Base-Promoted Chemodivergent Formation of 1,4-Benzoxazepin-5(4H)-ones and 1,3-Benzoxazin-4(4H)-ones Switched by Solvents

Chemodivergent Oxidative Annulation of Benzamides and Enynes via 1,4-Rhodium Migration

(2019) Jiaqiong Sun et al.   ORGANIC LETTERS

Base-Promoted SNAr Reactions of Fluoro- and Chloroarenes as a Route to N-Aryl Indoles and Carbazoles

(2019) Muhammad Iqbal et al.   MOLECULES

Quinazolinone Synthesis through Base-Promoted SNAr Reaction of ortho-Fluorobenzamides with Amides Followed by Cyclization

(2019) Muhammad Asif Iqbal et al.   ACS Omega

Acetylenes in the Superbase-Promoted Assembly of Carbocycles and Heterocycles

(2018) Boris A. Trofimov et al.   ACCOUNTS OF CHEMICAL RESEARCH

Ligand-Directed Divergent Synthesis of Carbo- and Heterocyclic Ring Systems

(2018) Yen-Chun Lee et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ligand- and Solvent-Controlled Regio- and Chemodivergent Carbonylative Reactions

(2018) Jin-Bao Peng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium(iii)-catalyzed chemodivergent annulations between N-methoxybenzamides and sulfoxonium ylides via C–H activation

(2018) Youwei Xu et al.   CHEMICAL COMMUNICATIONS

NaI-mediated divergent synthesis of isatins and isoindigoes: a new protocol enabled by an oxidation relay strategy

(2018) Hong-hua Zhang et al.   CHEMICAL COMMUNICATIONS

Divergent Strategy in Natural Product Total Synthesis

(2018) Lei Li et al.   CHEMICAL REVIEWS

Solvent-Dependent Copper-Catalyzed Indolyl C3-Oxygenation and N1-Cyclization Reactions: Selective Synthesis of 3H-Indol-3-ones and Indolo[1,2-c]quinazolines

(2018) Shenghai Guo et al.   JOURNAL OF ORGANIC CHEMISTRY

Synthesis of Heterocycles by Using Propargyl Compounds as Versatile Synthons

(2018) Ruimao Hua et al.   MINI-REVIEWS IN ORGANIC CHEMISTRY

Base-promoted nucleophilic fluoroarenes substitution of C F bonds

(2018) Ji Su et al.   TETRAHEDRON

Palladium-Catalyzed Solvent-Dependent Divergent Synthesis of Benzylformamides

(2018) Fu-Peng Wu et al.   ADVANCED SYNTHESIS & CATALYSIS

Metamorphosis of cycloalkenes for the divergent total synthesis of polycyclic indole alkaloids

(2018) Zhengren Xu et al.   CHEMICAL SOCIETY REVIEWS

Rh(III)-Catalyzed and Solvent-Controlled Chemoselective Synthesis of Chalcone and Benzofuran Frameworks via Synergistic Dual Directing Groups Enabled Regioselective C–H Functionalization: A Combined Experimental and Computational Study

(2018) Wei Yi et al.   ACS Catalysis

AlCl3-Catalyzed Intramolecular Cyclization of N-Arylpropynamides with N-Sulfanylsuccinimides: Divergent Synthesis of 3-Sulfenyl Quinolin-2-ones and Azaspiro[4,5]trienones

(2017) Wen-Chao Gao et al.   JOURNAL OF ORGANIC CHEMISTRY

Divergent Rhodium-Catalyzed Cyclization Reactions of Enoldiazoacetamides with Nitrosoarenes

(2017) Qing-Qing Cheng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Solvent-Controlled Switchable Domino Reactions of MBH Carbonate: Synthesis of Benzothiophene Fused α-Pyran, 2,3-Dihydrooxepine, and Oxatricyclodecene Derivatives

(2017) Jiru Jia et al.   ORGANIC LETTERS

Silver-catalyzed chemoselective annulation of propargyl amines with alkynes for access to pyridines and pyrroles

(2017) Tauqir A. Nizami et al.   TETRAHEDRON

Development of Selective CBP/P300 Benzoxazepine Bromodomain Inhibitors

(2016) Tobias A. Popp et al.   JOURNAL OF MEDICINAL CHEMISTRY

Catalyst-Free Chemoselective Synthesis of 3,4-Dihydroquinazoline-2-thiones and 2-Imino[1,3]benzothiazines

(2016) Ting Xie et al.   JOURNAL OF ORGANIC CHEMISTRY

The Divergent Synthesis of Nitrogen Heterocycles by Rhodium(I)-Catalyzed Intermolecular Cycloadditions of Vinyl Aziridines and Alkynes

(2016) Jian-Jun Feng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Divergent Synthesis of Carbo- and Heterocycles via Gold-Catalyzed Reactions

(2016) Yin Wei et al.   ACS Catalysis

Solvent-Enabled Radical Selectivities: Controlled Syntheses of Sulfoxides and Sulfides

(2015) Huamin Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium catalyzed Csp2–H activation for direct aryl hydroxylation: the unprecedented role of 1,4-dioxane as a source of hydroxyl radicals

(2015) Kapileswar Seth et al.   CHEMICAL COMMUNICATIONS

Synthesis of 2-Fluoro-1,4-benzoxazines and 2-Fluoro-1,4-benzoxazepin-5-ones by Exploring the Nucleophilic Vinylic Substitution (SNV) Reaction of gem-Difluoroenamides

(2015) Tamara Meiresonne et al.   JOURNAL OF ORGANIC CHEMISTRY

Catalytic Divergent Synthesis of 3H or 1H Pyrroles by [3 + 2] Cyclization of Allenoates with Activated Isocyanides

(2015) Jia-Yu Liao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Experimental and DFT Studies Explain Solvent Control of C–H Activation and Product Selectivity in the Rh(III)-Catalyzed Formation of Neutral and Cationic Heterocycles

(2015) David L. Davies et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Process Development and Scale-Up of a Benzoxazepine-Containing Kinase Inhibitor

(2015) Sriram Naganathan et al.   ORGANIC PROCESS RESEARCH & DEVELOPMENT

Cesium hydroxide-catalyzed isomerization of terminal alkynes for the synthesis of O-allenes and N-allenes

(2015) You Li et al.   TETRAHEDRON LETTERS

Cycloaddition of 1,3-Butadiynes: Efficient Synthesis of Carbo- and Heterocycles

(2014) Tauqir Nizami et al.   MOLECULES

Base mediated 7-exo-dig intramolecular cyclization of Ugi–propargyl precursors: a highly efficient and regioselective synthetic approach toward diverse 1,4-benzoxazepine-5(2H)-ones

(2014) Shashi Pandey et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Stereodivergent Ruthenium-Catalyzed Transfer Semihydrogenation of Diaryl Alkynes

(2011) Jie Li et al.   CHEMISTRY-A EUROPEAN JOURNAL

Synthesis and evaluation of 7-substituted-3,4-dihydrobenzo[f][1,4]oxazepin-5(2H)-ones as anticonvulsant and hypnotic agents

(2010) Xian-Qing Deng et al.   MEDICINAL CHEMISTRY RESEARCH

Rhodium(I)-Catalyzed Reductive Cyclocarbonylation of Internal Alkynes: Atom-Economic Process for Synthesis of 2-Cyclopenten-1-ones, 5-Alkylidenefuran-2(5 H)-ones and Indan-1-ones

(2009) Qiufeng Huang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Domino Ring-Opening/Carboxamidation Reactions ofN-Tosyl Aziridines and 2-Halophenols/Pyridinol: Efficient Synthesis of 1,4-Benzo- and Pyrido-oxazepinones

(2009) Gagan Chouhan et al.   ORGANIC LETTERS