Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 84, Issue 24, Pages 16139-16146Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.9b02454
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Funding
- ICSN
- Labex Charm3at
- Institut Universitaire de France
- GENCI [A0050810547]
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A series of organic dyes derived from s-tetrazine have been synthesized, and their photophysical and electrochemical properties are systematically investigated. Testing these compounds as photoredox catalysts in a model oxidative C-S bond cleavage of thioethers has led us to identify new classes of active s-tetrazines. Moreover, some of them can be formed in situ from commercially available 3,6-dichlorotetrazine, making this photocatalyzed C-S bond functionalization simple and highly practical.
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