Journal
MICROCHIMICA ACTA
Volume 186, Issue 11, Pages -Publisher
SPRINGER WIEN
DOI: 10.1007/s00604-019-3824-8
Keywords
Phenol-formaldehyde resin; Molecular imprinting; Molybdenum disulfide; Self-assembly; Pluronic F127
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Funding
- National Natural Science Foundation of China [21775112]
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A space-confined synthesis method is employed for the preparation of a single-layer MoS2-boron doped ordered mesoporous carbon nanocomposite. A phenol-formaldehyde resin is used as carbon source to create a confined space for the formation of single-layer MoS2. The addition of pluronic F127, as a soft template, suppresses the stacking of MoS2 layers and makes the composite porous. The nanocomposite is characterized by scanning electron and transmission electron microscopy, X-ray diffraction, X-ray photoelectron spectroscopy and energy dispersive X-ray spectroscopy. The single-layer MoS2 sheets have a lateral size of about 5 nm and are uniformly embedded in the composite. They possess numerous active edge sites and display a strong synergistic effect with other components. The composite is modified on a glassy carbon electrode, followed by the electrochemical imprinting of theophylline, and the resulting electrode exhibits good electrochemical response to theophylline. The linear response range is 0.01-250 mu M by differential pulse voltammetry, and the lower detection limit is 5 nM. It has been successfully applied to the determination of theophylline in spiked tea drink samples.
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