Article
Polymer Science
Romana Kratochvilova, Milan Kracalik, Marcela Smilkova, Petr Sedlacek, Miloslav Pekar, Elke Bradt, Jiri Smilek, Petra Zavodska, Martina Klucakova
Summary: This study aimed to analyze the hydrogels' use in soil by characterizing their FT-IR spectra, morphology, swelling ability, and rheological properties. It was found that lignohumate improved water absorbency, while the addition of NPK had a negative effect. The stability of the hydrogels was affected by repeated drying/re-swelling cycles and freezing.
Review
Polymer Science
Eyal Malka, Shlomo Margel
Summary: This review examines the utilization of environmentally friendly, shapable hydrogels in agriculture for crop protection, fertilizing, and watering. The hydrogels, composed of PVA and PVP, were loaded with hydrophilic and hydrophobic pesticides to effectively control release. The study demonstrates that these hydrogels contribute significantly to the stabilization and controlled release of essential nutrients and biocides for plants.
Article
Polymer Science
Irina Popescu, Marieta Constantin, Irina M. Pelin, Dana M. Suflet, Daniela L. Ichim, Oana M. Daraba, Gheorghe Fundueanu
Summary: PVA/chitosan (PVA/CS) composite hydrogels incorporating silver nanoparticles (AgNPs) were prepared successfully by double-cross-linking methods, resulting in good physicochemical properties and antimicrobial activity.
Article
Chemistry, Physical
Zahra Karimzadeh, Mansour Mahmoudpour, Elaheh Rahimpour, Abolghasem Jouyban
Summary: This review provides an up-to-date and comprehensive summary of the research progress of PVA hydrogel based wearable sensors, including their properties, strain sensory efficiency, and potential applications. The review specifically highlights the probes using metallic/non-metallic, liquid metal, 2D materials, bio-nanomaterials, and polymer nanofillers. The flexible electrodes and strain/pressure sensing performance of designed PVA hydrogels are described. The review also discusses the necessity and requirements for future advances of conductive and stretchable hydrogels engaged in wearable strain sensors, as well as the opportunities and challenges.
ADVANCES IN COLLOID AND INTERFACE SCIENCE
(2022)
Article
Materials Science, Multidisciplinary
Yingqi Chen, Cairong Li, Zhenming Wang, Jing Long, Ruiqi Wang, Jin Zhao, Wanze Tang, Yu Zhao, Ling Qin, Songlin Peng, Yuxiao Lai
Summary: The newly developed CSMAP-MgO hydrogel shows promising performance in stable release of Mg2+, increased compressive modulus, superior promotion of in vitro calcium phosphate deposition, cell proliferation, and osteogenic differentiation compared to Magnesium-free groups. In rat critical-sized calvarial defect experiments, it significantly promotes more new bone formation after 12 weeks.
APPLIED MATERIALS TODAY
(2021)
Article
Engineering, Environmental
Md. Sabbir Hasan, Jannat Al Foisal, G. M. Arifuzzaman Khan, Rownok Jahan, Md. Hasanuzzaman, Md. Shamsul Alam, M. Minnatul Karim, M. A. Gafur, Muhammad Angkan Khan, Md. Abdus Sabur
Summary: Modification of cellulose with silver nanoparticles produces a PVA hydrogel modified with cellulose/silver nanocomposites, which exhibits significant porosity and antimicrobial properties.
JOURNAL OF POLYMERS AND THE ENVIRONMENT
(2022)
Article
Chemistry, Physical
Noor Ul Ain, Farha Masood, Minaal Noor, Muhammad Farooq
Summary: This study demonstrates the potential use of nanocomposite hydrogels as wound dressing materials for the treatment of multidrug-resistant infected wounds. The physical, structural, mechanical, and antibacterial properties of the nanocomposite hydrogels were evaluated, showing good moisture retention capacities and antibacterial effects.
APPLIED CLAY SCIENCE
(2022)
Article
Environmental Sciences
Dennis A. Mwalongo, Nils H. Haneklaus, Jacob B. Lisuma, Thomas T. Kivevele, Kelvin M. Mtei
Summary: Phosphate rock, the primary raw material for mineral phosphate fertilizer production, can contain heavy metal impurities such as cadmium and uranium. This study assesses the concentration of uranium in East African phosphate rocks and fertilizers, finding relatively high concentrations. It recommends establishing public-private partnerships to recover uranium from deposits with the highest concentrations.
ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
(2023)
Article
Biochemistry & Molecular Biology
Pilar Alaman-Diez, Carlos Borau, Pedro Enrique Guerrero, Hippolyte Amaveda, Mario Mora, Jose Maria Fraile, Elena Garcia-Gareta, Jose Manuel Garcia-Aznar, Maria Angeles Perez
Summary: The extracellular matrix (ECM) plays a crucial role in the development and progression of tumoral tissue, affecting tumor cell behavior such as invasion, migration, and malignancy. Our study examines the role of collagen type I in cancer development and spread using engineered tumor models grown in collagen-based hydrogels. We utilize microfluidic techniques to investigate the effects of modifying the mechanical properties of collagen hydrogels with Laponite nanoclay and changing the stiffness of the collagen microenvironment on tumor spheroid growth. Our findings support the use of ECM components and engineered tumor models in cancer research, providing a biocompatible and biomimetic approach to tailor the mechanical properties of conventional collagen hydrogels.
Article
Chemistry, Multidisciplinary
Danila Merino, Andrea Yamila Mansilla, Mariia Florencia Salcedo, Athanassia Athanassiou
Summary: In this study, agar-based hydrogels incorporating different concentrations of orange peel particles and 1.5 wt% limonene were developed as active soil conditioners for agriculture. The results showed that acid hydrolysis or ultrasonication pretreatments of orange peel were counterproductive, and the simplest method of pretreatment resulted in the most efficient hydrogels in terms of swelling. The incorporation of limonene increased the swelling capacity of the hydrogels in tap water, while the incorporation of orange peel particles did not significantly influence their swelling capacity.
ACS SUSTAINABLE CHEMISTRY & ENGINEERING
(2023)
Article
Chemistry, Multidisciplinary
Yadong Yu, Zhaoming Liu, Qian Zhao
Summary: A synergistic toughening strategy was reported for the development of mechanical robust and recyclable nanocomposite hydrogels through in-situ inorganic ionic polymerization of calcium phosphate oligomers within polymer composite networks. The resulting hydrogels exhibited high strength and toughness, controllable mechanical anisotropy, and significant energy absorption/dissipation ability. Moreover, the hydrogels could be easily recycled and regenerated, making them suitable for sustainable large-scale production and application.
ADVANCED FUNCTIONAL MATERIALS
(2023)
Article
Materials Science, Multidisciplinary
Tahani A. Alrebdi, Hoda A. Ahmed, Salhah H. Alrefaee, Rami Adel Pashameah, Arafat Toghan, Ayman M. Mostafa, Fatemah H. Alkallas, Reham A. Rezk
Summary: A nanocomposite material, Ag-doped NiO/PVA, was prepared using multiple laser ablation technique to remove phosphate. The adsorption tests showed that the nanocomposite material has excellent performance in controlling phosphorus contamination in water.
JOURNAL OF MATERIALS RESEARCH AND TECHNOLOGY-JMR&T
(2022)
Article
Chemistry, Multidisciplinary
Yanmin Shen, He Wang, Zijun Liu, Weikun Li, Yuhua Liu, Jingjing Li, Hongliang Wei, Huayun Han
Summary: A new type of water-retaining, slow-release fertilizer based on double-network hydrogels was fabricated, and the presence of halloysite nanotubes clearly adjusted the swelling and release properties of the fertilizer. Kinetic modeling indicated a Fickian diffusion mechanism for the swelling and slow release behavior, suggesting good prospects for application.
JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY
(2021)
Article
Polymer Science
Farzaneh Sabbagh, Nadia Mahmoudi Khatir, Khadijeh Kiarostami
Summary: Nanocomposites were prepared by combining k-carrageenan, polyvinyl alcohol (PVA), and doped nanoparticles (MgO and MgZnO). The structure of the composites was analyzed, and active ingredient catechin was loaded. SEM and texture analysis revealed that MgZnO composites had increased entrapment efficiency and drug release. ZnO played an effective role in the structure and performance of the composites.
Article
Polymer Science
Yasemin Balcik Tamer
Summary: Poly(N-isopropylacrylamide) (P(NIPAAm)) hydrogels crosslinked with biodegradable poly (beta-amino ester) (PBAE) showed higher crosslinking degrees and compressive strength and lower swelling ratios compared to conventional N,N'-methylene bisacrylamide (MBA)-crosslinked hydrogel. The controlled release of KNO3 was achieved with the N/T5/1 sample, which demonstrated the most controlled release with 66.9% after 18 days in soil. The hydrogel with a porosity of 71.65% and crosslinking degree of 2.85 x 10(-5) mol cm(-3) showed promising properties for agricultural applications.
Article
Materials Science, Composites
Ali Reza Zanjanijam, Shokoufeh Hakim, Hamed Azizi
POLYMER COMPOSITES
(2019)
Article
Polymer Science
Mohammad Barghamadi, Mohammad Karrabi, Mir Hamid Reza Ghoreishy, Somayyeh Mohammadian-Gezaz
JOURNAL OF APPLIED POLYMER SCIENCE
(2019)
Article
Polymer Science
Mohammad Barghamadi, Mir Hamid Reza Ghoreishy, Mohammad Karrabi, Somayyeh Mohammadian-Gezaz
JOURNAL OF APPLIED POLYMER SCIENCE
(2020)
Article
Polymer Science
Mohammad Javad Azizli, Mohammad Barghamadi, Katayoon Rezaeeparto, Masoud Mokhtary, Somayeh Parham, Vahabodin Goodarzi, Sedigheh Soltani
Summary: In this study, a series of elastomeric nanocomposites based on PA6/CR blends compatibilized with EPDM-g-MA and GO were prepared and analyzed. The results showed that EPDM-g-MA and GO significantly affected the microstructure and mechanical properties of the samples. The addition of GO as a reinforcement and EPDM-g-MA as a compatibilizer resulted in enhanced thermal stability and mechanical performance of the PA6/CR blends.
JOURNAL OF APPLIED POLYMER SCIENCE
(2021)
Article
Materials Science, Composites
Mohammad Barghamadi, Mir Hamid Reza Ghoreishy, Mohammad Karrabi, Somayyeh Mohammadian-Gezaz
Summary: This research focused on developing multiple material models to describe the mechanical behavior of nanocomposites based on NBR/PVC, and validated the model's accuracy and applicability through experimental data.
POLYMER COMPOSITES
(2021)
Article
Materials Science, Composites
Mohammad Javad Azizli, Mohammad Barghamadi, Katayoon Rezaeeparto, Masoud Mokhtary, Somayeh Parham
COMPOSITES COMMUNICATIONS
(2020)
Article
Polymer Science
Leila Bazli, Mohammad Barghamadi, Sara Shafiee, Mohammad Karrabi, Mir Hamid Reza Ghoreishy
Summary: The study found that the addition of graphene nanoparticles can improve the mechanical properties of nanocomposites of acrylonitrile butadiene rubber/phenolic resin, increasing tensile modulus and strength while decreasing elongation at break. Additionally, the presence of nanoparticles reduced the deterioration of mechanical properties at high temperatures.
JOURNAL OF APPLIED POLYMER SCIENCE
(2021)
Article
Polymer Science
Mohammad Javad Azizli, Mohammad Barghamadi, Katayoon Rezaeeparto, Masoud Mokhtary, Somayeh Parham, Mehdi Joker Darabi
Summary: The effects of graphene oxide on rubber hybrid nanocomposites were investigated, showing improved adhesion between blend phases and increased curing rate and torque. Adding a compatibilizer also enhanced tear strength and hardness of the samples.
IRANIAN POLYMER JOURNAL
(2021)
Article
Polymer Science
Mohammad Javad Azizli, Mohammad Barghamadi, Katayoon Rezaeeparto, Masoud Mokhtary, Somayeh Parham, Fatemeh Khademeh Molavi, Sedigheh Soltani
Summary: In this study, nanocomposites based on PA6/XNBR reinforced by OMMT were prepared, and the addition of XNBR-g-GMA compatibilizer and increased OMMT content was found to significantly improve the tensile strength, rheological and dynamic mechanical properties of the nanocomposites. The incorporation of Cloisite 30B as compared to Cloisite 20A resulted in substantial enhancement of the PA6/XNBR composite when XNBR-g-GMA was used as a compatibilizer.
JOURNAL OF APPLIED POLYMER SCIENCE
(2021)
Article
Polymer Science
Mohammad Javad Azizl, Mohammad Barghamadi, Katayoon Rezaeeparto, Masoud Mokhtary, Somayeh Parham
Summary: In this study, elastomer nanocomposites based on PP/EVA blends compatibilized with PTW and nanofillers were successfully prepared. Mechanical properties were closely related to the interphase characteristics and rubber-nanoparticle interactions. The incorporation of nanofillers and PTW compatibilizer led to changes in the dispersion and localization, affecting the stress-strain behavior and creep resistance of the nanocomposites.
JOURNAL OF POLYMER RESEARCH
(2021)
Article
Engineering, Chemical
Mohammad Javad Azizli, Fatemeh Morshedi Dehaghi, Bahareh Nasrollahi, Mohammad Barghamadi, Katayoon Rezaeeparto, Somayeh Parham, Masoud Mokhtary, Seeram Ramakrishna, Erfan Rezvani Ghomi
Summary: The study investigated the nonlinear elastoplastic behavior of nanocomposites based on SAN/XNBR blend with graphene, graphene oxide nanoparticles, and XNBR-g-GMA as a compatibilizer. The presence of the compatibilizer was found to enhance the mechanical properties, specifically elongation at break, due to better dispersion of graphene oxide and chemical interaction among components. The Bergstrom-Boyce model showed good conformity with the experimental data in the elastic region but some deviations in the viscoplastic region, particularly near the breaking elongation region.
POLYMER ENGINEERING AND SCIENCE
(2021)
Article
Polymer Science
Mohammad Javad Azizli, Mohammad Barghamadi, Katayoon Rezaeeparto, Somayeh Parham
Summary: One of the modern methods of improving the properties of nanocomposites is the incorporation of nanofillers into the polymer matrix. This study used graphene oxide to reinforce polypropylene and a compatibilizer to enhance the dispersion of graphene oxide and the compatibility between polypropylene and ethylene-propylene rubber. The results showed significant improvements in mechanical properties and morphology with the increase of graphene oxide concentration and the presence of the compatibilizer.
JOURNAL OF POLYMER RESEARCH
(2022)
Article
Polymer Science
Mohammad Barghamadi, Mohammad Karrabi, Mir Hamid Reza Ghoreishy, Ghasem Naderi
Summary: The various properties of hybrid nanocomposite based on SSBR/BR rubber blend have been investigated. The addition of nano-silica and surface-modified silica improved curing behavior and morphology. The replacement of nano-silica with CB improved mechanical properties and dissipation characteristics.
JOURNAL OF APPLIED POLYMER SCIENCE
(2023)