Journal
MICROPOROUS AND MESOPOROUS MATERIALS
Volume 294, Issue -, Pages -Publisher
ELSEVIER
DOI: 10.1016/j.micromeso.2019.109917
Keywords
Hierarchical ZIFs; Cyclic carbonates; Synthesis; Heterogeneous catalyst
Categories
Funding
- National Natural Science Foundation of China [21676095, 21736003]
- Public welfare research project of Guangdong Province [2016A020221004]
- Research Fund Program of Guangdong Provincial Key Lab of Green Chemical Product Technology [GC201820]
- Science and Technology Program of Guangzhou, China [201804020014]
- Guangdong Provincial Laboratory of Green Chemical Technology
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An efficient heterogeneous catalyst hierarchical mixed metal Co/ZIF-8 materials were developed for the cycloaddition reaction between CO2 and styrene oxide. The synthesized hierarchical Co/ZIF-8 have been characterized by powder x-ray diffraction, electron microscope, nitrogen adsorption-desorption and thermal gravimetric analysis. The acid-base characteristics of hierarchical Co/ZIF-8 were investigated by NH3 and CO2 adsorption. A maximum cyclic carbonate yield can be obtained over hierarchical 70% Co/ZIF-8 (Co salt content in the substrates mixture is 70%). The styrene oxide conversion reached 96.8% with a selectivity of 97.9% after 8 h of reaction at 0.05 g catalyst dosage, 120 degrees C, 0.70 MPa. The hierarchical Co/ZIF-8 catalyst can be separated by simple centrifugation and reused at least four times with a little loss of catalytic activity. The hierarchical Co/ZIF8 showed enhanced catalytic activity and excellent recyclability and are thus potential heterogeneous catalysts in various catalytic reactions.
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