Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 362, Issue 4, Pages 755-759Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201901318
Keywords
gold catalysis; gold carbene; N-oxides; diyne; carbene transfer
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Funding
- CSC (China Scholarship Council)
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A vinyl/alpha-oxo carbene is generated via an alpha-oxo carbene formation and subsequently transferred across the second alkyne. These highly active species can react with nitriles in an intermolecular fashion to provide substituted oxazoles. This methodology goes through 1,6-carbene shift and offers a range of valuable products.
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