4.7 Article

Boosting visible-light photocatalytic degradation of indomethacin by an efficient and photostable Ag3PO4/NG/WO3 composites

Journal

APPLIED SURFACE SCIENCE
Volume 490, Issue -, Pages 481-491

Publisher

ELSEVIER SCIENCE BV
DOI: 10.1016/j.apsusc.2019.06.072

Keywords

Silver phosphate; Tungsten trioxide; Nitrogen-doped graphene; Visible-light photocatalytic degradation; Indomethacin

Funding

  1. National Natural Science Foundation of China [51578249]
  2. Natural Science Foundation of Guangdong Province [2016A030313434]
  3. Science & Technology Planning Project of Guangdong Province [2015A020215028]

Ask authors/readers for more resources

In our work, Z-scheme Ag3PO4/NG/WO3 composites were fabricated via a facile deposition approach, which was used in the photocatalytic degradation of indomethacin (IDM) under visible light irradiation. The as-prepared Ag3PO4 -based photocatalysts were characterized by X-ray diffraction analysis, scanning electron microscopy, transmission electron microscope, Fourier transform infrared, X-ray photoelectron spectroscopy and UV-visible diffuse reflectance spectroscopy in order to determine the chemical structure, morphological feature and optical performance. From the degradation experiments of IDM, the Ag3PO4/NG/WO3 composite exhibited the highest photocatalytic activity and stability, and its kinetics constant was similar to 8 times of pure Ag3PO4. Furthermore, reactive species trapping experiment, electron spin resonance, liquid chromatography-mass spectrometry, total organic carbon, photoelectrochemical measurement and photoluminescence spectra were applied to analyze the possible degradation pathways and photocatalytic mechanism of IDM. The results indicated that the visible-light photocatalytic degradation of IDM using Ag3PO4/NG/WO3 conformed to a Z-scheme photocatalysis mechanism, further facilitating the photoinduced charge carriers separation, and inhibiting the recombination of photo-induced electron-hole pairs. It also confirmed that the holes, (OH)-O-center dot and O-center dot(2)- radicals generated in Z-scheme system played the significant roles during the photocatalytic degradation of IDM.

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