Article
Chemistry, Physical
Maryam Sadat Ghorashi, Hamid Reza Madaah Hosseini, Ezeddin Mohajerani, Marco Pedroni, Reza Taheri Ghahrizjani
Summary: This study demonstrated the successful preparation of very small upconverter SrF2:Yb,Tm@ CaF2:Yb @Fluorine-doped TiO2 heteronanoparticles with strong photocatalytic performance. The nanoparticles showed superior photocatalytic functioning in degrading methylene blue under various light sources, and also exhibited efficient reactive oxygen species generation ability under NIR light for potential application in photodynamic therapy.
JOURNAL OF PHYSICAL CHEMISTRY C
(2021)
Article
Chemistry, Multidisciplinary
Tongtong Liu, Xiaomeng Liu, Yansong Feng, Chang-Jiang Yao
Summary: This review explores the processes and factors affecting plasmon-enhanced upconversion, investigating the influence of plasmonic nanostructures on upconversion efficiency.
MATERIALS TODAY CHEMISTRY
(2023)
Article
Materials Science, Ceramics
Meidong Yu, Yun Zhang, Bo Liu, Jiandi Liu, Zuofu Hu, Wen Ruan, Xinyuan Sun
Summary: In this study, a novel core-shell hybrid structure of (mCu2-xS, NaYF4:Er/Yb)@ porous silica composites was constructed for upconversion luminescence (UCL). The amplified internal optical field of the composites, induced by the localized surface plasmon resonance (LSPR) coupling between Cu2-xS nanoparticles, allowed more photons to participate in the upconversion process. The UCL intensity of the composites in the emission band of green was 45 times higher than that of NaYF4:Er/Yb@SiO2, and the quantum yield of the composites was 1.32%. The UCL enhancement mechanism of the composites was also investigated.
CERAMICS INTERNATIONAL
(2023)
Article
Chemistry, Physical
Beata Tim, Paulina Blaszkiewicz, Michal Kotkowiak
Summary: This study explains how local excitation of gold nanorods (Au-NRs) causes a temperature increase in their vicinity and affects the properties of a model cell membrane. The results show that illumination of the Au-NRs changes the organization of the model membrane and makes it more stable and elastic. These findings are important for understanding how the photoactivation of nanoparticles influences the transport of medicinal substances.
JOURNAL OF MOLECULAR LIQUIDS
(2022)
Article
Nanoscience & Nanotechnology
Feng Xu, Ying Sun, Huiping Gao, Suyue Jin, Zhenlong Zhang, Huafang Zhang, Gencai Pan, Miao Kang, Xinqi Ma, Yanli Mao
Summary: By synthesizing NaCsWO3@NaYF4@NaYF4:Yb,Er nanoparticles to enhance the UCL intensity, which were then used in PSCs, the power conversion efficiency of highly efficient PSCs reached 18.89%, showing a significant improvement compared to the control group.
ACS APPLIED MATERIALS & INTERFACES
(2021)
Review
Chemistry, Multidisciplinary
Blassan P. George, Alexander Chota, Paromita Sarbadhikary, Heidi Abrahamse
Summary: The introduction of nanotechnology in Photodynamic Therapy (PDT) has shown great potential in overcoming challenges associated with traditional photosensitizers (PSs). Combining traditional PSs with metallic nanoparticles can enhance singlet oxygen production and light excitability.
FRONTIERS IN CHEMISTRY
(2022)
Editorial Material
Biotechnology & Applied Microbiology
Ruixue Xiao, Jian Zeng, Fangyuan Li, Daishun Ling
Summary: Phototherapeutics is an increasingly popular cancer treatment, and gold-semiconductor nanocomposites have emerged as promising agents due to their tunability, biocompatibility, and diversity. This perspective explores the latest research on these nanohybrids for photodynamic, photothermal, and photocatalytic therapies, providing insights for the design and fabrication of novel composite nanoplatforms to enhance phototherapeutic efficiency and advance nanotechnology-based biomedical applications.
Article
Optics
Feng Xu, Wen Luo, Aibibula Abudula, Yuying Wang, Zhijun Sun
Summary: Resonant control and enhancement of upconversion luminescence (UCL) of NaYF4:Yb,Er nanoparticles were achieved using multiplexed metal gratings. By designing doublet plasmon resonance modes at the excitation and green- or red-UCL emission wavelengths, or at the excitation wavelength and one of the emission wavelengths, the excitation/emission efficiencies of UCL were improved. Experimental results showed that matching the doublet plasmon resonance modes with both the excitation and emission wavelengths led to further UCL enhancements and significant modification of the emission intensity ratios. The mechanisms and resonance structures were investigated by analyzing the dependence of UCL emissions on excitation power and lifetimes. These principles and resonance structures can be applied to a broad range of optical phenomena involving photons of multiple frequencies.
JOURNAL OF LUMINESCENCE
(2023)
Article
Chemistry, Physical
Chengyun Zhang, Yuyang Wang, Xiaohu Mi, Dazhong Wang, Huan Chen, Jinping Li, Zhengkun Fu, Zhenglong Zhang
Summary: In this study, horizontally aligned gold nanorod arrays with self-contained spacer and polarization-dependent plasmonic properties were prepared on silicon wafer substrates using a self-assembly method. The enhancement of upconversion luminescence of rare earth ions doped nanoparticles (NaYF4: Yb3+, Er3+) was investigated. Results showed that the luminescence intensity of the nanoparticles was greatly enhanced when the horizontally aligned gold nanorod arrays were used as a substrate. The self-contained spacer effectively prevented quenching of the luminescence and the arrays exhibited excellent optical polarization anisotropy.
JOURNAL OF ALLOYS AND COMPOUNDS
(2023)
Article
Materials Science, Ceramics
Ying Sun, Huiping Gao, Hao Zhang, Feng Xu, Wenwu You, Gencai Pan, Huafang Zhang, Zhenlong Zhang, Yanli Mao
Summary: This paper focuses on the development and utilization of novel semiconductor nanocrystals with remarkable localized surface plasmon resonance (LSPR) effect. Tungsten bronze nanocrystals with strong LSPR effect have been synthesized by introducing high valence metal ions, and the regulation and application of the corresponding LSPR effect are still being explored. Sn0.33WO3 nanocrystals with different crystal phases and morphologies were synthesized using different types of Sn precursors, and the acid radical ions provided by different types of Sn precursors were found to be an important factor affecting the LSPR absorption characteristics. The LSPR effect of Sn0.33WO3 enhances the excitation field of NaYF4:Yb3+, Er3+ nanocrystals, resulting in significant upconversion luminescence enhancement in the layered Glass/Sn0.33WO3/PMMA/NaYF4:Yb3+, Er3+ film.
CERAMICS INTERNATIONAL
(2023)
Review
Chemistry, Multidisciplinary
Pavan Kumar Chintamaneni, Dasari Nagasen, Katta Chanti Babu, Atul Mourya, Jitender Madan, Dadi A. Srinivasarao, R. K. Ramachandra, P. Madhuri Santhoshi, Sai Kiran S. S. Pindiprolu
Summary: Breast cancer is the most common type of cancer in women, and early diagnosis and effective therapeutic interventions are crucial for improving survival and quality of life. Nanotheranostics, specifically rare earth metal-doped upconversion nanoparticles (UCNPs), show promise in providing both in vivo diagnosis and therapeutics in breast cancer treatment.
JOURNAL OF CONTROLLED RELEASE
(2022)
Article
Chemistry, Applied
Yuanyuan Zhang, Jing Wang, Wanlu Sun, Hui Yu, Shubo An, Hai-Yan Wang, Yi Liu
Summary: Increasing interest has been observed in the design of photosensitizers. Most small molecular photosensitizers currently have limitations in penetration depth and photostability. In order to overcome these drawbacks, Frequency upconversion luminescence (FUCL) small molecules were used for photosensitizer design, as they offer deeper penetration, sensitive imaging, and improved photostability. A series of FUCL molecules with rigid structures (NIR-NH2, NIR-NHEt, NIR-NEt2) were developed, with NIR-NEt2 showing the highest generation of singlet oxygen, strongest upconversion luminescence intensity under 808 nm irradiation, and mitochondria-targeted ability. FUCL can serve as a superior molecular platform for image-guided photodynamic therapy of cancer cells.
Article
Chemistry, Physical
Yun Zhou, Peng Zheng, Fang Wang, Fangna Gu, Wenqing Xu, Qinyang Lu, Tingyu Zhu, Ziyi Zhong, Guangwen Xu, Fabing Su
Summary: This study successfully prepared a three-dimensional honeycomb N-doped carbon nanomaterial with good photothermal catalytic performance, and investigated the synergistic effect of NiO@Ni and NC on the CO2 reduction reaction and water splitting reaction.
Review
Biotechnology & Applied Microbiology
Mitchell Lee Taylor, Raymond Edward Wilson, Kristopher Daniel Amrhein, Xiaohua Huang
Summary: Noble metal nanoparticles, especially gold nanorods, have been widely used in cancer photothermal therapy due to their unique optical properties and long blood circulation half-life. This review summarizes the optical properties of gold nanorods and their applications in photothermal therapy, as well as recent strategies to improve the therapy through combination with chemotherapy and photodynamic therapy.
BIOENGINEERING-BASEL
(2022)
Review
Engineering, Biomedical
Zhuoqian Lv, Sijia He, Youfu Wang, Xinyuan Zhu
Summary: Developing anticancer therapeutic agents or technologies with high specificity, patient compliance, and low toxicity is important. Noble metal nanomaterials present strong potential for cancer treatment through photothermal therapy, with the ability to achieve multifunctional cancer therapy when combined with various functional reagents.
ADVANCED HEALTHCARE MATERIALS
(2021)
Article
Chemistry, Physical
Huiting Bi, Fei He, Yushan Dong, Dan Yang, Yunlu Dai, Liangge Xu, Ruichan Lv, Shili Gai, Piaoping Yang, Jun Lin
CHEMISTRY OF MATERIALS
(2018)
Article
Chemistry, Physical
Lili Feng, Shili Gai, Yunlu Dai, Fei He, Chunqiang Sun, Piaoping Yang, Ruichan Lv, Na Niu, Guanghui An, Jun Lin
CHEMISTRY OF MATERIALS
(2018)
Article
Chemistry, Inorganic & Nuclear
Miao Feng, Ruichan Lv, Liyang Xiao, Bo Hu, Shouping Zhu, Fei He, Piaoping Yang, Jie Tian
INORGANIC CHEMISTRY
(2018)
Article
Chemistry, Multidisciplinary
Ruichan Lv, Miao Feng, Wolfgang J. Parak
Article
Chemistry, Inorganic & Nuclear
Ruichan Lv, Liyang Xiao, Yanxing Wang, Fan Yang, Jie Tian, Jun Lin
INORGANIC CHEMISTRY
(2019)
Article
Materials Science, Biomaterials
Ruichan Lv, Yanxing Wang, Jun Liu, Miao Feng, Fan Yang, Xue Jiang, Jie Tian
ACS BIOMATERIALS SCIENCE & ENGINEERING
(2019)
Article
Materials Science, Biomaterials
Ruichan Lv, Miao Feng, Jun Liu, Xue Jiang, Huijuan Yuan, Ruyu Yan, Jie Tian
ACS BIOMATERIALS SCIENCE & ENGINEERING
(2019)
Article
Chemistry, Physical
Bi Lin, Jun Liu, Yanxing Wang, Fan Yang, Liyu Huang, Ruichan Lv
CHEMISTRY OF MATERIALS
(2020)
Article
Chemistry, Analytical
Ruichan Lv, Yanxing Wang, Bi Lin, Xiangrong Peng, Jun Liu, Wei-dong Lu, Jie Tian
Summary: The study proposes a strategy of combining antibodies with optical probes for the precise diagnosis of lung adenocarcinoma, utilizing hub genes and designed fluorescence imaging probes with multimodal optical imaging properties. The results show that this dual-modal luminescence imaging method can be excellently used for accurate diagnosis and surgery navigation.
ANALYTICAL CHEMISTRY
(2021)
Article
Nanoscience & Nanotechnology
Yaqun Ma, Yanxing Wang, Xin Hui, Bi Lin, Ying Yuan, Xiaofeng Tao, Ruichan Lv
Summary: In this research, a fluorescent probe with multiple binding sites was synthesized to detect biothiols in tumor cells with strong NIR II luminescence. The probe showed good stability and biocompatibility with little luminescence quenching in aqueous phase. When combined with bevacizumab and Capmatinib, the probe exhibited stronger targeted imaging in head and neck squamous cell carcinoma.
Review
Chemistry, Inorganic & Nuclear
Ruichan Lv, Micah Raab, Yanxing Wang, Jie Tian, Jun Lin, Paras N. Prasad
Summary: Researchers have proposed a method using rare-earth doped nanoparticles for photon upconversion luminescence and downshifting luminescence, and optimized the nanostructures with the help of artificial intelligence and machine learning to achieve more efficient optical imaging and theranostics. The method can be applied in deep tissue imaging, multimodal imaging, nanothermometry, photodynamic therapy, and more.
COORDINATION CHEMISTRY REVIEWS
(2022)
Article
Chemistry, Physical
Ruichan Lv, Zhan Wang, Yaqun Ma, Wenjing Li, Jie Tian
Summary: This article discusses the importance of combining machine learning methods with spectroscopic detection methods in disease detection, and highlights the effectiveness and potential of support vector machine and convolutional neural network in spectral analysis.
JOURNAL OF PHYSICAL CHEMISTRY LETTERS
(2022)
Article
Chemistry, Multidisciplinary
Yanxing Wang, Miao Feng, Bi Lin, Xiangrong Peng, Zhan Wang, Ruichan Lv
Summary: Degradable peptide-modified upconversion nanoparticles (ZUPEA) were designed for NIR II imaging and photodynamic therapy of triple-negative breast cancer. These nanoparticles showed good therapeutic effects in vitro and could recognize TNBC cells in vivo, providing new ideas for clinical tumor treatment.
Article
Chemistry, Multidisciplinary
Fan Yang, Jun Liu, Xue Jiang, Weiwei Wu, Zhenni Wang, Qi Zeng, Ruichan Lv