Enantioselective Radical Addition/Cross-Coupling of Organozinc Reagents, Alkyl Iodides, and Alkenyl Boron Reagents

Enantioselective Construction of Quaternary All-Carbon Centers via Copper-Catalyzed Arylation of Tertiary Carbon-Centered Radicals

(2019) Lianqian Wu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Conjunctive Coupling of Carboxylic Acid Derivatives with 9-BBN-Derived Ate Complexes

(2019) James Patrick Morken et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ni-Catalyzed Asymmetric Reductive Arylalkylation of Unactivated Alkenes

(2019) Youxiang Jin et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Nickel-Catalyzed Asymmetric Reductive Diarylation of Vinylarenes

(2019) David Anthony et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Highly Enantioselective Cross-Electrophile Aryl-Alkenylation of Unactivated Alkenes

(2019) Zhi-Xiong Tian et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Selective, Intermolecular Alkylarylation of Alkenes via Photoredox/Nickel Dual Catalysis

(2019) Lei Guo et al.   ORGANIC LETTERS

Synthesis of α-Chiral Ketones and Chiral Alkanes Using Radical Polar Crossover Reactions of Vinyl Boron Ate Complexes

(2018) Carolin Gerleve et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Visible-Light-Mediated Decarboxylative Radical Additions to Vinyl Boronic Esters: Rapid Access to γ-Amino Boronic Esters

(2018) Adam Noble et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ni-catalyzed two-component reductive dicarbofunctionalization of alkenes via radical cyclization

(2018) Yulong Kuang et al.   CHEMICAL COMMUNICATIONS

Transition Metal-Catalyzed Dicarbofunctionalization of Unactivated Olefins

(2018) Roshan K. Dhungana et al.   CHEMICAL RECORD

Radical-Triggered Three-Component Coupling Reaction of Alkenylboronates, α-Halocarbonyl Compounds, and Organolithium Reagents: The Inverse Ylid Mechanism

(2018) Nicholas D. C. Tappin et al.   CHEMISTRY-A EUROPEAN JOURNAL

Ni-Catalyzed Regioselective Dicarbofunctionalization of Unactivated Olefins by Tandem Cyclization/Cross-Coupling and Application to the Concise Synthesis of Lignan Natural Products

(2018) Shekhar KC et al.   JOURNAL OF ORGANIC CHEMISTRY

Enantioselective 1,2-Difunctionalization of 1,3-Butadiene by Sequential Alkylation and Carbonyl Allylation

(2018) Yang Xiong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Radical-Polar Crossover Reactions of Dienylboronate Complexes: Synthesis of Functionalized Allylboronic Esters

(2018) Marvin Kischkewitz et al.   ORGANIC LETTERS

Directed nickel-catalyzed 1,2-dialkylation of alkenyl carbonyl compounds

(2018) Joseph Derosa et al.   Chemical Science

Nickel-catalyzed difunctionalization of allyl moieties using organoboronic acids and halides with divergent regioselectivities

(2018) Wanfang Li et al.   Chemical Science

Ni-catalysed regioselective 1,2-diarylation of unactivated olefins by stabilizing Heck intermediates as pyridylsilyl-coordinated transient metallacycles

(2018) Surendra Thapa et al.   Chemical Science

Synthesis of Functionalized Cyclopropanes from Carboxylic Acids via a Radical Addition-Polar Cyclization Cascade

(2018) Chao Shu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Construction of Tertiary Boronic Esters by Conjunctive Cross-Coupling

(2018) Jesse A. Myhill et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ni-Catalyzed Regioselective Alkylarylation of Vinylarenes via C(sp3)–C(sp3)/C(sp3)–C(sp2) Bond Formation and Mechanistic Studies

(2018) Shekhar KC et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-Catalyzed Stereoselective Diarylation of Alkenylarenes

(2018) Pin Gao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ni-Catalyzed Enantioselective Reductive Diarylation of Activated Alkenes by Domino Cyclization/Cross-Coupling

(2018) Kuai Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-Catalyzed Synthesis of Benzo[b]naphtho[1,2-d]azepine via Intramolecular Radical Tandem Cyclization of Alkyl Bromide-Tethered Alkylidenecyclopropanes

(2018) Bo Jiang et al.   ORGANIC LETTERS

Diastereoselective and Enantioselective Conjunctive Cross-Coupling Enabled by Boron Ligand Design

(2018) Jesse A. Myhill et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synergistic Bimetallic Ni/Ag and Ni/Cu Catalysis for Regioselective γ,δ-Diarylation of Alkenyl Ketimines: Addressing β-H Elimination by in Situ Generation of Cationic Ni(II) Catalysts

(2018) Prakash Basnet et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-Catalyzed 1,2-Diarylation of Simple Alkenyl Amides

(2018) Joseph Derosa et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cu/Chiral Phosphoric Acid-Catalyzed Asymmetric Three-Component Radical-Initiated 1,2-Dicarbofunctionalization of Alkenes

(2018) Jin-Shun Lin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Visible-Light-Mediated Deaminative Three-Component Dicarbofunctionalization of Styrenes with Benzylic Radicals

(2018) Felix J. R. Klauck et al.   ACS Catalysis

Merging Photoredox with 1,2-Metallate Rearrangements: The Photochemical Alkylation of Vinyl Boronate Complexes

(2017) Mattia Silvi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-Catalyzed β,γ-Dicarbofunctionalization of Alkenyl Carbonyl Compounds via Conjunctive Cross-Coupling

(2017) Joseph Derosa et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Conjunctive Cross-Coupling of Bis(alkenyl)borates: A General Synthesis of Chiral Allylboron Reagents

(2017) Emma K. Edelstein et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pd-Catalyzed Conjunctive Cross-Coupling between Grignard-Derived Boron “Ate” Complexes and C(sp2) Halides or Triflates: NaOTf as a Grignard Activator and Halide Scavenger

(2017) Gabriel J. Lovinger et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ni-Catalyzed Enantioselective Conjunctive Coupling with C(sp3) Electrophiles: A Radical-Ionic Mechanistic Dichotomy

(2017) Gabriel J. Lovinger et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-Catalyzed Reductive Dicarbofunctionalization of Alkenes

(2017) Andrés García-Domínguez et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Cu-Catalyzed Intermolecular Trifluoromethylarylation of Styrenes: Enantioselective Arylation of Benzylic Radicals

(2017) Lianqian Wu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ni-Catalyzed Regioselective 1,2-Dicarbofunctionalization of Olefins by Intercepting Heck Intermediates as Imine-Stabilized Transient Metallacycles

(2017) Bijay Shrestha et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed Dicarbofunctionalization of Unactivated Olefins by Tandem Cyclization/Cross-Coupling

(2017) Surendra Thapa et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Radical-polar crossover reactions of vinylboron ate complexes

(2017) Marvin Kischkewitz et al.   SCIENCE

Fragment Coupling with Tertiary Radicals Generated by Visible-Light Photocatalysis

(2016) Christopher R. Jamison et al.   ACCOUNTS OF CHEMICAL RESEARCH

Tandem Difluoroalkylation-Arylation of Enamides Catalyzed by Nickel

(2016) Ji-Wei Gu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Additive Effects on Asymmetric Catalysis

(2016) Liang Hong et al.   CHEMICAL REVIEWS

Enantioselective Copper-Catalyzed Intermolecular Cyanotrifluoromethylation of Alkenes via Radical Process

(2016) Fei Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A general, modular method for the catalytic asymmetric synthesis of alkylboronate esters

(2016) J. Schmidt et al.   SCIENCE

A general alkyl-alkyl cross-coupling enabled by redox-active esters and alkylzinc reagents

(2016) T. Qin et al.   SCIENCE

Radical Instability in Aid of Efficiency: A Powerful Route to Highly Functional MIDA Boronates

(2015) Béatrice Quiclet-Sire et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Enantioselective Diarylation of Alkenes

(2015) Wei You et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective 1,2-Difunctionalization of Dienes Enabled by Chiral Palladium Complex-Catalyzed Cascade Arylation/Allylic Alkylation Reaction

(2015) Xiang Wu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iron-Catalyzed Oxidative C–H/C–H Cross-Coupling between Electron-Rich Arenes and Alkenes

(2015) Yiyang Ma et al.   ORGANIC LETTERS

Catalytic conjunctive cross-coupling enabled by metal-induced metallate rearrangement

(2015) L. Zhang et al.   SCIENCE

Highly Enantioselective Rhodium(I)-Catalyzed Activation of Enantiotopic Cyclobutanone CC Bonds

(2014) Laetitia Souillart et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Structure–kinetic relationship study of organozinc reagents

(2014) Guanghui Zhang et al.   CHEMICAL COMMUNICATIONS

Catalytic Enantioselective Cyclization/Cross-Coupling with Alkyl Electrophiles

(2014) Huan Cong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed Intermolecular Trifluoromethylarylation of Alkenes: Mutual Activation of Arylboronic Acid and CF3+ Reagent

(2014) Fei Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Functionalized olefin cross-coupling to construct carbon–carbon bonds

(2014) Julian C. Lo et al.   NATURE

A Palladium-Catalyzed Three-Component-Coupling Strategy for the Differential Vicinal Diarylation of Terminal 1,3-Dienes

(2014) Benjamin J. Stokes et al.   ORGANIC LETTERS

Atom- and Step-Economical Pathway to Chiral Benzobicyclo[2.2.2]octenones through Carbon-Carbon Bond Cleavage

(2012) Lantao Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Nickel-Mediated Inter- and Intramolecular Reductive Cross-Coupling of Unactivated Alkyl Bromides and Aryl Iodides at Room Temperature

(2012) Chang-Song Yan et al.   CHEMISTRY-A EUROPEAN JOURNAL

Highly Enantioselective Rh-Catalyzed Carboacylation of Olefins: Efficient Syntheses of Chiral Poly-Fused Rings

(2012) Tao Xu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Split Personality of Lithium Chloride: Recent Salt Effects in Organometallic Recipes

(2011) Eva Hevia et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Bond Formations between Two Nucleophiles: Transition Metal Catalyzed Oxidative Cross-Coupling Reactions

(2011) Chao Liu et al.   CHEMICAL REVIEWS

Vicinal C-Functionalization of Alkenes. Pd/Light-Induced Multicomponent Coupling Reactions Leading to Functionalized Esters and Lactones

(2011) Akira Fusano et al.   ORGANIC LETTERS

Nickel-Catalyzed Reductive Cross-Coupling of Unactivated Alkyl Halides

(2011) Xiaolong Yu et al.   ORGANIC LETTERS

Lithium Organozincate Complexes LiRZnX2: Common Species in Organozinc Chemistry

(2011) Julia E. Fleckenstein et al.   ORGANOMETALLICS

What is the Rate of the Csp2−Csp2Reductive Elimination Step? Revealing an Unusually Fast Ni-Catalyzed Negishi-Type Oxidative Coupling Reaction

(2009) Liqun Jin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanistic approaches to palladium-catalyzed alkene difunctionalization reactions

(2008) Katrina H. Jensen et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Enantioselective Synthesis of 3,3-Disubstituted Oxindoles through Pd-Catalyzed Cyanoamidation

(2008) Yoshizumi Yasui et al.   ORGANIC LETTERS