4.6 Article

Design and preparation of SnO2/SnS2/conjugated polyvinyl chloride derivative ternary composite with enhanced visible-light photocatalytic activity

Journal

MATERIALS RESEARCH BULLETIN
Volume 118, Issue -, Pages -

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.materresbull.2019.110524

Keywords

Composites; Nanostructures; Chemical synthesis; Raman spectroscopy; Catalytic properties

Funding

  1. Natural Science Foundation of Jiangsu Province [BK20171282]

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A new high-efficiency ternary composite photocatalyst (SnO2/SnS2/conjugated polyvinyl chloride derivative (CPVC)) was designed based on the hypothesis that any two of its components can constitute type-II heterojunction, and its three components should have synergistic effect on the enhancement of photoinduced charge separation. SnO2/SnS2/CPVC ternary composite was prepared adopting an easy-to-implement four-step synthesis method. Photoluminescence and electrochemical impedance spectra showed that SnO2/SnS2/CPVC is more efficient than SnO2/SnS2, SnS2/CPVC, SnO2/CPVC and SnS2 in the separation and transfer of photoinduced charges. Results from their photocatalytic reduction of Cr(VI) under visible-light irradiation indicated that SnO2/SnS2/CPVC has significantly higher visible-light photocatalytic activity than SnO2/SnS2, SnS2/CPVC, SnO2/CPVC, SnS2, CPVC and SnO2. Moreover, SnO2/SnS2/CPVC also demonstrated good photocatalytic reusability and stability. This study not only has developed a new high-activity visible-light photocatalyst (SnO2/SnS2/CPVC), but is also useful for the design of other new ternary composite photocatalysts with synergistically enhanced visible-light photocatalysis.

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