Article
Engineering, Chemical
Jianna Li, Shuzhong Wang, Yanhui Li, Chuang Yang, Donghai Xu, Jie Zhang, Yishu Zhang, Tiantian Xu
Summary: This paper investigates the treatment characteristics of glyphosate wastewater using supercritical water oxidation (SCWO) technology. It explores the effects of different operating parameters on the degradation of COD and NH3-N, proposes a simplified SCWO reaction pathway, and designs a comprehensive SCWO system for efficiently treating wastewater and improving economic benefits.
CHEMICAL ENGINEERING RESEARCH & DESIGN
(2021)
Review
Engineering, Environmental
Tejasvini Ahuja, Urmila Brighu, Kanika Saxena
Summary: The transition in chemicals used in industries has led to an increase in non-biodegradable compounds in effluents, negatively impacting water quality. Strict effluent discharge standards have necessitated the use of advanced oxidation processes (AOPs) for efficient degradation of these compounds. This paper critically reviews the performance of various photocatalytic materials for treatment of different types of wastewater and identifies their suitability for specific applications. However, scalability and robustness of the system remain major challenges.
JOURNAL OF WATER PROCESS ENGINEERING
(2023)
Article
Agronomy
Paraskevas Parlakidis, Ioanna Gounari, Aristidis Georgiou, George Adamidis, Zisis Vryzas, Georgios D. Gikas
Summary: This study aims to investigate the efficiency of four pilot-scale horizontal subsurface flow constructed wetlands in remediating myclobutanil and triticonazole. The results show that the removal rate of the fungicides is influenced by the wetland design and plant species.
Article
Environmental Sciences
J. H. Ramirez Franco, S. D. Castaneda Cardenas, H. R. Zea Ramirez
Summary: The present research aimed to assess the effects of ilmenite use in the discoloration process of clinical laboratory wastewater. The wastewater originates from a Gram staining process used to identify pathogenic microorganisms present in biological samples. The ilmenite was characterized and the discoloration process of the wastewater was measured in different conditions.
Article
Chemistry, Physical
Vijay Khanal, Narmina O. Balayeva, Carsten Guennemann, Zamin Mamiyev, Ralf Dillert, Detlef W. Bahnemann, Vaidyanathan (Ravi) Subramanian
Summary: A wet chemical-synthesized high surface area ultrafine Ta2O5 nanoparticle and its application to NOx control was reported, showing better photocatalytic activity and stability compared to TiO2.
APPLIED CATALYSIS B-ENVIRONMENTAL
(2021)
Article
Environmental Sciences
Dorcas O. Adenuga, Shepherd M. Tichapondwa, Evans M. N. Chirwa
Summary: A significant amount of research has been conducted on the development and application of photocatalytic materials for the visible light degradation of organic pollutants in wastewater. Most studies have used simulated wastewater, which is not representative of real water systems. In this study, the photocatalytic activity of a photocatalyst was investigated in the secondary effluent of a wastewater treatment plant in Pretoria, South Africa. The results showed that pH had the highest significant influence on the degradation rate, followed by the initial concentration of the pollutant. The presence of certain anions and cations also affected the degradation rate.
ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
(2023)
Article
Environmental Sciences
Kaique S. G. C. Oliveira, Rosimeire M. Farinos, Alyne B. Veroli, Luis A. M. Ruotolo
Summary: The study focused on the anodic oxidation of recalcitrant organic compounds using a PbO2 electrode on a three-dimensional matrix of reticulated vitreous carbon (RVC). By optimizing the experimental conditions, high current efficiency and reduced energy consumption were achieved for the degradation of glyphosate-containing wastewater. The use of the RVC/PbO2 anode demonstrated effective treatment of real effluents.
ENVIRONMENTAL TECHNOLOGY
(2021)
Article
Chemistry, Physical
Guodong Pan, Xuesen Hou, Zheyuan Liu, Chengkai Yang, Jinlin Long, Guocheng Huang, Jinhong Bi, Yan Yu, Liuyi Li
Summary: A hydration-initiated pathway of photocatalytic water oxidation over covalent organic frameworks (COFs) is proposed, where the hydration of water addition to the hydrazone unit efficiently induces the initial step of photocatalytic water oxidation. The subsequent oxidative deprotonation and the coupling of the bonded hydroxyl radicals selectively yield H2O2. This study provides a mechanistic insight into water oxidation over COFs.
Review
Engineering, Environmental
Guanyi Chen, Yang Yu, Lan Liang, Xiaoguang Duan, Rui Li, Xukai Lu, Beibei Yan, Ning Li, Shaobin Wang
Summary: This study provides a comprehensive overview of the PPOH system for antibiotic wastewater treatment, categorizing it into PPA, PAP, and CPPA systems. Through discussing the synergistic effects between photocatalysis and persulfate activation, the performance of the coupled oxidation systems and internal mechanisms for antibiotic degradation are summarized and analyzed, along with proposing conclusions and future prospects for the PPOH systems.
JOURNAL OF HAZARDOUS MATERIALS
(2021)
Review
Environmental Sciences
Basma Al-Najar, Ayman H. Kamel, Hanan Albuflasa, Nicholas P. Hankins
Summary: This article reviews the application of spinel ferrite nanomaterials (SFNs) in the removal of chlorophenols (CPs). It highlights the unique crystal structure, optical and magnetic properties of SFNs and their potential in CP removal. The article also discusses the structure and properties of SFN, as well as the factors that affect its efficiency in CP removal.
ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
(2023)
Review
Environmental Sciences
K. Sharma, D. Vaya, G. Prasad, P. K. Surolia
Summary: This review primarily focuses on the treatment of oily wastewater through advanced oxidation processes, primarily the photocatalytic process. The basic functioning mechanism of photocatalysts and their modifications have been explained, as well as the impact of photocatalysis on the degradation of harmful oily pollutants in water.
INTERNATIONAL JOURNAL OF ENVIRONMENTAL SCIENCE AND TECHNOLOGY
(2023)
Article
Engineering, Environmental
Priyanka Gupta, Komal Pandey, Nishith Verma
Summary: Glyphosate, a commonly used herbicide known for its detrimental impact on the environment, is effectively mineralized through a two-step process involving catalytic wet air oxidation (cWAO) and microbial degradation. Iron nanoparticle-tipped carbon nanofibers supported on activated carbon beads serve as the cWAO catalyst, leading to significant degradation of glyphosate followed by complete mineralization with the assistance of a bacteria strain identified as Providencia vermicola. The non-toxicity of the catalyst towards the bacteria strain simplifies the remediation process, making it a promising approach for treating toxic pollutants in wastewater.
CHEMICAL ENGINEERING JOURNAL
(2022)
Article
Environmental Sciences
G. Divyapriya, Seema Singh, Carlos A. Martinez-Huitle, Jaimy Scaria, Ansaf Karim, P. Nidheesh
Summary: Photoelectrochemical methods are emerging as promising options among advanced oxidation processes due to their higher treatment efficiency and synergistic effects. This review discusses the fundamental reaction mechanisms, integrated processes, real wastewater treatment, and hydrogen production efficiency in photoelectrochemical methods.
Article
Environmental Sciences
A. K. Pandey, R. Reji Kumar, B. Kalidasan, Imtiaz Ali Laghari, M. Samykano, Richa Kothari, Abdullah M. Abusorrah, Kamal Sharma, V. V. Tyagi
Summary: This article discusses the trends in the use of photocatalysis process, desalination technologies, and solar disinfection techniques for treating industrial and domestic wastewater. It highlights the global water crisis, major pollutants, and environmental impacts. The article also emphasizes the benefits of using solar power for wastewater treatment.
JOURNAL OF ENVIRONMENTAL MANAGEMENT
(2021)
Article
Environmental Sciences
Bruna Castanheira, Larissa Otubo, Cristiano L. P. Oliveira, Rosa Montes, Jose Benito Quintana, Rosario Rodil, Sergio Brochsztain, Vitor J. P. Vilar, Antonio Carlos S. C. Teixeira
Summary: The photocatalytic activity of TiO2 nanoparticles supported on mesoporous silica SBA-15 was evaluated for the photodegradation of sulfadiazine. The 30% TiO2/SBA-15 sample showed the best performance in pure water solutions and also demonstrated higher SDZ degradation efficiency in urban secondary wastewater. Additionally, LC-MS analysis identified 65 other CECs in the wastewater sample, which were effectively removed by the photocatalytic system.
Article
Environmental Sciences
Eric Bollinger, Jochen P. P. Zubrod, Dominic Englert, Annika Pollitt, Bastian Fuss, Ralf Schulz, Mirco Bundschuh
Summary: This study investigates the effect of the neonicotinoid thiacloprid on stable isotope signatures and the feasibility of using stable isotope analysis to track dietary composition in organisms. The results show that the impact of thiacloprid on trophic enrichment factors is small and stable isotope analysis aligns with direct observations of consumption.
ENVIRONMENTAL TOXICOLOGY AND CHEMISTRY
(2023)
Article
Environmental Sciences
Alexis P. Roodt, Sonja Schaufelberger, Ralf Schulz
Summary: Exposure of freshwater ecosystems to insecticides can negatively impact the development of emerging aquatic insects, which in turn affects terrestrial food webs.
ENVIRONMENTAL TOXICOLOGY AND CHEMISTRY
(2023)
Article
Chemistry, Applied
Patricia Garcia-Munoz, Fernando Fresno, Christophe Lefevre, Didier Robert, Nicolas Keller
Summary: In the search for more efficient low-temperature catalysts, the substitution of La3+ by Ti3+ cations in LaFeO3 orthoferrites was found to enhance the UV-A light driven activity. La1_xTixFeO3 catalysts were synthesized using a modified Pechini sol-gel route with a solid source of titanium. The amorphous content of the TiO2 precursor played a crucial role in the substitution process. The substitution was proposed to occur via solid-solid diffusion between TiO2 and amorphous LaFeO3 during thermal treatment.
Article
Chemistry, Applied
Patricia Garcia-Munoz, Javier Ivanez, Victor A. de la Pena O'Shea, Nicolas Keller, Fernando Fresno
Summary: In this study, the feasibility of using alveolar open-cell beta-SiC foams as a catalyst support for solar hydrogen production was explored. Pt and Ru nanoparticles were obtained through photoassisted synthesis and tested for gas-phase hydrogen production from water-ethanol mixtures. The foam-supported photocatalysts, including Pt/TiO2 and Ru/TiO2, showed activity in solar photocatalytic reactions, with Pt/TiO2 being the most active. The foam pore size had little influence on hydrogen outcome, and a UV-to-hydrogen conversion efficiency of 14% (equivalent to 0.49% solar-to-hydrogen) was achieved under the best conditions, with a photonic efficiency higher than 30%.
Article
Engineering, Environmental
Sascha Bub, Jakob Wolfram, Lara L. Petschick, Sebastian Stehle, Ralf Schulz
Summary: This study proposes the assessment of pesticide toxicity for different species groups based on both mass and toxicity to evaluate environmental risks. The authors calculated and compared the Total Applied Toxicity (TAT) in Germany between 1995 and 2019, finding a decrease in TAT for terrestrial vertebrates by about 20%, whereas TAT for fishes increased by a factor of three largely due to insecticides. Different species groups showed varying trends in TAT, with pollinators likely being affected by neonicotinoid use restrictions.
ENVIRONMENTAL SCIENCE & TECHNOLOGY
(2023)
Article
Energy & Fuels
Emilia Soszka, Marcin Jedrzejczyk, Nicolas Keller, Agnieszka M. Ruppert
Summary: The sustainable production of environmentally-friendly alternative fuels is important for future biorefinery schemes. In this study, bimetallic Ni-Co/gamma-Al2O3 catalysts were used to efficiently produce 2-MTHF, and the key factors affecting the yield and selectivity were identified.
Article
Environmental Sciences
Jakob Wolfram, Sascha Bub, Lara L. Petschick, Anna Schemmer, Sebastian Stehle, Ralf Schulz
Summary: A complete ban on pesticide use in sensitive areas, such as nature conservation areas, is currently being discussed in the EU. A study in Germany found that surface waters in protected areas are contaminated by pesticides, posing ecological risks. Therefore, it is crucial to improve the protection of these valuable water resources.
SCIENCE OF THE TOTAL ENVIRONMENT
(2023)
Article
Environmental Sciences
Sebastian Stehle, Viktoriia Ovcharova, Jakob Wolfram, Sascha Bub, Larissa Zoe Herrmann, Lara Luisa Petschick, Ralf Schulz
Summary: Neonicotinoids are widely used insecticides that have raised concerns over their impact on non-target ecosystems, specifically surface waters. A meta-analysis of 173 peer-reviewed studies found a lack of exposure information in over 90% of agricultural areas globally. The study revealed low acute risks but significant chronic risks, especially for multispecies endpoints.
SCIENCE OF THE TOTAL ENVIRONMENT
(2023)
Review
Chemistry, Physical
Jorge Rodriguez-Chueca, Jaime Carbajo, Patricia Garcia-Munoz
Summary: In recent decades, UV-AOPs have been used to remove various contaminants from polluted water, but their industrial-scale application is limited by high operational costs. Researchers have been working on increasing their efficiency and reducing costs by optimizing operational parameters, developing photocatalytic materials, and combining different UV-AOPs for pollutant treatment.
Review
Chemistry, Multidisciplinary
Patricia Garcia-Munoz, Laura Valenzuela, Deborah Wegstein, Tobias Schanz, Girlie Eunice Lopez, Agnieszka M. Ruppert, Hynd Remita, Jonathan Z. Bloh, Nicolas Keller
Summary: Hydrogen peroxide is a powerful and green oxidant that is used in various applications. The article reviews the recent development of photocatalytic synthesis of hydrogen peroxide, discussing different mechanisms, kinetic models, and key reaction parameters. A wide range of photocatalytic materials, including titania-based and graphitic carbon nitride-based systems, are reviewed. Strategies for enhancing the performance of solar-driven photocatalysts and the search for new photocatalytic materials are discussed. The promise of in situ photocatalytic synthesis of hydrogen peroxide, its coupling with enzymes, and the synthesis of other technical peroxides are also described.
TOPICS IN CURRENT CHEMISTRY
(2023)
Article
Engineering, Environmental
Patricia Garcia-Munoz, Cecilia Lopez-Maxias, Sonia Guerra-Rodriguez, Jaime Carbajo, Jose A. Casas, Jorge Rodriguez-Chueca
Summary: In this study, ilmenite paired with peroxymonosulfate (PMS) and UV-A light was found to effectively inactivate Enterococcus faecalis. The system's performance was optimized by adjusting operational parameters and assessing reactive species. Further research and understanding are needed to apply the findings to real wastewater treatment.
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
(2022)
Article
Engineering, Environmental
Patricia Garcia-Munoz, Paul Henri Alle, Calogera Bertoloni, Alvaro Torres, Maria Ulagares de la Orden, Joaquin Martinez Urreaga, Marie-Antoinette Dziurla, Fernando Fresno, Didier Robert, Nicolas Keller
Summary: The study investigates the reliability and quantifiability of a wide range of characterization and analytical tools in monitoring the mineralization process of polystyrene nanoparticles. The immobilized reaction mode is found to be superior to the slurry mode due to the absence of restrictive nanoparticulate photocatalyst. Direct imaging and light-scattering characterization provide incomplete and irrelevant data due to the change in polystyrene substrate morphology. TOC analysis remains the most suitable and reliable technique for monitoring and quantifying the mineralization process of polystyrene nanoparticles.
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
(2022)
Article
Engineering, Environmental
Xinping Zhang, Yuxin Guo, Xiaoyang Liu, Shun-Yu Wu, Ya-Xuan Zhu, Shao-Zhe Wang, Qiu-Yi Duan, Ke-Fei Xu, Zi-Heng Li, Xiao-Yu Zhu, Guang-Yu Pan, Fu-Gen Wu
Summary: This study develops a nanotrigger HCFT for simultaneous photodynamic therapy and light-triggered ferroptosis therapy. The nanotrigger can relieve tumor hypoxia, induce enhanced photodynamic reaction, and facilitate the continuation of Fenton reaction, ultimately leading to lethal ferroptosis in tumor cells.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Olumide Bolarinwa Ayodele, Toyin Daniel Shittu, Olayinka S. Togunwa, Dan Yu, Zhen-Yu Tian
Summary: This study focused on the semihydrogenation of acetylene in an ethylene-rich stream using two alloyed Pt catalysts PtCu and PtCo. The PtCu catalyst showed higher activity and ethylene yield compared to PtCo due to its higher unoccupied Pt d-orbital density. This indicates that alloying Pt with Cu is more promising for industrial relevant SHA catalyst.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Guowei Chen, Wen-Cheng Chen, Yaozu Su, Ruicheng Wang, Jia-Ming Jin, Hui Liang, Bingxue Tan, Dehua Hu, Shaomin Ji, Hao-Li Zhang, Yanping Huo, Yuguang Ma
Summary: This study proposes an intramolecular dual-locking design for organic luminescent materials, achieving high luminescence efficiency and performance for deep-blue organic light-emitting diodes. The material also exhibits unique mechanochromic luminescence behavior and strong fatigue resistance.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Joren van Stee, Gregory Hermans, Jinu Joseph John, Koen Binnemans, Tom Van Gerven
Summary: This work presents a continuous solvent extraction method for the separation of cobalt and nickel in a millifluidic system using Cyphos IL 101 (C101) as the extractant. The optimal conditions for extraction performance and solvent properties were determined by investigating the effects of channel length, flow rate, and temperature. The performance of a developed manifold structure was compared to a single-channel system, and excellent separation results were achieved. The continuous separation process using the manifold structure resulted in high purity cobalt and nickel products.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Yan Xu, Jingai Jiang, Xinyi Lv, Hui Li, Dongliang Yang, Wenjun Wang, Yanling Hu, Longcai Liu, Xiaochen Dong, Yu Cai
Summary: A programmed gas release nanoparticle was developed to address the challenges in treating diabetic infected wounds. It effectively removes drug-resistant pathogens and remodels the wound microenvironment using NO and H2S. The nanoparticle can eliminate bacteria and promote wound healing through antibacterial and anti-inflammatory effects.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Tong Xia, Zhilin Xi, Lianquan Suo, Chen Wang
Summary: This study investigated a highly efficient coal dust suppressant with low initial viscosity and high adhesion-solidification properties. The results demonstrated that the dust suppressant formed a network of multiple hydrogen bonding cross-linking and achieved effective adhesion and solidification of coal dust through various chemical reactions.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Jinzhi Cai, Zhenshan Li
Summary: A density functional theory-based rate equation was developed to predict the gas-solid reaction kinetics of CaO carbonation with CO2 in calcium looping. The negative activation energy of CaO carbonation close to equilibrium was accurately predicted through experimental validation.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Jianxiong Chen, Fuhao Ren, Ningning Yin, Jie Mao
Summary: This study presents an economically efficient and easily implementable surface modification approach to enhance the high-temperature electrical insulation and energy storage performance of polymer dielectrics. The self-assembly of high-insulation-performance boron nitride nanosheets (BNNS) on the film surface through electrostatic interactions effectively impedes charge injection from electrodes while promoting charge dissipation and heat transfer.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Zijian Li, Zhaohui Yang, Shao Wang, Hongxia Luo, Zhimin Xue, Zhenghui Liu, Tiancheng Mu
Summary: This study reports a strategy for upgrading polyester plastics into value-added chemicals using electrocatalytic methods. By inducing the targeted transfer of *OH species, polyethylene terephthalate was successfully upgraded into potassium diformate with high purity. This work not only develops an excellent electrocatalyst, but also provides guidance for the design of medium entropy metal oxides.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Navneet Singh Shekhawat, Surendra Kumar Patra, Ashok Kumar Patra, Bamaprasad Bag
Summary: This study primarily focuses on developing a sulphur dyeing process at room temperature using bacterial Lysate, which is environmentally friendly, energy and cost effective, and sustainable. The process shows promising improvements in dye uptake and fastness properties.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Dengjia Shen, Hongyang Ma, Madani Khan, Benjamin S. Hsiao
Summary: This study developed cationic PVC nanofibrous membranes with high filtration and adsorption capability for the removal of bacteria and hexavalent chromium ions from wastewater. The membranes demonstrated remarkable performance in terms of filtration efficiency and maximum adsorption capacity. Additionally, modified nanofibrous membranes were produced using recycled materials and showed excellent retention rates in dynamic adsorption processes.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Xiaoyan Wang, Zhikun Wang, Ben Jia, Chunling Li, Shuangqing Sun, Songqing Hu
Summary: Inspired by photosystem II, self-supported Fe-doped NiCoP nanowire arrays modified with carboxylate were constructed to boost industrial-level overall water splitting by employing the concerted proton-coupled electron transfer mechanism. The introduction of Fe and carboxyl ligand led to improved catalytic activity for HER and OER, and NCFCP@NF exhibited long-term durability for overall water splitting.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Pengyao Yu, Ge Yang, Yongming Chai, Lubomira Tosheva, Chunzheng Wang, Heqing Jiang, Chenguang Liu, Hailing Guo
Summary: Thin LTA zeolite membranes were prepared through secondary growth of nano LTA seeds in a highly reactive gel, resulting in membranes with superior permeability and selectivity in gas separation applications.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Baiqin Zhou, Huiping Li, Ziyu Wang, Hui Huang, Yujun Wang, Ruichun Yang, Ranran Huo, Xiaoyan Xu, Ting Zhou, Xiaochen Dong
Summary: The use of machine learning to predict the performance of specific adsorbents in phosphate adsorption shows great promise in saving time and revealing underlying mechanisms. However, the small size of the dataset and insufficient detailed information limits the model training process and the accuracy of results. To address this, the study employs a fuzzing strategy that replaces detailed numeric information with descriptive text messages on the physiochemical properties of adsorbents. This strategy allows the recovery of discarded samples with limited information, leading to accurate prediction of adsorption amount, capacity, and kinetics. The study also finds that phosphate uptake by adsorbents is generally through physisorption, with some involvement of chemisorption. The framework established in this study provides a practical approach for quickly predicting phosphate adsorption performance in urgent scenarios, using easily accessible information.
CHEMICAL ENGINEERING JOURNAL
(2024)
Article
Engineering, Environmental
Paula Alejandra Lamprea Pineda, Joren Bruneel, Kristof Demeestere, Lisa Deraedt, Tex Goetschalckx, Herman Van Langenhove, Christophe Walgraeve
Summary: This study evaluates the use of four esterified fatty acids and three vegetable oils as absorption liquids for hydrophobic VOCs. The experimental results show that isopropyl myristate is the most efficient liquid for absorbing the target VOCs.
CHEMICAL ENGINEERING JOURNAL
(2024)