4.4 Article

Effect of anodizing on galvanic corrosion behavior of T300 CFRP/5083P-O Al bolted joints

Journal

MATERIALS AND CORROSION-WERKSTOFFE UND KORROSION
Volume 71, Issue 3, Pages 409-418

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/maco.201911235

Keywords

5083P-O Al; anodizing; CFRP; galvanic corrosion

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T300 carbon fiber reinforced polymer (CFRP) and 5083P-O aluminum (5083P-O Al) alloy bolted joints have been used in high-speed trains due to the advantages of light weight and high strength. However, high potential difference between the CFRP and 5083P-O Al will induce galvanic corrosion and result in accelerating corrosion rate of 5083P-O Al, which is a potential risk for its engineering applications. In this work, combination with the electrochemical analysis, surface and cross-section corrosive morphologies analysis, the galvanic corrosion behavior between CFRP/5083P-O Al bolted joints with and without anodizing in 3.5 wt.% NaCl spray was investigated. Results indicated that severe corrosion occurred on unanodized 5083P-O Al in the coupled regions of the CFRP/5083P-O Al bolted joint due to galvanic corrosion. With the content of sulfuric acid increasing, the thickness of each Al2O3 layer and atomic oxygen content increases significantly. 5083P-O Al anodized by the 135 g/L H2SO4 + 8 g/L H3BO3 mixed solution had the favorable Al2O3 film, which increased the resistance of 5083P-O Al by roughly three orders of magnitude, effectively improving the corrosion resistance of 5083P-O Al.

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