Article
Chemistry, Physical
Linfeng Nie, Shuangde Li, Shaohua Chai, Ning Han, Yunfa Chen
Summary: In this study, a photothermal catalyst CuMn2O4/Mn2O3 with heterojunction was prepared by the sol-gel method, and high-efficiency catalytic oxidation of toluene was achieved through different calcination temperature treatments. Under the irradiation of 700 mW/cm(2) Xe lamp, the CuMn2O4/Mn2O3 catalyst exhibited excellent photo-thermal conversion ability and toluene conversion performance, with good catalytic stability.
APPLIED SURFACE SCIENCE
(2022)
Article
Chemistry, Physical
Maxim Zabilskiy, Iztok Arcon, Petar Djinovic, Elena Tchernychova, Albin Pintar
Summary: The study found that Cu2+/Cu+ and Ce4+/Ce3+ ionic pairs play dynamic and crucial roles in the N2O decomposition reaction, with the initial formation of reduced Cu+ and Ce3+ species during activation process. The concentration of these species significantly decreases during the steady-state reaction. The copper-ceria interface plays a crucial role in mediating electron and oxygen transfer during the catalytic reaction.
Article
Materials Science, Ceramics
Shannon E. Murray, Yu-Ying Lin, Soumitra S. Sulekar, Mebatsion S. Gebre, Nicola H. Perry, Daniel P. Shoemaker
Summary: Reactive flash sintering is an effective method for densifying and synthesizing ceramic materials, but the predictive capability of the BBR model for phase transformations during the process is limited. CuO reduction and Mn(2)O(3) reduction demonstrate the challenges of predicting phase transformations due to local, stochastic current flow and localized heating. Understanding and engineering the complex thermal profile that results from these sources of inhomogeneity can be beneficial for optimizing reaction kinetics.
JOURNAL OF THE AMERICAN CERAMIC SOCIETY
(2021)
Article
Chemistry, Multidisciplinary
Azam Sobhani
Summary: The treatment of effluents using adsorption of pollution of solvent is a necessary aspect of research. The use of photocatalysts for this purpose has received much attention from researchers. In current research, micro composites based on copper manganese oxides were synthesized and used as photocatalyst, showing high efficiency in degrading RBBR.
ARABIAN JOURNAL OF CHEMISTRY
(2023)
Article
Chemistry, Physical
Azam Sobhani
Summary: This study successfully addresses the elimination of dye pollution from the solvent phase by synthesizing Cu-based spinel nanocomposites and optimizing their morphology and structural characteristics. The nanocomposites exhibit excellent photocatalytic activity for the degradation of organic dyes and display both ferromagnetic and antiferromagnetic behaviors.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2022)
Article
Chemistry, Physical
Jingjing Wang, Jun Chen, Lishan Peng, Haidong Zhang, Zhiquan Jiang, Kun Xiong, Qi Yang, Jia Chen, Na Yang
Summary: The study provides a new understanding of the active site of CuMnOx catalysts and suggests a new perspective in the development of effective and low-cost CuMnOx catalysts for heterogeneous catalytic oxidation reactions. The CuMnOx catalysts were found to consist of uniform CuO-Mn2O3 oxide pair structure, with highly isolated/dispersed CuO species anchored in the framework of Mn2O3. The speciation in these CuMnOx catalysts shifts from highly isolated or single Cu2+ oxide species to CuO nanoclusters and CuO microcrystalline with increasing Cu content.
APPLIED SURFACE SCIENCE
(2022)
Article
Nanoscience & Nanotechnology
Sourav Bhowmick, Arijeet Sarangi, Ching Thian Moi, Sudip Chakraborty, Mohammad Qureshi
Summary: A strategical approach involving morphological transformation and heterojunction formation is used to address the limitations of uni-metal oxide electrocatalysts and enhance their bifunctionality. The in situ generation of CuO over Mn2O3 leads to a morphological transformation from solid spheres to hollow spherical structures, which improves the electrocatalytic performance by increasing exposed surface active sites. Deposition of 2D VOP sheets further enhances the electrocatalytic efficiency of Mn2O3/CuO. The formation of an n-p heterojunction between Mn2O3 and CuO, along with the effect of the VOP overlayer, significantly increases the turnover frequency compared to the bare counterpart.
ACS APPLIED MATERIALS & INTERFACES
(2022)
Article
Thermodynamics
Clayton R. Mulvihill, Sulaiman A. Alturaifi, Eric L. Petersen
Summary: This study measured the low-pressure limit rate constant of the N2O + M reaction using laser absorption spectroscopy and analyzed the results with excellent agreement with historical data. The determined expression for the rate constant showed better stability and precision over a wide temperature range.
COMBUSTION AND FLAME
(2021)
Article
Materials Science, Multidisciplinary
Bushra Zafar, Syed Salman Shafqat, Muhammad Nadeem Zafar, Sajjad Haider, Sajjad Hussain Sumrra, Muhammad Zubair, Norah Alwadai, Fwzah H. Alshammari, Amani Saleh Almuslem, Muhammad Saeed Akhtar
Summary: This study synthesized metal oxide nanoparticles using a hydrothermal approach, characterized their morphology and crystal structure, and investigated their adsorption, antimicrobial, and antioxidant properties. The results showed that these nanoparticles have great potential for pollutant removal and biological activities.
MATERIALS TODAY COMMUNICATIONS
(2022)
Article
Chemistry, Analytical
Amanzhol Turlybekuly, Madina Sarsembina, Almagul Mentbayeva, Zhumabay Bakenov, Baktiyar Soltabayev
Summary: A highly sensitive N2O gas sensor operating at room temperature has been developed using CuO/TiO2 heterojunctioned nano-interfaces, demonstrating outstanding response and recovery times and an excellent detection limit at ultra-low concentrations.
SENSORS AND ACTUATORS B-CHEMICAL
(2023)
Article
Engineering, Environmental
Ye Li, Xinping Wang, Chuan Shi
Summary: A series of Ba-Ce-Cu catalysts were prepared by the citric acid method and used for N2O decomposition. The doping effects of Ba and Ce on CuO were studied. It was found that the activity and tolerance of the catalyst to impurity gases can be effectively modified by the doping components. Ba0.2Cu displayed high activity due to the stabilizing effect of Ba on the active Cu+ species, while Ba0.2Ce0.5Cu exhibited higher catalytic activity and strong tolerance to NO, thanks to the synergistic effect of Ba and Ce and the ability of CeO2 to remove NOx species.
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
(2023)
Article
Engineering, Environmental
Liming Zhao, Yingju Yang, Jing Liu, Junyan Ding
Summary: The reaction mechanism of benzene catalytic oxidation over CuMn2O4 catalyst was investigated using density functional theory, revealing that Cu atom serves as the primary active site and the rate-determining step is the ring-opening reaction.
JOURNAL OF HAZARDOUS MATERIALS
(2022)
Article
Materials Science, Multidisciplinary
Jinhuan Yao, Ying Liu, Yanwei Li, Jiqiong Jiang, Qing Zhu
Summary: Mn2O3/Mn3O4 composites are synthesized by a facile thermal decomposition strategy using MnCl2 center dot 4H(2)O and sucrose as raw materials. The addition of sucrose transforms the phase structure of manganese oxides from single Mn2O3 to Mn2O3/Mn3O4 composites, reduces particle size, and enhances zinc storage performances. The Mn2O3/Mn3O4 sample (MO-1.0) prepared with a Mn2+/sucrose molar ratio of 1:1 exhibits the best zinc storage performances, delivering high specific capacities at different current densities. This study provides a simple and cost-efficient method for preparing high-performance Mn2O3/Mn3O4 composite cathode materials for ZIBs.
MATERIALS RESEARCH BULLETIN
(2023)
Article
Energy & Fuels
Jie Fan, Ye Zhang, Yongxing Yang, Junsheng Hao, Yongzhao Wang, Aniu Qian
Summary: This article investigates the potential of spinel as a candidate for thermochemical energy storage materials, demonstrating its suitable redox properties and cycle stability. Samples with a Cu mole ratio of 1/3 exhibit the best performance in terms of cycle stability and flexibility in temperature range, indicating its potential as a thermal energy storage material. Additionally, comparing air and nitrogen-air redox cycles reveals more thorough reduction in an inert atmosphere.
JOURNAL OF ENERGY STORAGE
(2021)
Article
Materials Science, Multidisciplinary
Cuixia Cheng, Yinfang Cheng, Guosong Lai
Summary: In this study, CuMn2O4 hierarchical microspheres were prepared using micro/nano MnCO3 precursor. The resulting supercapacitors demonstrated a remarkable specific capacitance and excellent capacitance retention, indicating promising applications.
Article
Electrochemistry
Jianghong Zhao, Wei Li, Shiping Wu, Feifei Xu, Jiafeng Du, Jiefeng Li, Kaixi Li, Jun Ren, Yongxiang Zhao
ELECTROCHIMICA ACTA
(2020)
Article
Chemistry, Physical
Yong Li, Yun Zhao, Canliang Ma, Jing Shi, Yongxiang Zhao
JOURNAL OF ALLOYS AND COMPOUNDS
(2020)
Article
Chemistry, Physical
Xiaobo Hu, Yongzhao Wang, Ruifang Wu, Lili Zhao, Xuhui Wei, Yongxiang Zhao
APPLIED SURFACE SCIENCE
(2020)
Article
Chemistry, Physical
Jianbing Wu, Zeping Sun, Zhihong Wei, Zhangfeng Qin, Yongxiang Zhao
Summary: This study revealed the relationship between the catalytic performance of HZSM-5 zeolite and Si/Al ratio and reaction temperature, showing their interdependent effects on PODEn yield. By investigating the reaction mechanism through in-situ IR characterization and DFT calculation, important intermediates and reaction steps were elucidated. The differences in catalytic performance resulting from Si/Al ratio and reaction temperature were explained based on the proposed mechanisms.
Article
Chemistry, Physical
Xuhui Wei, Yongzhao Wang, Xiao Li, Ruifang Wu, Yongxiang Zhao
MOLECULAR CATALYSIS
(2020)
Article
Chemistry, Physical
Xiaobo Hu, Yongzhao Wang, Ruifang Wu, Yongxiang Zhao
Summary: The cobalt oxide catalyst supported on graphitic carbon nitride exhibited superior activity in decomposing N2O compared to other catalysts. The excellent performance was attributed to the high surface Co2+ content, massive surface oxygen species, and facile electron transfer characteristics of the catalyst. Additionally, the synergistic effects among active species also contributed to the catalyst's high efficiency.
APPLIED SURFACE SCIENCE
(2021)
Article
Chemistry, Physical
Xiaoli Liu, Yongzhao Wang, Ruifang Wu, Yongxiang Zhao
Summary: The study showed that Co/HAP exhibited better catalytic activity for N2O decomposition compared to Co/FAP, due to its larger specific surface area, more ion-exchanged Co2+, and stronger oxygen desorption capacity. Additionally, Co/HAP had higher basic content and basic site density than Co/FAP, which may enhance the electron donating ability of Co2+ and promote the N2O catalytic decomposition.
CATALYSIS SURVEYS FROM ASIA
(2021)
Article
Chemistry, Physical
Yongzhao Wang, Xiang Zhou, Xuhui Wei, Xiao Li, Ruifang Wu, Xiaobo Hu, Yongxiang Zhao
Summary: Different methods were used to prepare Co/hydroxyapatite catalysts with various Co species, and it was found that Co(II)(2+)Oh in Co(1.2)-IE prepared by ion exchange exhibited higher catalytic activity and stability, as well as stronger resistance against oxygen and water.
MOLECULAR CATALYSIS
(2021)
Article
Chemistry, Physical
Xiao Li, Lisha Xing, Wanjun Zhao, Yongzhao Wang, Yongxiang Zhao
Summary: The addition of FeCl3 can enhance the catalytic performance of Pd-Cu/HAP in low-temperature CO selective oxidation reactions, resulting in higher CO conversion rate and CO2 selectivity. This is attributed to the strong interaction between Fe2O3 species and Pd-Cu/HAP, promoting the oxidation of Pd0 species and enhancing CO activation.
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
(2021)
Article
Chemistry, Physical
Xiaobo Hu, Yongzhao Wang, Ruifang Wu, Yongxiang Zhao
Summary: The study prepared a series of defective N-doped Co3O4 catalysts using a facile method and confirmed the successful doping of N atoms into Co3O4. Among them, N-Co3O4-0.05 exhibited the best performance in N2O decomposition reaction, attributed to the promotion of defective structures and oxygen vacancies, as well as the enhanced redox properties of Co2+ and Co3O4 by N doping.
MOLECULAR CATALYSIS
(2021)
Article
Chemistry, Physical
Wanjun Zhao, Xiao Li, Hui Dang, Ruifang Wu, Yongzhao Wang, Yongxiang Zhao
Summary: The addition of Sn improves the catalytic performance of Pd-Cu-Sn/APT for CO oxidation by facilitating the formation of more active phases and Cu+ species, enhancing the oxidation ability of Pd-0 species, and suppressing water vapor adsorption on the catalyst surface. As a result, the Sn-modified Pd-Cu/APT catalyst shows excellent catalytic performance for CO oxidation in moist conditions at room temperature.
REACTION KINETICS MECHANISMS AND CATALYSIS
(2021)
Article
Chemistry, Physical
Jingjing Tan, Yihao Su, Xueqing Hai, Long Huang, Jinglei Cui, Yulei Zhu, Yongzhao Wang, Yongxiang Zhao
Summary: A series of layered Cu-Co-Al hydrotalcite (LDHs) catalysts with different Cu/Co molar ratio were synthesized and applied for the hydrogenation of furfuryl alcohol to 1,5-pentanediol. The Cu0.2Co5.8/Al2O3 catalyst showed superior catalytic efficiency compared to monometallic Co/Al2O3 or Cu/Al2O3 catalysts. In-situ XPS, H-2-TPR, CO2-TPD analysis revealed that the synergistic catalysis between surface Cu-0, CoOx and the basicity of metal oxides contributed to the high efficiency of this catalyst.
MOLECULAR CATALYSIS
(2022)
Article
Chemistry, Physical
Jingjing Tan, Jing He, Kuan Gao, Shanhui Zhu, Jinglei Cui, Long Huang, Yulei Zhu, Yongxiang Zhao
Summary: This study investigates the hydrogenation of furfural to furfuryl alcohol using different morphologies of Cu/CeO2 catalyst. The results show that the Cu/CeO2-R (110) catalyst exhibits superior catalytic performance, with a high yield of 98%. The structure-activity relationship reveals that the catalyst's intrinsic activity is positively correlated with the concentration of oxygen vacancies and Cu(0) metal sites. DFT calculations and in-situ FTIR further confirm that the Cu/CeO2-R (110) catalyst with more oxygen vacancies promotes the adsorption and activation of furfural on its surface.
APPLIED SURFACE SCIENCE
(2022)
Article
Chemistry, Physical
Yong Li, Haiting Ren, Yun Zhao, Zhouru Guo, Canliang Ma, Ruifang Wu, Cheng-meng Chen, Yongxiang Zhao
Summary: Researchers have developed a simple chemical reduction strategy to prepare a new Sn/graphene nanocomposite material as an anode for lithium-ion batteries, with significant contributions from the complexing and reducing agents used. The nanocomposite exhibits excellent lithium storage performance, high rate capability, and good performance at low temperatures. This work provides a reliable method for synthesizing Sn/C material and suggests a potential candidate for low-temperature lithium storage applications.
JOURNAL OF ALLOYS AND COMPOUNDS
(2023)
Article
Chemistry, Multidisciplinary
Yue-Wei Wei, Guang Yang, Xi-Xi Xu, Yan-Yan Liu, Bao-Jun Li, Yong-Zhao Wang, Yong-Xiang Zhao
Summary: In this study, a carbon-coated zeolite was prepared by calcination at high temperatures using glucose as a carbon source, and Pt nanoparticles were fixed on a core-shell composite support by a simple chemical reduction method. The catalyst PSC-2 showed excellent performance for the hydrolytic dehydrogenation of AB in alkaline solution at room temperature, with a turnover frequency (TOF) of 593 min(-1). The carbon layer on the zeolite surface inhibited the aggregation or deformation of metals in the catalytic reaction, and the metal-support interaction activated the water and accelerated the rate-limiting step of hydrolysis.