Journal
POWDER TECHNOLOGY
Volume 356, Issue -, Pages 661-670Publisher
ELSEVIER
DOI: 10.1016/j.powtec.2019.09.003
Keywords
CaTiO3; Rare earth doping; Single-component phosphor; Warm white; Sol-gel method
Categories
Funding
- National Natural Science Foundation of China [51602032, 41673109]
- Sichuan Science and Technology Program [2018SZDZX0022, 2017SZ0185]
Ask authors/readers for more resources
In this study, a series of Ca0.7Y0.3Ti0.7Al0.3O3:Dy3+ white-emitting phosphors were prepared using the sol-gel method, and Eu3+ were co-doped in Ca0.7Y0.3Ti0.7Al0.3O3:Dy3+ for excellent luminescence properties such as low CCT. The effects of synthesis temperature and Dy3+/Eu3+ concentrations on the crystal structure and luminescence properties of Ca0.7Y0.3Ti0.7Al0.3O3:Dy3+, Eu3+ phosphors were investigated. The X-ray diffraction results indicated that the Ca0.7Y0.3Ti0.7Al0.3O3:Dy3+, Eu3+ samples had a standard CaTiO3 structure. Under the excitation of 390 nm, Ca0.7Y0.3Ti0.7Al0.3O3:Dy3+ phosphors exhibited a white emission consisting of two emission peaks at 488 nm and 582 nm, which corresponded to the F-4(9/2) -> H-6(15/2) and F-4(9/2) -> H-6(13/2) transitions of Dy3+ ions, respectively. With the addition of Eu3+, a red emission appeared and significantly improved via the energy transfer from Dy3+ to Eu3+ ions, and a lower CCTvalue was achieved. Overall, Ca0.7Y0.3Ti0.7Al0.3O3:Dy3+, Eu3+ phosphors have potential applications in warm white light-emitting diodes as a single-component phosphor. (C) 2019 Elsevier B.V. All rights reserved.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available