Article
Agricultural Engineering
Jingjing Liao, Nicolas Brosse, Sandrine Hoppe, Xiaojian Zhou, Xuedong Xi, Guanben Du, Antonio Pizzi
Summary: Bio-composites based on tannin acetate and polylactic acid (PLA) were successfully prepared with improved molecular weight, Young's modulus, and tensile strength, showing strong interfacial adhesion. Enhanced thermal stability and crystallinity were observed, along with a more hydrophobic characteristic suitable for food packaging applications.
INDUSTRIAL CROPS AND PRODUCTS
(2021)
Article
Polymer Science
Sofia P. Makri, Eleftheria Xanthopoulou, Miguel Angel Valera, Ana Mangas, Giacomo Marra, Victor Ruiz, Savvas Koltsakidis, Dimitrios Tzetzis, Alexandros Zoikis Karathanasis, Ioanna Deligkiozi, Nikolaos Nikolaidis, Dimitrios Bikiaris, Zoi Terzopoulou
Summary: In this study, PLA composites with 0.5 wt% lignin or nanolignin were prepared using conventional melt-mixing and in situ Ring Opening Polymerization (ROP) methods. The reactive processing method allowed for rapid synthesis of the composites in less than 20 minutes, with a reduction in reaction time to under 15 minutes when the catalyst amount was doubled. The resulting composites were evaluated for their dispersion, thermal transitions, mechanical properties, antioxidant activity, and optical properties, showing improved properties when nanolignin was used in the reactive processing.
Article
Polymer Science
Zoi Terzopoulou, Alexandra Zamboulis, Dimitrios N. Bikiaris, Miguel Angel Valera, Ana Mangas
Summary: Block copolymers with tunable properties based on poly(lactic acid) were prepared via reactive extrusion, successfully increasing the elongation and biodegradation rate of PLA. Reactive extrusion is an efficient and economical method for the fast and continuous synthesis of PLA-based copolymers.
Article
Biochemistry & Molecular Biology
Wen-Xiang Ou, Yunxuan Weng, Jian-Bing Zeng, Yi-Dong Li
Summary: Improved compatibility and interfacial adhesion of PLA/lignin composites were achieved through reactive compatibilization with epoxidized natural rubber (ENR) as a compatibilizer. The interfacial reaction of ENR with both PLA and lignin was confirmed by morphology analysis and Fourier transform infrared spectroscopy. The incorporation and increase in the content of ENR significantly enhanced the compatibility, interfacial adhesion, and mechanical properties of the composites.
INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES
(2023)
Article
Polymer Science
Massimiliano Barletta, Elisa Pizzi
Summary: This work focuses on the design and experimental development of bioplastic materials for high-performance packaging products suitable for food contact, characterized by high thermo-mechanical stability. By adding nucleating agents, four different PLA/PBS formulations were produced and the crystallinity of the materials was evaluated using various analysis methods.
JOURNAL OF APPLIED POLYMER SCIENCE
(2021)
Article
Polymer Science
Laura Aliotta, Alessandro Vannozzi, Daniele Bonacchi, Maria-Beatrice Coltelli, Andrea Lazzeri
Summary: Two different typologies of hazelnuts shell powders were melt-compounded into a PLA matrix with varying concentrations to achieve biocomposites with high filler quantity and acceptable mechanical properties. The scaled-up composites showed improved mechanical and melt fluidity properties compared to lab-scaled composites due to efficient removal of residual moisture. Analytical models were used to predict mechanical properties trend and analyze the interfacial adhesion between fillers and matrix.
Article
Biochemistry & Molecular Biology
Dawei Luo, Weijun Zhen, Chengyuan Dong, Ling Zhao
Summary: In this study, amino-functionalized nano-SiO2 (m@g-SiO2) was synthesized and used as fillers to prepare PLA/m@g-SiO2 nanocomposites, improving their mechanical properties, crystallization behavior, and thermal stability. The surface modification of m@g-SiO2 significantly enhanced the interaction energy and miscibility between the filler and PLA bulk, as confirmed by multi-scale investigation through rheological behaviors analysis and molecular dynamics simulations.
INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES
(2021)
Article
Polymer Science
Gizem Urtekin, Ayse Aytac
Summary: The study investigated the effects of different functional groups of multi-walled carbon nanotubes on the properties of polycarbonate/poly(lactic acid) nanocomposites. Functionalization was confirmed by FTIR analysis, showing that MWCNT-OH increased the onset decomposition temperature significantly, while MWCNT-COOH improved the elongation at break, tensile strength, and modulus. The selective localization of PC-g-MWCNT provided the highest electrical conductivity in the nanocomposites.
JOURNAL OF POLYMER RESEARCH
(2021)
Review
Chemistry, Physical
Ilaria Cusano, Laura Campagnolo, Marco Aurilia, Salvatore Costanzo, Nino Grizzuti
Summary: Polyethylene terephthalate (PET) is widely used in various fields, and its recycling has become important due to its contribution to global solid waste. The mechanical properties of recycled PET are inferior to those of virgin material, so chain extension is needed to improve the final product. Reactive extrusion is commonly used for chain extension, and rheological studies play a crucial role in understanding the process and tailoring the mechanical properties of recycled PET.
Article
Chemistry, Physical
Jacek Andrzejewski, Michal Nowakowski
Summary: This study focused on developing flax fiber reinforced composites using a PLA/PBAT blend system to improve impact properties and reduce brittleness. The addition of a chain extender in the form of an epoxy-functionalized oligomer improved modulus and strength, while the use of PBAT as an impact modifier reduced PLA brittleness. The study also showed that the reactive extrusion process enhanced fiber-matrix interactions, resulting in higher stiffness and strength.
Article
Biochemistry & Molecular Biology
Zhaoliang Jiang, Meng Ma, Xinpeng Wang, Si Chen, Yanqin Shi, Huiwen He, Xu Wang
Summary: Researchers have successfully designed and synthesized a bio-based flame retardant, APP@CS, by electrostatic self-assembly method and prepared toughened PLLA composites. The CS shell not only reduces the hydrophilicity of the flame retardant, but also exhibits excellent flame retardant property. The addition of 10 phr APP@CS improves the flame retardancy to UL-94 V-2 rating and increases the LOI value to 24.9% for PLLA/CPU composites. Furthermore, the CS shell participates in an in-situ reaction, resulting in improved mechanical properties of the composite.
INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES
(2023)
Article
Engineering, Environmental
Pankaj Agrawal, Aylanna P. M. Araujo, Gustavo F. Brito, Shirley N. Cavalcanti, Amanda M. Alves, Daniel M. G. Freitas, Tomas J. A. Melo
Summary: The study investigated the effects of OMMT and OVT clays, as well as EMA-GMA copolymer, on the properties of PLA/BioPE composites, showing improvements in impact strength and reductions in glass transition and cold crystallization temperatures. Rheological properties were significantly altered with the addition of EMA-GMA copolymer to the biocomposites.
JOURNAL OF POLYMERS AND THE ENVIRONMENT
(2021)
Article
Materials Science, Multidisciplinary
Maria-Beatrice Coltelli, Laura Aliotta, Gianluca Fasano, Filip Miketa, Filip Brkic, Rafael Alonso, Marco Romei, Patrizia Cinelli, Ilaria Canesi, Vito Gigante, Andrea Lazzeri
Summary: Poly(lactic acid)/poly(butylene succinate-co-adipate) (PLA/PBSA) blends are promising for film packaging due to their flexibility, resistance, and compostability. The blends were tested in terms of melt flow rate as a function of PBSA content, both through mini-extrusion and injection molding cycles. The results showed negligible variation in melt fluidity and thermo-mechanical properties for up to 3 injection molding cycles, with evident color changes in the blend.
MACROMOLECULAR MATERIALS AND ENGINEERING
(2023)
Article
Polymer Science
Muhammad Saeed Ullah, Rumeysa Yildirim, Lulia Caraseva, Ester Zuza, Guralp Ozkoc, Mehmet Kodal
Summary: This study investigates the effect of mono- and multi-epoxide POSS nanoparticles on the compatibility of PLA/PBS blends from a rheological perspective. The addition of PBS reduces the viscosity and moduli, indicating weak interactions between polymers. However, the presence of MoEpPOSS and MuEpPOSS increases viscosity and moduli by forming complex polymeric structures. MuEpPOSS shows stronger interaction due to its multiple epoxide groups. The introduction of POSS improves dispersion, phase homogeneity, and compatibility, as observed in the Cole-Cole plots, and enhances interfacial adhesion.
JOURNAL OF APPLIED POLYMER SCIENCE
(2023)
Article
Chemistry, Multidisciplinary
K. De Smit, Y. W. Marien, P. H. M. Van Steenberge, D. R. D'hooge, M. Edeleva
Summary: Polylactic acid (PLA) is an important polymer that can replace oil-based polymers in the biomedical field and degradable single use materials. Physical or chemical modifications are desired to fully exploit the potential of PLA. Monte Carlo simulations can provide insight into which molecules are modified and how, allowing for in silico design of PLA chemical modification routes.
REACTION CHEMISTRY & ENGINEERING
(2023)