CATALYSIS

High Resolution HAADF Characterization of Ir/TiO2 Catalyst Reduced at 500 °C: Intensity Profile Analysis

(2015) Orlando Hernández-Cristóbal et al.   Journal of Physical Chemistry C

Strong Metal–Support Interactions between Gold Nanoparticles and Nonoxides

(2015) Hailian Tang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Hot-Electron-Induced Highly Efficient O2 Activation by Pt Nanoparticles Supported on Ta2O5 Driven by Visible Light

(2015) Hirokatsu Sakamoto et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Stable Bimetallic AuIr/TiO2 Catalyst: Physical Origins of the Intrinsic High Stability against Sintering

(2015) Chang Wan Han et al.   NANO LETTERS

Adhesion and Atomic Structures of Gold on Ceria Nanostructures: The Role of Surface Structure and Oxidation State of Ceria Supports

(2015) Yuyuan Lin et al.   NANO LETTERS

Nanoscale intimacy in bifunctional catalysts for selective conversion of hydrocarbons

(2015) Jovana Zecevic et al.   NATURE

Counting electrons on supported nanoparticles

(2015) Yaroslava Lykhach et al.   NATURE MATERIALS

Au–Rh and Au–Pd nanocatalysts supported on rutile titania nanorods: structure and chemical stability

(2015) Zere Konuspayeva et al.   PHYSICAL CHEMISTRY CHEMICAL PHYSICS

Nano-socketed nickel particles with enhanced coking resistance grown in situ by redox exsolution

(2015) Dragos Neagu et al.   Nature Communications

Cobalt-Catalyzed Fischer–Tropsch Synthesis: Chemical Nature of the Oxide Support as a Performance Descriptor

(2015) Gonzalo Prieto et al.   ACS Catalysis

Promoting Strong Metal Support Interaction: Doping ZnO for Enhanced Activity of Cu/ZnO:M (M = Al, Ga, Mg) Catalysts

(2015) Julia Schumann et al.   ACS Catalysis

Tailoring the Oxidation Activity of Pt Nanoclusters via Encapsulation

(2015) Fan Zhang et al.   ACS Catalysis

Support Functionalization To Retard Ostwald Ripening in Copper Methanol Synthesis Catalysts

(2015) Roy van den Berg et al.   ACS Catalysis

Transforming Nano Metal Nonselective Particulates into Chemoselective Catalysts for Hydrogenation of Substituted Nitrobenzenes

(2015) Pedro Serna et al.   ACS Catalysis

Selective CO Methanation on Ru/TiO2 Catalysts: Role and Influence of Metal–Support Interactions

(2015) Ali M. Abdel-Mageed et al.   ACS Catalysis

A Case of Strong Metal-Support Interactions: Combining Advanced Microscopy and Model Systems to Elucidate the Atomic Structure of Interfaces

(2014) Marc G. Willinger et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Electrochemistry of Nanoparticles

(2014) Steven E. F. Kleijn et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Formation of Intermetallic Compounds by Reactive Metal-Support Interaction: A Frequently Encountered Phenomenon in Catalysis

(2014) Simon Penner et al.   ChemCatChem

Strong Metal-Support Interaction in Pt/TiO2 Induced by Mild HCHO and NaBH4 Solution Reduction and Its Effect on Catalytic Toluene Combustion

(2014) Zebao Rui et al.   INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH

Interfacial Bonding Stabilizes Rhodium and Rhodium Oxide Nanoparticles on Layered Nb Oxide and Ta Oxide Supports

(2014) Megan E. Strayer et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Influence of the support on surface rearrangements of bimetallic nanoparticles in real catalysts

(2014) N. J. Divins et al.   SCIENCE

Synergistic Catalysis over Bimetallic Alloy Nanoparticles

(2013) Ashish Kumar Singh et al.   ChemCatChem

In situ growth of nanoparticles through control of non-stoichiometry

(2013) Dragos Neagu et al.   Nature Chemistry

Electronic interactions and charge transfers of metal atoms and clusters on oxide surfaces

(2013) Gianfranco Pacchioni   PHYSICAL CHEMISTRY CHEMICAL PHYSICS

Metal Nanoparticle Catalysts Beginning to Shape-up

(2012) Beatriz Roldan Cuenya   ACCOUNTS OF CHEMICAL RESEARCH

Hydrogen Spillover. Facts and Fiction

(2012) R. Prins   CHEMICAL REVIEWS

Selective oxidation of alcohols and aldehydes over supported metal nanoparticles

(2012) Sara E. Davis et al.   GREEN CHEMISTRY

Alloys in catalysis: phase separation and surface segregation phenomena in response to the reactive environment

(2012) Spiros Zafeiratos et al.   Catalysis Science & Technology

Nature of Ag Islands and Nanoparticles on the CeO2(111) Surface

(2011) Paola Luches et al.   Journal of Physical Chemistry C

First Direct Visualization of Spillover Species Emitted from Pt Nanoparticles†

(2010) Satoru Takakusagi et al.   LANGMUIR

Ceria Maintains Smaller Metal Catalyst Particles by Strong Metal-Support Bonding

(2010) J. A. Farmer et al.   SCIENCE

Synthesis and catalytic properties of metal nanoparticles: Size, shape, support, composition, and oxidation state effects

(2010) Beatriz Roldan Cuenya   THIN SOLID FILMS

Correlating Particle Size and Shape of Supported Ru/γ-Al2O3Catalysts with NH3Decomposition Activity

(2009) Ayman M. Karim et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Interface Structures of Gold Nanoparticles onTiO2(110)

(2009) N. Shibata et al.   PHYSICAL REVIEW LETTERS

Nanoalloys:  From Theory to Applications of Alloy Clusters and Nanoparticles

(2008) Riccardo Ferrando et al.   CHEMICAL REVIEWS