Journal
JOURNAL OF ALLOYS AND COMPOUNDS
Volume 804, Issue -, Pages 549-553Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jallcom.2019.06.232
Keywords
Polysulfide phase transformation; Shuttle effect; Vanadium dioxide; Li-S battery
Categories
Funding
- leading talents of innovation and entrepreneurship of Dongguan city
- National Natural Science Foundation of China [51807180]
Ask authors/readers for more resources
Rather than preventing the dissolution and diffusion of polysulfides, promoting polysulfide conversion through improved polysulfide redox is another promising strategy to suppress the dissolution of polysulfides and enhance the cycle life of sulfur cathodes. We demonstrated that VO2-rGO not only facilities liquid-involving polysulfide redox (Li2S8 -> Li2S6 -> Li2S4), but also promotes the effective decompositions of lithium sulfide (Li2S). As evidenced by the visual experiments and DFT calculation, VO2-rGO has strong affinity for polysulfides species. With sulfur loading of 2.15 mg cm(-2) and sulfur content of 76 wt%, the reversible capacity retained at 896 mAh g(-1) after 200 cycles. (C) 2019 Elsevier B.V. All rights reserved.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available