Picosecond to millisecond tracking of a photocatalytic decarboxylation reaction provides direct mechanistic insights

Perspective: How can ultrafast laser spectroscopy inform the design of new organic photoredox catalysts for chemical and materials synthesis?

(2019) Andrew J. Orr-Ewing   Structural Dynamics

Photocatalytic decarboxylative alkylations mediated by triphenylphosphine and sodium iodide

(2019) Ming-Chen Fu et al.   SCIENCE

Infrared spectroscopy reveals multi-step multi-timescale photoactivation in the photoconvertible protein archetype dronpa

(2018) Sergey P. Laptenok et al.   Nature Chemistry

Catalytic dehydrogenative decarboxyolefination of carboxylic acids

(2018) Xiang Sun et al.   Nature Chemistry

Decarboxylative alkylation for site-selective bioconjugation of native proteins via oxidation potentials

(2017) Steven Bloom et al.   Nature Chemistry

Femtosecond to microsecond observation of the photochemical reaction of 1,2-di(quinolin-2-yl)disulfide with methyl methacrylate

(2017) Daisuke Koyama et al.   PHYSICAL CHEMISTRY CHEMICAL PHYSICS

Photoinduced decarboxylative borylation of carboxylic acids

(2017) Alexander Fawcett et al.   SCIENCE

A 100 kHz Time-Resolved Multiple-Probe Femtosecond to Second Infrared Absorption Spectrometer

(2016) Gregory M. Greetham et al.   APPLIED SPECTROSCOPY

Organic Photoredox Catalysis

(2016) Nathan A. Romero et al.   CHEMICAL REVIEWS

Translational, rotational and vibrational relaxation dynamics of a solute molecule in a non-interacting solvent

(2016) Michael P. Grubb et al.   Nature Chemistry

Detecting the oxyl radical of photocatalytic water oxidation at an n-SrTiO3/aqueous interface through its subsurface vibration

(2016) David M. Herlihy et al.   Nature Chemistry

Visible-Light-Induced Decarboxylative Functionalization of Carboxylic Acids and Their Derivatives

(2015) Jun Xuan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Mechanistic photodecarboxylation of pyruvic acid: Excited-state proton transfer and three-state intersection

(2014) Xue-Ping Chang et al.   JOURNAL OF CHEMICAL PHYSICS

New insights into the photochemistry of [CpFe(CO)2]2 using picosecond through microsecond time-resolved infrared spectroscopy (TRIR)

(2014) Christopher M. Brookes et al.   POLYHEDRON

Spurious Observation of the Marcus Inverted Region in Bimolecular Photoinduced Electron Transfer

(2012) Arnulf Rosspeintner et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Investigating the Rate of Photoreductive Glucosyl Radical Generation

(2011) R. Stephen Andrews et al.   ORGANIC LETTERS

Inter- and Intramolecular Addition Reactions of Electron-Deficient Alkenes with Alkyl Radicals, Generated by SET-Photochemical Decarboxylation of Carboxylic Acids, Serve as a Mild and Efficient Method for the Preparation of γ-Amino Acids and Macrocyclic Lactones

(2009) Yasuharu Yoshimi et al.   ORGANIC LETTERS

Decarboxylative photosubstitution of dicyanobenzenes with aliphatic carboxylate ions

(2008) Tatsuya Itou et al.   TETRAHEDRON

A quantum mechanics study on the reaction mechanism of chalcone formation from p-coumaroyl-CoA and malonyl-CoA catalyzed by chalcone synthase

(2008) Dai-lin Li et al.   THEORETICAL CHEMISTRY ACCOUNTS