The Manganese(I)-Catalyzed Asymmetric Transfer Hydrogenation of Ketones: Disclosing the Macrocylic Privilege

Asymmetric Transfer Hydrogenation with a Bifunctional Iron(II) Hydride: Experiment Meets Computation

(2019) Lorena De Luca et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Manganese Catalyzed Asymmetric Transfer Hydrogenation of Ketones Using Chiral Oxamide Ligands

(2019) Matthias Beller et al.   SYNLETT

Introduction: First Row Metals and Catalysis

(2019) Matthias Beller   CHEMICAL REVIEWS

Lutidine-Based Chiral Pincer Manganese Catalysts for Enantioselective Hydrogenation of Ketones

(2019) Linli Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Phosphine-NHC Manganese Hydrogenation Catalyst Exhibiting a Non-Classical Metal-Ligand Cooperative H2 Activation Mode

(2019) Ruqaya Buhaibeh et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Hydrogenation of Ketones using Different Metal Complexes with a Chiral PNP Pincer Ligand

(2019) Marcel Garbe et al.   ADVANCED SYNTHESIS & CATALYSIS

Highly Enantioselective Synthesis of Chiral Benzhydrols via Manganese Catalyzed Asymmetric Hydrogenation of Unsymmetrical Benzophenones Using an Imidazole-Based Chiral PNN Tridentate Ligand

(2019) Fei Ling et al.   ORGANIC LETTERS

Mn(I) and Fe(II)/PN(H)P Catalysts for the Hydrogenation of Ketones: A Comparison by Experiment and Calculation

(2019) Alessandro Passera et al.   ADVANCED SYNTHESIS & CATALYSIS

Manganese Catalyzed Hydrogenation of Carbamates and Urea Derivatives

(2019) Uttam Kumar Das et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanistic Studies of Hydride Transfer to Imines from a Highly Active and Chemoselective Manganate Catalyst

(2019) Frederik Freitag et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanistic Complexity of Asymmetric Transfer Hydrogenation with Simple Mn–Diamine Catalysts

(2019) Robbert van Putten et al.   ORGANOMETALLICS

Practical (asymmetric) transfer hydrogenation of ketones catalyzed by manganese with (chiral) diamines ligands

(2018) Ding Wang et al.   CATALYSIS COMMUNICATIONS

Manganese Catalyzed Hydrogenation of Enantiomerically Pure Esters

(2018) Magnus B. Widegren et al.   ORGANIC LETTERS

Iron(II)-Catalyzed Hydrogenation of Acetophenone with a Chiral, Pyridine-Based PNP Pincer Ligand: Support for an Outer-Sphere Mechanism

(2018) Raffael Huber et al.   ORGANOMETALLICS

Chemoselective Hydrogenation of Aldehydes under Mild, Base-Free Conditions: Manganese Outperforms Rhenium

(2018) Mathias Glatz et al.   ACS Catalysis

P-Stereogenic PN(H)P Iron(II) Catalysts for the Asymmetric Hydrogenation of Ketones: The Importance of Non-Covalent Interactions in Rational Ligand Design by Computation

(2018) Raffael Huber et al.   ADVANCED SYNTHESIS & CATALYSIS

Catalytic Hydrogenation of Cyclic Carbonates using Manganese Complexes

(2018) Akash Kaithal et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Manganese Catalyzed Hydrogenation of Organic Carbonates to Methanol and Alcohols

(2018) Amit Kumar et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Aminotriazole Mn(I) Complexes as Effective Catalysts for Transfer Hydrogenation of Ketones

(2018) Oriol Martínez-Ferraté et al.   ChemCatChem

3d-Metal Catalyzed N- and C-Alkylation Reactions via Borrowing Hydrogen or Hydrogen Autotransfer

(2018) Torsten Irrgang et al.   CHEMICAL REVIEWS

3d Transition Metals for C–H Activation

(2018) Parthasarathy Gandeepan et al.   CHEMICAL REVIEWS

Catalytic Homogeneous Asymmetric Hydrogenation: Successes and Opportunities

(2018) Chris S. G. Seo et al.   ORGANOMETALLICS

Asymmetric Transfer Hydrogenation of Ketones with Well-Defined Manganese(I) PNN and PNNP Complexes

(2018) Karl Z. Demmans et al.   ORGANOMETALLICS

The role of the metal-bound N–H functionality in Noyori-type molecular catalysts

(2018) Pavel A. Dub et al.   Nature Reviews Chemistry

Synthesis and evaluation of haloperidol metabolite II prodrugs as anticancer agents

(2017) Maria Dichiara et al.   Future Medicinal Chemistry

Transfer Hydrogenation of Carbonyl Derivatives Catalyzed by an Inexpensive Phosphine-Free Manganese Precatalyst

(2017) Antoine Bruneau-Voisine et al.   ORGANIC LETTERS

From imine to amine: an unexpected left turn. Cis-β iron(ii) PNNP′ precatalysts for the asymmetric transfer hydrogenation of acetophenone

(2017) Karl Z. Demmans et al.   Chemical Science

Carbon dioxide hydrogenation catalysed by well-defined Mn(i) PNP pincer hydride complexes

(2017) Federica Bertini et al.   Chemical Science

Efficient and selective hydrogenation of amides to alcohols and amines using a well-defined manganese–PNN pincer complex

(2017) Veronica Papa et al.   Chemical Science

Highly Active and Selective Manganese C=O Bond Hydrogenation Catalysts: The Importance of the Multidentate Ligand, the Ancillary Ligands, and the Oxidation State

(2016) Fabian Kallmeier et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Hydrogenation of Esters to Alcohols Catalyzed by Defined Manganese Pincer Complexes

(2016) Saravanakumar Elangovan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Manganese-Catalyzed Hydrogenation of Esters to Alcohols

(2016) Noel Angel Espinosa-Jalapa et al.   CHEMISTRY-A EUROPEAN JOURNAL

Molecularly Defined Manganese Pincer Complexes for Selective Transfer Hydrogenation of Ketones

(2016) Marc Perez et al.   ChemSusChem

Selective Catalytic Hydrogenations of Nitriles, Ketones, and Aldehydes by Well-Defined Manganese Pincer Complexes

(2016) Saravanakumar Elangovan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Enantioselective Transfer Hydrogenation of Polar Double Bonds by Macrocyclic Iron(II)/(NH)2P2 Catalysts

(2016) Raphael Bigler et al.   ORGANIC PROCESS RESEARCH & DEVELOPMENT

Iron(II) Complexes Containing Chiral Unsymmetrical PNP′ Pincer Ligands: Synthesis and Application in Asymmetric Hydrogenations

(2016) Afrooz Zirakzadeh et al.   ORGANOMETALLICS

Ketone Asymmetric Hydrogenation Catalyzed by P-NH-P′ Pincer Iron Catalysts: An Experimental and Computational Study

(2016) Jessica F. Sonnenberg et al.   ACS Catalysis

Iron(II)/(NH)2P2 Macrocycles: Modular, Highly Enantioselective Transfer Hydrogenation Catalysts

(2016) Raphael Bigler et al.   ACS Catalysis

Getting Down to Earth: The Renaissance of Catalysis with Abundant Metals

(2015) Paul Chirik et al.   ACCOUNTS OF CHEMICAL RESEARCH

Exploration of Earth-Abundant Transition Metals (Fe, Co, and Ni) as Catalysts in Unreactive Chemical Bond Activations

(2015) Bo Su et al.   ACCOUNTS OF CHEMICAL RESEARCH

Highly Enantioselective Transfer Hydrogenation of Ketones with Chiral (NH)2P2Macrocyclic Iron(II) Complexes

(2015) Raphael Bigler et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Haloperidol metabolite II prodrug: Asymmetric synthesis and biological evaluation on rat C6 glioma cells

(2015) Piera Sozio et al.   EUROPEAN JOURNAL OF MEDICINAL CHEMISTRY

Details of the Mechanism of the Asymmetric Transfer Hydrogenation of Acetophenone Using the Amine(imine)diphosphine Iron Precatalyst: The Base Effect and The Enantiodetermining Step

(2015) Weiwei Zuo et al.   ACS Catalysis

The activation strain model and molecular orbital theory: understanding and designing chemical reactions

(2014) Israel Fernández et al.   CHEMICAL SOCIETY REVIEWS

Iron(II) Complexes Containing Unsymmetrical P–N–P′ Pincer Ligands for the Catalytic Asymmetric Hydrogenation of Ketones and Imines

(2014) Paraskevi O. Lagaditis et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Isonitrile Iron(II) Complexes with Chiral N2P2 Macrocycles in the Enantioselective Transfer Hydrogenation of Ketones

(2014) Raphael Bigler et al.   ORGANIC LETTERS

Synthesis of Iron P-N-P′ and P-NH-P′ Asymmetric Hydrogenation Catalysts

(2014) Jessica F. Sonnenberg et al.   ORGANOMETALLICS

Abundant Metals Give Precious Hydrogenation Performance

(2013) R. M. Bullock   SCIENCE

Amine(imine)diphosphine Iron Catalysts for Asymmetric Transfer Hydrogenation of Ketones and Imines

(2013) W. Zuo et al.   SCIENCE

Iron Nanoparticles Catalyzing the Asymmetric Transfer Hydrogenation of Ketones

(2012) Jessica F. Sonnenberg et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The Mechanism of Efficient Asymmetric Transfer Hydrogenation of Acetophenone Using an Iron(II) Complex Containing an (S,S)-Ph2PCH2CH═NCHPhCHPhN═CHCH2PPh2 Ligand: Partial Ligand Reduction Is the Key

(2012) Alexandre A. Mikhailine et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Resolving Heterogeneity Problems and Impurity Artifacts in Operationally Homogeneous Transition Metal Catalysts

(2011) Robert H. Crabtree   CHEMICAL REVIEWS

Revealing Noncovalent Interactions

(2010) Erin R. Johnson et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Efficient Asymmetric Transfer Hydrogenation of Ketones Catalyzed by an Iron Complex Containing a P−N−N−P Tetradentate Ligand Formed by Template Synthesis

(2009) Alexandre Mikhailine et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Efficient Catalyst Systems Using Iron Complexes with a Tetradentate PNNP Ligand for the Asymmetric Hydrogenation of Polar Bonds

(2007) Christine Sui-Seng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION