4.8 Article

Iron-nitrogen-activated carbon as cathode catalyst to improve the power generation of single-chamber air-cathode microbial fuel cells

Journal

BIORESOURCE TECHNOLOGY
Volume 206, Issue -, Pages 285-289

Publisher

ELSEVIER SCI LTD
DOI: 10.1016/j.biortech.2016.01.112

Keywords

Iron-nitrogen-activated carbon; Microbial fuel cell; Oxygen reduction reaction; Electrochemical catalysis

Ask authors/readers for more resources

In order to improve the performance of microbial fuel cell (MFC), iron-nitrogen-activated carbon (Fe-N-C) as an excellent oxygen reduction reaction (ORR) catalyst was prepared here using commercial activated carbon (AC) as matrix and employed in single chamber MFC. In MFC, the maximum power density increased to 2437 +/- 55 mW m(-2), which was 2 times of that with AC. The open circuit potential (OCP) of Fe-N-C cathode (0.47) was much higher than that of AC cathode (0.21 V). The R-0 of Fe-N-C decreased by 47% from 14.36 Omega (AC) to 7.6 X (Fe-N-C). From X-ray photoelectron spectroscopy (XPS), pyridinic nitrogen, quaternary nitrogen and iron species were present, which played an important role in the ORR performance of Fe-N-C. These results demonstrated that the as-prepared Fe-N-C material provided a potential alternative to Pt in AC air cathode MFC for relatively desirable energy generation and wastewater treatment. (C) 2016 Elsevier Ltd. All rights reserved.

Authors

I am an author on this paper
Click your name to claim this paper and add it to your profile.

Reviews

Primary Rating

4.8
Not enough ratings

Secondary Ratings

Novelty
-
Significance
-
Scientific rigor
-
Rate this paper

Recommended

Article Engineering, Chemical

Cu particles confined in three-dimensional open porous carbon foam monolith as highly efficient electrode for electroreduction of nitrate with significant alleviation of nitrite

Fukuan Li, Peng Zhang, Ao Gong, Xueli Zhang, Weizhe Zhang, Kexun Li

Summary: This study developed a novel 3D open porous carbon foam electrode for the electroreduction of nitrate, which exhibited high efficiency and selectivity in nitrate removal.

SEPARATION AND PURIFICATION TECHNOLOGY (2022)

Article Engineering, Chemical

Expeditious and effectual capacitive deionization performance by chitosan-based carbon with hierarchical porosity

Benqiang Cen, Kexun Li, Rui Yang

Summary: Capacitive deionization (CDI) technology is a high-efficiency, energy-saving, green and environmentally friendly water treatment technology. Layered porous carbon materials have been shown to have faster ion migration rates and higher salt removal capacities, making them promising for CDI desalination.

DESALINATION (2022)

Article Chemistry, Physical

Ligand-exchange-induced child-mother metal-organic frameworks derived a novel heterostructured iron-based carbon for neutral oxygen reduction in microbial fuel cell

Xueli Zhang, Bolong Liang, Kexun Li, Hao Wang

Summary: An innovative ligand exchange strategy was proposed to construct a multi-structured Fe-N-C-based electrocatalyst, which showed remarkable catalytic activity and stability for neutral pH oxygen reduction reaction (ORR). MFCs using this electrocatalyst exhibited high power density and significantly improved COD removal efficiency, with potential practical applications.

JOURNAL OF POWER SOURCES (2022)

Article Engineering, Chemical

Well-dispersed Prussian blue analogues connected with carbon nanotubes for efficient capacitive deionization process

Wei Zhang, Xujie Wei, Xueli Zhang, Silu Huo, Ao Gong, Xiaoping Mo, Kexun Li

Summary: Prussian blue analogs (PBAs) have the potential to be used as Faradic electrodes materials in capacitive deionization (CDI) for desalination purposes. However, PBAs face limitations such as agglomeration, poor conductivity, and structural collapse. In this study, a 3D composite material, NaFeHCF@CNT, was synthesized to enhance CDI performance by improving charge transfer and ion diffusion. The NaFeHCF@CNT electrode showed high desalination capacity and low energy consumption, making it a promising candidate for CDI systems.

SEPARATION AND PURIFICATION TECHNOLOGY (2022)

Article Engineering, Chemical

Three-dimensional Prussian blue nanoflower as a high-performance sodium storage electrode for water desalination

Ao Gong, Yubo Zhao, Xueli Zhang, Bolong Liang, Wei Zhang, Kexun Li

Summary: This study presents a facile strategy to prepare three-dimensional flowerlike Prussian blue intercalation material for efficient water desalination. The flowerlike structure enhances the desalination capacity and cycling stability due to the enlarged contact area and improved Na+ ion delivery and conversion. This work proves the promising application of flowerlike Prussian blue in CDI and other electrochemical fields.

SEPARATION AND PURIFICATION TECHNOLOGY (2022)

Article Chemistry, Physical

High-efficiency power amplification of microbial fuel cell by modifying cathode with iron-incorporated thermalized covalent organic framework

Xueli Zhang, Zhiyuan Lin, Wei Su, Mingtao Zhang, Xiaojing Wang, Kexun Li

Summary: A series of electrocatalysts (Fe/TTF) were synthesized and tested in microbial fuel cells (MFCs), and Fe/TTF-0.5-900 showed the best catalytic performance, resulting in an increased maximum power density of the MFCs. The study also revealed the roles of TTF and iron carbide in promoting charge and mass transfer, as well as the effectiveness of iron carbide in ORR catalysis.

APPLIED SURFACE SCIENCE (2022)

Article Green & Sustainable Science & Technology

Efficient electro-assisted adsorption/desorption of phosphate on MOF-derived hierarchically porous carbon electrode

Mingming He, Peng Zhang, Xueli Zhang, Fukuan Li, Silu Huo, Dezhi Fang, Bolong Liang, Kexun Li

Summary: In this study, a hierarchically porous carbon electrode derived from MOF (ZrMC) was fabricated for the selective electrosorption of phosphate. The electrode demonstrated high removal rate and maximum adsorption capacity, attributed to its porous structure, conductivity, and active centers. Additionally, the electrode showed excellent desorption capacity when a reversed voltage was applied. The electrosorption mechanism was comprehensively clarified by FTIR and XPS measurements.

JOURNAL OF CLEANER PRODUCTION (2022)

Review Engineering, Environmental

Recent progress in metal-based composites toward adsorptive removal of phosphate: Mechanisms, behaviors, and prospects

Peng Zhang, Mingming He, Silu Huo, Fukuan Li, Kexun Li

Summary: This article reviews the recent progress in the application of metal-based composites for the removal of phosphate, including both pristine adsorption and electrosorption methods. The dominating mechanisms affecting phosphate removal by metal-based composites are discussed in detail, along with possible improvements such as structural modulation, surface modification, heteroatom doping, and defect engineering. Furthermore, the mechanisms, behaviors, and improvements of metal-based composites applied to phosphate electrosorption are comprehensively detailed for the first time. The challenges and prospects of future research in this field are also evaluated and elucidated.

CHEMICAL ENGINEERING JOURNAL (2022)

Article Engineering, Environmental

Remarkable phosphate electrosorption/desorption by bimetallic MOF-derived hierarchically porous carbon electrode: In-situ creation of multiple active centers and boosting electrochemical activities

Mingming He, Peng Zhang, Silu Huo, Xueli Zhang, Ao Gong, Wei Zhang, Kexun Li

Summary: In this study, an electro-assisted adsorption method was proposed and a novel electrode material was fabricated for efficient phosphate electrosorption. The synergistic effects of Zr and Al were found to enhance the reaction rate and removal capacity of the electrode. Furthermore, the electro-assisted phosphate removal demonstrated low energy consumption and operating cost.

CHEMICAL ENGINEERING JOURNAL (2022)

Article Engineering, Chemical

Hierarchical N-Doped porous 3D network electrode with enhanced capacitive deionization performance

Mingming He, Mingzhu Zong, Peng Zhang, Silu Huo, Xueli Zhang, Xue Song, Kexun Li

Summary: In this study, nitrogen-doped porous carbon (NPC) was synthesized and facilely activated to obtain hierarchical porous carbon (KNPC) for capacitive deionization (CDI) desalination. The optimized KNPC exhibited outstanding desalination performance and regeneration performance, which can be attributed to its abundant pore structures, large specific surface area, and excellent electrochemical properties.

SEPARATION AND PURIFICATION TECHNOLOGY (2022)

Article Engineering, Chemical

From MOF to Al/N-doped porous carbon: Creating multiple capture sites for efficient capacitive deionization defluorination

Wei Zhang, Peng Zhang, Fukuan Li, Mingminf He, Ao Gong, Weizhe Zhang, Xiaoping Mo, Kexun Li

Summary: Fluorine pollution is a major global concern, and metal-organic frameworks (MOFs) have unique chemical reactivity and broad functionalities as potential fluoride adsorbents. However, their application is limited by instability and difficult separation. In this study, a lotus flower-like Al/N-doped porous carbon composite was prepared using Al-based MOF as a precursor and was used for capacitive deionization (CDI) defluorination. The carbon material derived from the MOF showed a larger specific surface area and N-rich structure, as well as multiple F- capture sites. Through the CDI defluorination system, F- was rapidly captured under the synergistic effect of metal sites and carbon substrate. The maximum F- removal capacity was 76.28 mg g(-1) at 1.2 V, and the adsorption kinetics followed a pseudo-second-order model. This electroenhanced adsorption method showed high adsorption capacity and selectivity for F-.

DESALINATION (2022)

Article Engineering, Chemical

Opposite role of humic acid in capacitive desalination system using intercalation electrode: Effect of electrode crystal structure

Yubo Zhao, Yang Song, Kexun Li, Feiyong Chen, Bing Liu, Lun Meng

Summary: This study investigates the relationship between crystal microstructures of intercalation electrodes and desalination performance in the presence of naturally occurring organic matters (NOM), with a focus on the impact of humic acid (HA). The results show that HA has contrasting effects on the ion storage performances of tunnel and layered sodium manganese oxides (T-NMO and L-NMO) electrodes. HA causes capacity fading in T-NMO electrodes due to crystal lattice contraction, hinderance of ions diffusion, and electrode dissolution. On the other hand, HA insertion enlarges the interlayer distance and diminishes electrode dissolution in L-NMO electrodes, resulting in an improvement of ion storage capacity. These findings provide important guidance for the design and deployment of CDI in real-world applications.

SEPARATION AND PURIFICATION TECHNOLOGY (2023)

Article Chemistry, Physical

Engineering bimetallic capture sites on hierarchically porous carbon electrode for efficient phosphate electrosorption: multiple active centers and excellent electrochemical properties

Peng Zhang, Mingming He, Fukuan Li, Dezhi Fang, Kexun Li, Hao Wang

Summary: Excessive phosphate in water bodies is a major concern, and electro-assisted adsorption technology shows great potential for wastewater treatment. In this study, bimetallic Ti-La active centers were created on hierarchically porous carbon electrode materials resulting in TLPC2, which exhibited exceptional phosphate removal capability. The coupling of electric field, ligand exchange, oxygen vacancy sites consumption, and electrostatic attraction contribute to the superior performance of TLPC2. This study provides insight into phosphate electrosorption and promotes the development of highly efficient electrode materials.

JOURNAL OF MATERIALS CHEMISTRY A (2023)

Article Engineering, Environmental

Efficient nitrate removal by nitrogen-doped carbon spheres electrodes with interconnected architecture in novel stirring capacitive deionization: Dual promoting effect of facile mass transfer and additional active centers

Chen Li, Zheng Fang, Benqiang Cen, Peng Zhang, Fukuan Li, Dezhi Fang, Mingming He, Changhua Zhang, Jia Liu, Xiaoping Mo, Kexun Li

Summary: This study demonstrates the efficient removal of nitrate from water using a novel stirring capacitive deionization (CDI) system with nitrogen-doped carbon spheres (NCS) as the electrode material. The NCS-900 electrodes exhibited an interconnected framework and controllable mesoporous structure, which enhanced the transfer and diffusion of nitrate ions and resulted in excellent specific capacitive properties. The CDI system achieved an ultrahigh nitrate electrosorption capacity and rapid removal rate, surpassing previously reported nitrate capture electrodes. Furthermore, the stability and selectivity of nitrate electrosorption were well maintained in comprehensive conditions and actual sewage.

CHEMICAL ENGINEERING JOURNAL (2023)

Article Engineering, Chemical

Coeffect of Co-Mn in bimetallic oxide catalyst for ultrafast electrochemical reduction of nitrate: Insight into ion interaction

Weizhe Zhang, Fukuan Li, Peng Zhang, Wei Zhang, Shuai Liu, Cuicui Lv, Kexun Li

Summary: This study investigates the synergistic effect of Co3O4 and Mn on the electroreduction of nitrate. The results show that the electrodes doped with Mn, such as Mn1.5Co1.5O4 and 3-Mn/Co, exhibit significantly higher nitrate removal efficiency compared to Co3O4, confirming the existence of the Co-Mn coeffect.

SEPARATION AND PURIFICATION TECHNOLOGY (2024)

Article Agricultural Engineering

Carbamazepine facilitated horizontal transfer of antibiotic resistance genes by enhancing microbial communication and aggregation

Yinping Xiang, Meiying Jia, Rui Xu, Jialu Xu, Lele He, Haihao Peng, Weimin Sun, Dongbo Wang, Weiping Xiong, Zhaohui Yang

Summary: This study investigated the impact of the non-antibiotic pharmaceutical carbamazepine on antibiotic resistance genes (ARGs) during anaerobic digestion. The results showed that carbamazepine induced the enrichment of ARGs and increased the abundance of bacteria carrying these genes. It also facilitated microbial aggregation and intercellular communication, leading to an increased frequency of ARGs transmission. Moreover, carbamazepine promoted the acquisition of ARGs by pathogens and elevated their overall abundance.

BIORESOURCE TECHNOLOGY (2024)

Review Agricultural Engineering

A review of microbial responses to biochar addition in anaerobic digestion system: Community, cellular and genetic level findings

Weixin Zhao, Tianyi Hu, Hao Ma, Dan Li, Qingliang Zhao, Junqiu Jiang, Liangliang Wei

Summary: This review summarizes the effects and potential mechanisms of biochar on microbial behavior in AD systems. The addition of biochar has been found to promote microbial colonization, alleviate stress, provide nutrients, and enhance enzyme activity. Future research directions include targeted design of biochar, in-depth study of microbial mechanisms, and improved models.

BIORESOURCE TECHNOLOGY (2024)

Review Agricultural Engineering

Advances in nitrogen removal and recovery technologies from reject water: Economic and environmental perspectives

Christina Karmann, Anna Magrova, Pavel Jenicek, Jan Bartacek, Vojtech Kouba

Summary: This review assesses nitrogen removal technologies in reject water treatment, highlighting the differences in environmental impacts and economic benefits. Partial nitritation-anammox shows potential for economic benefits and positive environmental outcomes when operated and controlled properly.

BIORESOURCE TECHNOLOGY (2024)

Article Agricultural Engineering

Layered double hydroxide loaded pinecone biochar as adsorbent for heavy metals and phosphate ion removal from water

Wei-Hao Huang, Ying-Ju Chang, Duu-Jong Lee

Summary: This study modified pinecone biochar with layered double hydroxide (LDH) to enhance its adsorption capacity for heavy metal and phosphate ions. The LDH-biochar showed significantly improved adsorption capacities for Pb2+ and phosphate, and a slight increase for Cu2+ and Co2+. The LDH layer enhanced the adsorption through various mechanisms.

BIORESOURCE TECHNOLOGY (2024)

Article Agricultural Engineering

Machine learning-based prediction of methane production from lignocellulosic wastes

Chao Song, Fanfan Cai, Shuang Yang, Ligong Wang, Guangqing Liu, Chang Chen

Summary: This paper developed a machine learning model to predict the biochemical methane potential during anaerobic digestion. Model analysis identified lignin content, organic loading, and nitrogen content as key attributes for methane production prediction. For feedstocks with high cellulose content, early methane production is lower but can be improved by prolonging digestion time. Moreover, lignin content exceeding a certain value significantly inhibits methane production.

BIORESOURCE TECHNOLOGY (2024)

Article Agricultural Engineering

Engineering of Yarrowia lipolytica as a platform strain for producing adipic acid from renewable resource

Sang Min Lee, Ju Young Lee, Ji-Sook Hahn, Seung-Ho Baek

Summary: This study successfully developed an efficient platform strain using Yarrowia lipolytica for the bioconversion of renewable resources into adipic acid, achieving a remarkable increase in production level.

BIORESOURCE TECHNOLOGY (2024)

Article Agricultural Engineering

Synergies of pH-induced calcium phosphate precipitation and magnetic separation for energy-efficient harvesting of freshwater microalgae

Sefkan Kendir, Matthias Franzreb

Summary: This study presents a novel approach using magnetic separation to efficiently harvest freshwater microalgae, Chlorella vulgaris. By combining pH-induced calcium phosphate precipitation with cheap natural magnetite microparticles, harvesting efficiencies up to 98% were achieved in the model medium.

BIORESOURCE TECHNOLOGY (2024)

Article Agricultural Engineering

Solvothermal liquefaction of orange peels into biocrude: An experimental investigation of biocrude yield and energy compositional dependency on process variables

Ishaq Kariim, Ji-Yeon Park, Wajahat Waheed Kazmi, Hulda Swai, In-Gu Lee, Thomas Kivevele

Summary: The impact of reaction temperature, residence time, and ethanol: acetone on the energy compositions and yield enhancement of biocrudes was investigated. The results showed that under appropriate conditions, biocrudes with high energy and low oxygen content can be obtained, indicating a high potential for utilization.

BIORESOURCE TECHNOLOGY (2024)

Article Agricultural Engineering

Enhancing nitrogen removal performance through intermittent aeration in continuous plug-flow anaerobic/aerobic/anoxic process treating low-strength municipal sewage

Xiyue Zhang, Xiyao Li, Liang Zhang, Yongzhen Peng

Summary: Intermittent aeration is an innovative approach to enhance nitrogen removal in low carbon-to-nitrogen ratio municipal sewage, providing an efficient strategy for the continuous plug-flow AOA process.

BIORESOURCE TECHNOLOGY (2024)

Article Agricultural Engineering

Mechanism of magnetite-assisted aerobic composting on the nitrogen cycle in pig manure

Xu Yang, Mahmoud Mazarji, Mengtong Li, Aohua Li, Ronghua Li, Zengqiang Zhang, Junting Pan

Summary: This study investigated the impact of magnetite on the nitrogen cycle of pig manure biostabilisation. The addition of magnetite increased N2O emissions and decreased NH3 emissions during composting. It also increased the total nitrogen content but should be considered for its significant increase in N2O emissions in engineering practice.

BIORESOURCE TECHNOLOGY (2024)

Review Agricultural Engineering

Recent advances in microalgal production, harvesting, prediction, optimization, and control strategies

Ty Shitanaka, Haylee Fujioka, Muzammil Khan, Manpreet Kaur, Zhi-Yan Du, Samir Kumar Khanal

Summary: The market value of microalgae has exponentially increased in the past two decades, thanks to their applications in various industries. However, the supply of high-value microalgal bioproducts is limited due to several factors, and strategies are being explored to overcome these limitations and improve microalgae production, thus increasing the availability of algal-derived bioproducts in the market.

BIORESOURCE TECHNOLOGY (2024)

Article Agricultural Engineering

Efficient supply with carbon dioxide from flue gas during large scale production of microalgae: A novel approach for bioenergy facades

Martin Kerner, Thorsten Wolff, Torsten Brinkmann

Summary: The efficiency of using enriched CO2 from flue gas for large-scale production of green microalgae has been studied. The results show that the use of membrane devices and static mixers can effectively improve the CO2 recovery rate and maintain the suitable pH and temperature during cultivation, achieving a more economical and sustainable microalgae production.

BIORESOURCE TECHNOLOGY (2024)

Article Agricultural Engineering

Carbon dioxide and methane as carbon source for the production of polyhydroxyalkanoates and concomitant carbon fixation

Rui Ma, Ji Li, Rd Tyagi, Xiaolei Zhang

Summary: This review summarizes the microorganisms capable of using CO2 and CH4 to produce PHAs, illustrating the production process, factors influencing it, and discussing optimization techniques. It identifies the challenges and future prospects for developing economically viable PHAs production using GHGs as a carbon source.

BIORESOURCE TECHNOLOGY (2024)

Article Agricultural Engineering

Contribution of zeolite to nitrogen retention in chicken manure and straw compost: Reduction of NH3 and N2O emissions and increase of nitrate

Bing Wang, Peng Zhang, Xu Guo, Xu Bao, Junjie Tian, Guomin Li, Jian Zhang

Summary: The addition of zeolite in the co-composting of chicken manure and straw significantly reduced the emissions of ammonia and N2O, and increased the nitrate content. Zeolite also promoted the abundance of nitrification genes and inhibited the expression of denitrification genes.

BIORESOURCE TECHNOLOGY (2024)

Article Agricultural Engineering

Exploring advanced phycoremediation strategies for resource recovery from secondary wastewater using a large scale photobioreactor

Rohit Dey, Franziska Ortiz Tena, Song Wang, Josef Martin Messmann, Christian Steinweg, Claudia Thomsen, Clemens Posten, Stefan Leu, Matthias S. Ullrich, Laurenz Thomsen

Summary: This study investigated the operation of a 1000L microalgae-based membrane photobioreactor system for continuous secondary wastewater treatment. The research focused on a green microalgae strain called Desmodesmus sp. The study aimed to understand key trends and optimization strategies by conducting experiments in both summer and winter seasons. The findings showed that maintaining low cell concentrations during periods of light inhibition was beneficial for nutrient uptake rates. Effective strategies for enhancing algae-based wastewater treatment included cell mass recycling and adjusting dilution rates based on light availability.

BIORESOURCE TECHNOLOGY (2024)