Journal
CHEMICAL ENGINEERING JOURNAL
Volume 391, Issue -, Pages -Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.cej.2019.123491
Keywords
NH3-SCR; Acid-treatment seeds; Cu-Mn bi-metal; N2O; BrOnsted acid sites
Categories
Funding
- National Natural Science Foundation of China [21776266, 21476231]
- Yangquan Coal Industry (Group) Co. LTD., China
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In this paper, acid-treated seeds have been adopted to improve the yield of UZM-9 zeolite, which could reach 50% for the first time within only two days. When applied as NH3-SCR catalysts after ion exchange, Cu-Mn-UZM-9 catalysts exhibited high NO conversion and excellent N-2 selectivity in a wider temperature region. The ICP, H-2-TPR and XPS results further revealed that the Cu species in the catalysts mainly existed as isolated Cu2+ located in the interval parts of crystals, while Mn species mainly existed as Mn4+ in the outer parts. That means, the co-exchange of Mn cation could actually play an adverse role in the direct interaction between Cu2+ and NH3 to produce N2O. Finally, the NH3-TPD and in situ FTIR results proved that the addition of Mn cation could introduce extra BrOnsted acid sites into the catalysts, which could capture NH3 in NH3-SCR reaction and suppress its nonselective oxidation as well as the N2O formation.
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