4.8 Article

Honeycomb-like magnetic cornstalk for Cr(VI) removal and ammonium release

Journal

BIORESOURCE TECHNOLOGY
Volume 291, Issue -, Pages -

Publisher

ELSEVIER SCI LTD
DOI: 10.1016/j.biortech.2019.121856

Keywords

Cornstalk; Hexavalent chromium; Ammonium sulfite; High energy electron beam

Funding

  1. Youth Innovation Promotion Association of Chinese Academy of Sciences [2015385]
  2. Science and Technology Service Programs of Chinese Academy of Sciences [KFJ-STS-ZDTP-054, KFJ-STS-QYZD-115]
  3. National Key R&D Program of China [2018YFD0300903-4]
  4. Key R&D Program of Ningxia Province [2018BBF02021]
  5. Science and Technology Major Project of Anhui Province [17030701051]
  6. Environmental Protection Department of Anhui Province [2017-04]

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In this work, cornstalk (CS) was irradiated by high energy electron beam to obtain honeycomb-like porous CS (PCS). The PCS was loaded with ammonium sulfite (AS) and then coated by polyvinyl alcohol (PVA)-Fe3O4 to obtain PCS-AS@ PVA-Fe3O4. The PCS-AS@ PVA-Fe3O4 could reduce hexavalent chromium (Cr(VI)) to trivalent chromium (Cr(III)) by SO32-, then the Cr(III) combined with PCS-AS@ PVA-Fe3O4 through hydrogen bonds. The resulting PCS-AS@ PVA-Fe3O4/Cr with a high magnetism could be conveniently separated from water via a magnet. PCS-AS@ PVA-Fe3O4/Cr showed a high performance on controlling Cr(VI) migration in soil and uptake by plant. Meanwhile, ammonium could be released from PCS-AS@ PVA-Fe3O4, favoring plant growth. Therefore, this work not only provides a promising and low-cost approach to remove Cr(VI) and promote plant growth simultaneously, but also provides a new route for CS recycling, which might have a potential application value.

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