Journal
ADVANCED MATERIALS
Volume 31, Issue 48, Pages -Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.201904735
Keywords
0D; 3D heterostructured; high performance; inorganic perovskite; phase stability; solar cell
Categories
Funding
- City University of Hong Kong [7200587, 9610421] Funding Source: Medline
- Hong Kong Research Grants Council [606012, 16322416, 16305915, 16303917] Funding Source: Medline
- NSF [DMR-1719797, CHE-1856210, MRI- 1624430] Funding Source: Medline
- Office of Naval Research [N00014-17-1-2201] Funding Source: Medline
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Although organic-inorganic hybrid perovskite solar cells (PVSCs) have achieved dramatic improvement in device efficiency, their long-term stability remains a major concern prior to commercialization. To address this issue, extensive research efforts are dedicated to exploiting all-inorganic PVSCs by using cesium (Cs)-based perovskite materials, such as alpha-CsPbI3. However, the black-phase CsPbI3 (cubic alpha-CsPbI3 and orthorhombic gamma-CsPbI3 phases) is not stable at room temperature, and it tends to convert to the nonperovskite delta-CsPbI3 phase. Here, a simple yet effective approach is described to prepare stable black-phase CsPbI3 by forming a heterostructure comprising 0D Cs4PbI6 and gamma-CsPbI3 through tuning the stoichiometry of the precursors between CsI and PbI. Such heterostructure is manifested to enable the realization of a stable all-inorganic PVSC with a high power conversion efficiency of 16.39%. This work provides a new perspective for developing high-performance and stable all-inorganic PVSCs.
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