Journal
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2020, Issue 1, Pages 57-60Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201901629
Keywords
Carbon dioxide; Palladium; CO equivalent; Nitrogen heterocycles; Reductive cyclization
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Funding
- National Science Foundation [CHE1564959]
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A reductive amination process that constructs indoles, carbazoles or benzimidazoles from nitroarenes - irrespective of their electronic or steric nature - was developed that uses CO2 as the source of CO. The process is robust, tolerating common gaseous components of flue gas (H2S, SO2, NO and H2O) without adversely affecting the reductive cyclization.
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