4.7 Article

A novel floating adsorbents system of acid orange 7 removal: Polymer grafting effect

Journal

SEPARATION AND PURIFICATION TECHNOLOGY
Volume 227, Issue -, Pages -

Publisher

ELSEVIER
DOI: 10.1016/j.seppur.2019.115677

Keywords

Floating adsorbents; Hollow glass microspbere; Non-polymer grafting; Polymer grafting; Acid orange 7

Funding

  1. National Natural Science Foundation of China [21677020]
  2. Chongqing Technology Innovation and Application Demonstration (industry) Key Research and Development Projects [cstc2018jszx-cyzdX0035]

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Floating adsorbents are materials that can adsorb dissolved pollutants and float on the water surface stably, which enables rapid and efficient solid-liquid separation. In this study, by grafting silane coupling agent A-1100 and methacryloyloxyethyltrimethyl ammonium chloride on the surface of hollow glass microspheres, adsorbents with non-polymer graft and polymer graft were prepared which have the ability to adsorb anionic dye and can be easily separated by floating mechanism. The SEM, XPS, S-BET, TG, XRD characterization results confirmed the successful grafting of silane coupling agent A-1100 and methacryloyloxyethyltrimethyl ammonium chloride. Adsorption experiments on acid orange 7 show that non-polymer grafting adsorbents have better adsorption performance and the adsorption capacity reaches 217.39 mg g(-1), while polymer grafting adsorbents have stronger environmental adaptability.

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