Journal
MATERIALS AND CORROSION-WERKSTOFFE UND KORROSION
Volume 71, Issue 4, Pages 537-542Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/maco.201911304
Keywords
compressive residual stress; corrosion; current transient; metastable pit; XPS
Funding
- Sihui Science and Technology Programme [2017A0101001]
- National Natural Science Foundation of China [51701047]
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Metastable pitting behaviour of austenite stainless steel after compressive deformation in an acidic NaCl solution was investigated. The results show that the pit initiation rate increases while both metastable pit lifetime and growth rate decrease after compressive deformation. Meanwhile, the ratio of the surface oxide fraction of Cr to Fe increases whereas the average size of stable pits is smaller and shallow disk-shaped under compressive residual stress. The results reveal that with the aid of enrichment of Cr oxides and compressive residual stress, which helps break the remnants of the undermined passive film, pit repassivation can be accelerated.
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