4.7 Article

Design of dispersant for highly concentrated one-dimensional Nb2Se9 inorganic molecular chains from bulk crystal

Journal

SCIENTIFIC REPORTS
Volume 9, Issue -, Pages -

Publisher

NATURE PUBLISHING GROUP
DOI: 10.1038/s41598-019-51210-z

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Funding

  1. Nano Material Technology Development Program through the National Research Foundation of Korea (NRF) - Ministry of Science and ICT [2017M3A7B8065561, NRF-2019R1A2C1006972]
  2. National Research Foundation of Korea (NRF) - Korea government (MSIP) [NRF-2017R1A4A1015770]
  3. National Research Foundation of Korea [2017M3A7B8065561] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)

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We determined the optimum dispersant to separate bulk Nb2Se9 material into 1D chain units. The Nb2Se9, which had a negative zeta potential (-43.3 mV), showed acidic characteristics and strongly bonded with the amine head of octadecyl amine through a charge transfer (from the amine to Se atoms) reaction. The steric hindrance of the octadecyl tail resulted in excellent dispersion of Nb2Se9 (down to nanometre-sized mono-chains).

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