Journal
BIORESOURCE TECHNOLOGY
Volume 206, Issue -, Pages 204-210Publisher
ELSEVIER SCI LTD
DOI: 10.1016/j.biortech.2016.01.095
Keywords
Barley straw (Hordeum vulgare); Solid catalyst; Oxalic acid dihydrate; Mechanocatalytical conversion; Lignocellulose
Funding
- Fortum Foundation (Helsinki, Finland) [201500046]
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This study describes a time and energy saving, solvent-free procedure for the conversion of lignocellulosic barley straw into reducing sugars by mechanocatalytical pretreatment. The catalytic conversion efficiency of several solid acids was tested which revealed oxalic acid dihydrate as a potential catalyst with high conversion rate. Samples were mechanically treated by ball milling and subsequently hydrolyzed at different temperatures. The parameters of the mechanical treatment were optimized in order to obtain sufficient amount of total reducing sugar (TRS) which was determined following the DNS assay. Additionally, capillary electrophoresis (CE) and Fourier transform infrared spectrometry (FT-IR) were carried out. Under optimal conditions TRS 42% was released using oxalic acid dihydrate as a catalyst. This study revealed that the acid strength plays an important role in the depolymerization of barley straw and in addition, showed, that the oxalic acid-catalyzed reaction generates low level of the degradation product 5-hydroxymethylfurfural (HMF). (C) 2016 Elsevier Ltd. All rights reserved.
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