4.6 Article

Self-supported ternary (NixFey)2P nanoplates arrays as an efficient bifunctional electrocatalyst for overall water splitting

Journal

ELECTROCHIMICA ACTA
Volume 319, Issue -, Pages 561-568

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2019.07.022

Keywords

Ternary transition metal phosphides; Self supporting; Bifunctional electrocatalyst; Overall water splitting; Synergistic effect

Funding

  1. National Natural Science Foundation of China [51175472, 51672249]
  2. Zhejiang Outstanding Youth Fund [LR19E020004]
  3. Opening Fund of State Key Laboratory of Structural Analysis for Industrial Equipment (Dalian University of Technology) [GZ1704]
  4. Opening Fund of State Key Laboratory of Digital Manufacturing Equipment and Technology (Huazhong University of Science and Technology) [DMETKF2018017]

Ask authors/readers for more resources

Developing non-precious metal bifunctional electrocatalysts for effective overall water splitting is promising to realize high-efficient renewable energy production. In this work, ternary (NixFey)(2)P nanoplates arrays on 3D self-supported nickel foams were prepared through a simple coelectrodeposition followed by phosphorization. The synthesized (NixFey)(2)P nanoplates arrays showed remarkable bifunctional electrocatalytic performances in the KOH electrolyte, with the Tafel slopes of 57.8 mV.dec(-1) and 53.6 mV.dec(-1), and low overpotentials of 115 mV and 182 mV to reach a current density of 10 mA cm(-2) for hydrogen evolution reaction and oxygen evolution reaction, respectively. In addition, the optimized (Ni0.66Fe0.33)(2)P anode and cathode demonstrated outstanding ability for overall water splitting in the two-electrode alkaline electrolyzer, generating a current density of 10 mA cm(-2) at the applied cell voltage of 1.61 V. This benefited by the active surface to expedite reactants absorption, faster electron transport in the solid-liquid interface and reduced charge-transfer resistance due to the bimetallic synergistic effect. This delicate design of bifunctional transition metal phosphides provides a potential approach to realize water reuse and energy regeneration by the full water splitting. (C) 2019 Elsevier Ltd. All rights reserved.

Authors

I am an author on this paper
Click your name to claim this paper and add it to your profile.

Reviews

Primary Rating

4.6
Not enough ratings

Secondary Ratings

Novelty
-
Significance
-
Scientific rigor
-
Rate this paper

Recommended

Article Allergy

circS100A11 enhances M2a macrophage activation and lung inflammation in children with asthma

Qiuyan Liang, Jinrong Fu, Xiang Wang, Lijuan Liu, Wenfeng Xiao, Yajing Gao, Lan Yang, Hongmiao Yu, Xueru Xie, Zikun Tu, Saihua Huang, Xiao Han, Liling Qian, Yufeng Zhou

Summary: This study identified 372 differentially expressed circRNAs in peripheral blood mononuclear cells (PBMCs) of children with asthma. Among them, a circRNA called circS100A11 was highly expressed in monocytes and significantly upregulated in children with asthma. Further experiments demonstrated that circS100A11 promoted M2a macrophage activation by enhancing translation of its host gene, S100A11, and exacerbated lung inflammation in a mouse model of asthma. The study also found that circS100A11 competitively bound to CAPRIN1 to promote S100A11 translation, thereby enhancing M2a macrophage activation.

ALLERGY (2023)

Article Limnology

Expression profile of long non-coding RNAs in the intestine of black rockfish Sebastes schlegelii in response to Edwardsiella tarda infection

Xu Yan, Min Cao, Qiang Fu, Ning Yang, Ningning Wang, Lin Song, Chao Li

Summary: In this study, lncRNAs in the intestine of black rockfish after Edwardsiella tarda infection were identified and analyzed. Results showed that these lncRNAs were significantly regulated and involved in metabolic and immune-related pathways. Co-expression of lncRNAs and mRNAs with metabolic and immunity functions were also found. This research provides a foundation for further investigation of the regulatory roles of lncRNAs in the intestinal immune response of black rockfish.

JOURNAL OF OCEANOLOGY AND LIMNOLOGY (2023)

Article Fisheries

Bacterial induced miR-144-5p modulates intestinal inflammatory response of Japanese flounder by targeting Hsp90α-dependent NLR signaling pathway

Yingrui Li, Lin Su, Baoshan Guo, Shun Zhou, Chao Li, Yunji Xiu

Summary: Pathogens infection induces intestinal inflammatory processes. MicroRNAs in teleost serve as vital regulators in innate immunity responses against pathogen infection. MiR-144-5p is identified as negative regulator in teleost against bacterial infection. It down-regulates inflammation-related cytokines by targeting Hsp90 alpha, ultimately promoting bacterial infection.

AQUACULTURE (2023)

Article Fisheries

A basic investigation on evolution of CL-L1 in vertebrates and its bioactivities in black rockfish (Sebastes schlegelii)

Hui Jun Huo, Tian Zhen Yang, Qing Zhu, Ning Yang, Chao Li

Summary: This study compared collectins from a range of vertebrates and found that they are widely distributed and conserved. The collectin from a marine teleost, the black rockfish, was analyzed in detail, revealing the need for further research on its sugar binding mechanism.

AQUACULTURE (2023)

Article Engineering, Environmental

Construction of bidirectional electron transfer biofilms via periodic polarity reversal

Dandan Liang, Zeng Li, Guohong Liu, Chao Li, Weihua He, Jiannan Li, Yujie Feng

Summary: Periodic polarity reversal strategy can effectively cultivate bidirectional electron transfer biofilm and utilize the characteristics of biofilm to facilitate nitrate reduction.

CHEMICAL ENGINEERING JOURNAL (2023)

Article Pediatrics

Pediatric bronchial Dieulafoy's disease with bronchial artery embolization: two case reports

Lingyu Lai, Yong Lu, Zhimin Xi, Fang Liu, Liling Qian, Libo Wang, Quming Zhao

Summary: This study presented two cases of Bronchial Dieulafoy's disease (BDD) in children, diagnosed by bronchial arteriography and CTA. Both patients underwent successful bronchial artery embolization (BAE) and no recurrence of hemoptysis was observed during the follow-up period. It highlights the importance of considering BDD in children with hemoptysis and endobronchial protrusion.

TRANSLATIONAL PEDIATRICS (2023)

Article Fisheries

Integrative transcriptomic profiling reveals the key pathways in the regulation mechanism of fish intestine-spleen immunity during the bacterial challenges

Chengbin Gao, Xin Cai, Alan J. Lymbery, Le Ma, Min Cao, Chao Li

Summary: An integrative analysis was conducted in black rockfish intestine and spleen after bacterial infection, revealing a cooperation between the immune genes of the two organs. Two key immune genes and their related non-coding RNAs were identified in the regulation mechanism of the intestine-spleen axis during different bacterial infections. These findings provide insights into the immune response in black rockfish.

AQUACULTURE (2023)

Article Fisheries

Genome-wide identification and functional characterization of inhibitor of nuclear factor-ΚB (IΚB) kinase (IKK) in turbot (Scophthalmus maximus)

Zhe Liu, Peng Liu, Tong Cui, Xuan Chen, Beibei Wang, Chengbin Gao, Zhongyi Wang, Chao Li, Ning Yang

Summary: Six IKK genes were identified in turbot, and they were widely expressed in various tissues. After bacterial infection, these genes showed different expression patterns in mucosal tissues, indicating their potential roles in maintaining mucosal barrier integrity. Protein-protein interaction network analysis revealed that most interacting proteins of IKK genes were related to the NF-kappa B signaling pathway. Functional experiments confirmed the involvement of SmIKK alpha/SmIKK alpha 2/SmIKK beta in the activation of NF-kappa B in turbot.

FISH & SHELLFISH IMMUNOLOGY (2023)

Article Fisheries

Systematic analysis of circRNA-related ceRNA networks of black rockfish (Sebastes schlegelii) in response to Aeromonas salmonicides infection

Chengbin Gao, Xin Cai, Le Ma, Peng Sun, Chao Li

Summary: In this study, the regulatory roles of circRNA-related ceRNA networks in the spleen immune system of black rockfish infected with A. salmonicida were investigated. The results revealed 39 differentially expressed circRNAs during the infection, which were significantly enriched in multiple immune-related pathways. These findings suggest a potential role of circRNA in the antibacterial immune response of fish.

FISH & SHELLFISH IMMUNOLOGY (2023)

Article Cell Biology

Derivation and characterization of new cell line from intestine of turbot (Scophthalmus maximus)

Yiping Liu, Xuefeng Ge, Chao Li, Ting Xue

Summary: A continuous intestine cell line named SMI was established from turbot using tissue explant technique and had undergone more than 60 subcultures. The SMI cell line had a diploid chromosome number of 44 and showed characteristics of epidermal cells. It could be used as an ideal platform to explore gene function in vitro and exhibited immune functions similar to the intestinal epithelium in vivo.

IN VITRO CELLULAR & DEVELOPMENTAL BIOLOGY-ANIMAL (2023)

Article Biochemistry & Molecular Biology

Molecular characterization, expression analysis and function identification of TNF? in black rockfish (Sebastes schlegelii)

Chengbin Gao, Xin Cai, Le Ma, Ting Xue, Chao Li

Summary: In this study, the TNF alpha was characterized and its roles in the immune system of black rockfish during bacterial infections were explored. The results showed that Ss_TNF alpha was significantly up-regulated in the spleen and intestine after infections, while down-regulated in PBLs. The expression patterns of other inflammatory cytokines were also observed.

INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES (2023)

Article Biochemistry & Molecular Biology

The genetic basis and potential molecular mechanism of yellow-albino northern snakehead (Channa argus)

Donglei Sun, Xin Qi, Haishen Wen, Chao Li, Jianlong Li, Jiwei Chen, Zexin Tao, Mingxin Zhu, Xiaoyan Zhang, Yun Li

Summary: A new yellow-mutant northern snakehead with market-favoured yellow skin was discovered in China. It was confirmed to be an albino with a non-sense mutation in slc45a2 gene as the causation for the yellow skin. Comparative transcriptomic analysis revealed the potential involvement of fibroblasts in pigmentation in fish.

OPEN BIOLOGY (2023)

Article Biochemistry & Molecular Biology

Spatial transcriptomes and microbiota reveal immune mechanism that respond to pathogen infection in the posterior intestine of Sebastes schlegelii

Min Cao, Ting Xue, Huijun Huo, Xiaoyan Zhang, Ning Ning Wang, Xu Yan, Chao Li

Summary: Spatial transcriptomes were used to study the transcriptomic landscape in the posterior intestine of Sebastes schlegelii following Edwardsiella piscicida infection. A molecular regionalization of the posterior intestine was observed in the healthy condition. After bacterial infection, immune-related genes were predominantly found in the mucosa layer. The expression of regeneration-related genes suggested the constant proliferation of new cells in response to pathogen invasion, while increasing microbiota communities indicated their role in maintaining intestinal integrity and shaping the mucosal immune system.

OPEN BIOLOGY (2023)

Article Construction & Building Technology

An Enhancement Strategy for Macau's Largos from a Syntactic Perspective

Senyu Lou, Yaou Zhang, Chao Li, Jingjing Chen

Summary: This paper focuses on the Largos of the Macau Peninsula and categorizes their main functions as serving the community, facilitating traffic, and promoting religious culture through historical combing and field research. A spatial syntactic theory is applied to establish a model, using three syntactic parameters - synergy, integration, and choice - to interpret the analysis results. Based on the syntactic parameters, the results are divided into four categories, and improvement strategies are proposed for the selected spaces that require enhancements. Taking Macau's Largos as an example, this paper aims to provide a reference for the effective renewal of urban micro-spaces and small public spaces by applying space syntax analysis.

BUILDINGS (2023)

Article Green & Sustainable Science & Technology

Cathodic biofouling control by microbial separators in air-breathing microbial fuel cells

Chao Li, Kexin Yi, Shaogang Hu, Wulin Yang

Summary: A novel microbial separator was developed for air-breathing microbial fuel cells to protect cathodic catalytic activity. This concept effectively prevents biofouling, improves the stability of the cells, enhances chemical oxygen demand removal efficiency, prolongs lifespan, and reduces economic costs.

ENVIRONMENTAL SCIENCE AND ECOTECHNOLOGY (2023)

Article Electrochemistry

Recent advances in Bio-mass by electrochemically strategies generated hydrogen gas production: Environmentally sustainable technologies innovation

Abdul Qayoom Mugheri, Shaista Khan, Ali Asghar Sangah, Aijaz Ahmed Bhutto, Muhammad Younis Laghari, Nadeem Ahmed Mugheri, Asif Ali Jamali, Arsalan Ahmed Mugheri, Nagji Sodho, Abdul Waheed Mastoi, Aftab Kandhro

Summary: Green hydrogen has the potential to transition to a pollution-free energy infrastructure. This study proposes a solution to produce hydrogen during the photoelectrochemical process, offering greater stability and control over chemical reactions. Techno-economic assessments show the efficiency and economic feasibility of co-producing value-added chemicals to enhance green hydrogen production.

ELECTROCHIMICA ACTA (2024)

Article Electrochemistry

ACGNet: An interpretable attention crystal graph neural network for accurate oxidation potential prediction

Danpeng Cheng, Wuxin Sha, Qigao Han, Shun Tang, Jun Zhong, Jinqiao Du, Jie Tian, Yuan-Cheng Cao

Summary: LiNixCoyMn1-x-yO2 (NCM) is a critical cathode material for lithium-ion batteries in electric vehicles. The aging of cathode/electrolyte interfaces leads to capacity degradation and long-term cycle instability. A novel neural network model called ACGNet is developed to predict electrochemical stability windows of crystals, allowing for high-throughput screening of coating materials. LiPO3 is identified as a promising coating material with high oxidation voltage and low cost, which significantly improves the cycle stability of NCM batteries. This study demonstrates the accuracy and potential of machine learning in battery materials.

ELECTROCHIMICA ACTA (2024)

Article Electrochemistry

Enhanced electrochemical performance of CuO/NiO/rGO for oxygen evolution reaction

P. Mohana, R. Yuvakkumar, G. Ravi, S. Arunmetha

Summary: This study successfully fabricates a non-noble CuO/NiO/rGO nanocomposite and investigates its electrocatalytic performance for oxygen evolution reaction in alkaline environment. The experimental results demonstrate that the electrocatalyst exhibits high activity and good stability, offering a new synthetic approach for sustainable energy production.

ELECTROCHIMICA ACTA (2024)

Article Electrochemistry

Carbon nanofibers implanted porous catalytic metal oxide design as efficient bifunctional electrode host material for lithium-sulfur battery

Qiong Qu, Jing Guo, Hongyu Wang, Kai Zhang, Jingde Li

Summary: In this study, a bifunctional electrode host design consisting of carbon nanofibers implanted ordered porous Co-decorated Al2O3 supported on carbon nanotube film (CNTF) was proposed to address the shuttling effect of lithium polysulfides (LiPSs) and dendrite formation of metal lithium anode in lithium-sulfur (Li-S) batteries. The electrode exhibited excellent conductivity, efficient confinement of LiPSs, and catalytic conversion performance, resulting in high initial capacity and good capacity retention during cycling. As an anode, the electrode showed excellent Li+ diffusion performance and uniform lithium growth behavior, achieving a dendrite-free lithium electrode. The flexible pack cell assembled from these electrodes delivered a specific capacity of 972 mAh g(-1) with good capacity retention.

ELECTROCHIMICA ACTA (2024)

Article Electrochemistry

Spray coating of carbon nanoparticles as an effective and scalable method to enhance the performance of stainless steel anode in microbial electrochemical systems

Hong Zhang, Jin-Peng Yu, Chen Chen, Cheng-Yong Shu, Guang-Yu Xu, Jie Ren, Kai Cui, Wen-Fang Cai, Yun-Hai Wang, Kun Guo

Summary: Spray coating of acetylene black nanoparticles onto stainless steel mesh can enhance its biofilm formation ability and current density, making it a promising electrode material for microbial electrochemical systems. The spray coating method is simple, cost-effective, and suitable for large-size stainless steel electrodes.

ELECTROCHIMICA ACTA (2024)

Article Electrochemistry

Electrochemical properties of Li-rich ternary cathode material Li1.20Mn0.44Ni0.32Co0.04O2 and its oxygen-deficient phase

Binpeng Hou, Jingjin Chen, Li-Hong Zhang, Xiaowen Shi, Zizhong Zhu

Summary: The electrochemical performance of Li1.20Mn0.44Ni0.32Co0.04O2 and its oxygen-deficient phase Li1.20Mn0.44Ni0.32Co0.04O1.83 was studied through first-principles calculations. The results show that the oxygen-deficient phase has a higher theoretical capacity but lower voltage platform and higher chemical activity compared to the pristine phase.

ELECTROCHIMICA ACTA (2024)

Article Electrochemistry

Post-mortem analysis of the Li-ion battery with charge/discharge deterioration in high- and low-temperature environments

Yating Du, Sayoko Shironita, Daisuke Asakura, Eiji Hosono, Yoshitsugu Sone, Yugo Miseki, Eiichi Kobayashi, Minoru Umeda

Summary: This study investigates the effect of high- and low-temperature environments on the charge-discharge performance of a Li-ion battery. The deterioration mechanisms of the battery at different temperatures are analyzed through various characterization techniques. The results indicate that the battery performance deteriorates more significantly at a low-temperature environment of 5 degrees C compared to higher temperatures. The understanding of the deterioration mechanisms can contribute to the development of safer battery usage methods.

ELECTROCHIMICA ACTA (2024)

Article Electrochemistry

A Co3O4-x/Co nanocomposite with synergistically enhanced electrochemical activity for reduction of nitrite to ammonia

Si-Si Shi, Zhi-Xiang Yuan, Fei Zhang, Ping Chen

Summary: In this study, a new nano-electrocatalyst was prepared, which exhibited superior electrocatalytic activity for the reduction of NO2- to ammonia in a neutral electrolyte, potentially due to the synergistic enhancement between Co3O4-x and Co.

ELECTROCHIMICA ACTA (2024)

Article Electrochemistry

Facile fabrication of NaOH nanorods on pencil graphite electrode for simultaneous electrochemical detection of natural antioxidants by deep eutectic solvent

Berna Dalkiran, Havva Bekirog

Summary: This study reports the use of deep eutectic solvents (DES) based on ethylene glycol and urea as low-cost and green electrolytes for enhancing electrochemical detection of natural antioxidants. The study successfully developed a disposable and effective electrochemical sensing platform for simultaneous determination of ascorbic acid (AA) and gallic acid (GA) using NaOH nanorods on a pencil graphite electrode. The proposed electrode showed improved analytical performance, with higher peak currents and shifted oxidation potentials in DES compared to BR buffer medium.

ELECTROCHIMICA ACTA (2024)

Article Electrochemistry

A three-dimensional fibrous tungsten-oxide/carbon composite derived from natural cellulose substance as an anodic material for lithium-ion batteries

Sijun Ren, Jianguo Huang

Summary: In this study, a novel bio-inspired nanofibrous WO3/carbon composite was synthesized using a facile hydrothermal method. The three-dimensional network structure of the composite alleviated the volume expansion of WO3 nanorods and enhanced the charge-transport kinetics. The optimized composite exhibited superior lithium storage properties.

ELECTROCHIMICA ACTA (2024)

Article Electrochemistry

Stabilizing the dissolution kinetics by interstitial Zn cations in CoMoO4 for oxygen evolution reaction at high potential

Zhilong Zheng, Yu Chen, Hongxia Yin, Hengbo Xiao, Xiangji Zhou, Zhiwen Li, Ximin Li, Jin Chen, Songliu Yuan, Junjie Guo, Haibin Yu, Zhen Zhang, Lihua Qian

Summary: This study found that interstitial Zn cations in CoMoO4 can modulate the dissolution kinetics of Mo cations and improve the OER performance. The interstitial Zn cations can prevent the dissolution of Co cations at high potential, enhancing the durability of the catalyst.

ELECTROCHIMICA ACTA (2024)

Article Electrochemistry

Molecular insights on optimizing nanoporous carbon-based supercapacitors with various electrolytes

Xiaobo Lin, Shern R. Tee, Debra J. Searles, Peter T. Cummings

Summary: Molecular dynamics simulations using the constant potential method were used to investigate the charging dynamics and charge storage of supercapacitors. The simulations revealed that the water-in-salt electrolyte exhibited the highest charge storage and significantly higher capacitance on the negative electrode. The varying contributions of different electrode regions to supercapacitor performance were also demonstrated.

ELECTROCHIMICA ACTA (2024)

Article Electrochemistry

Interaction between bilirubin oxidase and Au nanoparticles distributed over dimpled titanium foil towards oxygen reduction reaction

Wiktoria Lipinska, Vita Saska, Katarzyna Siuzdak, Jakub Karczewski, Karol Zaleski, Emerson Coy, Anne de Poulpiquet, Ievgen Mazurenko, Elisabeth Lojou

Summary: The spatial distribution of enzymes on electrodes is important for bioelectrocatalysis. In this study, controlled spatial distribution of gold nanoparticles on Ti nanodimples was achieved. The efficiency of enzymatic O2 reduction was found to be influenced by the size of the gold nanoparticles and their colocalization with TiO2. The highest stability of enzymatic current was observed with the largest gold nanoparticles.

ELECTROCHIMICA ACTA (2024)

Article Electrochemistry

Electrochemical supercapacitor and water splitting electrocatalysis applications of self-grown amorphous Ni(OH)2 nanosponge-balls

Tariq M. Al-Hejri, Zeenat A. Shaikh, Ahmed H. Al-Naggar, Siddheshwar D. Raut, Tabassum Siddiqui, Hamdan M. Danamah, Vijaykumar V. Jadhav, Abdullah M. Al-Enizi, Rajaram S. Mane

Summary: This study explores a promising self-growth approach for the synthesis of nickel hydroxide (Ni(OH)2) nanosponge-balls on the surface of a nickel-foam (NiF) electrode. The modified NiF electrode, named Ni(OH)2@NiF, shows distinctive nanosponge-ball morphology and demonstrates excellent energy storage capability and electrocatalytic performance in both hydrogen and oxygen evolution reactions.

ELECTROCHIMICA ACTA (2024)

Article Electrochemistry

Versatile mixed ionic-electronic conducting binders for high-power, high-energy batteries

Rafael Del Olmo, Gregorio Guzman-Gonzalez, Oihane Sanz, Maria Forsyth, Nerea Casado

Summary: The use of Lithium-Ion Batteries (LIBs) is becoming increasingly extensive, and it is important to optimize the devices to achieve their maximum practical specific capacity. In this study, mixed ionic-electronic conducting (MIEC) binders based on PEDOT:PSS and PEDOT: PDADMA-TFSI were developed for Li-ion cathodes, and their performance was compared with conventional formulations. The influence of electrode formulations, including the addition of conducting carbon and an Organic Ionic Plastic Cristal (OIPC), was also analyzed. The proposed binders showed improved performance compared to conventional formulations with different electrolyte types and active materials.

ELECTROCHIMICA ACTA (2024)