Journal
TETRAHEDRON LETTERS
Volume 60, Issue 38, Pages -Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2019.151018
Keywords
Transition-metal-free; Isocyanate; Aryne; Diarylation
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Funding
- Basic Science Research Program through the National Research Foundation of Korea (NRF) - Ministry of Science, ICT & Future Planning [NRF-2015R1C1A2A01051829, NRF-2018R1D1A1B07042179, NRF-2017R1A4A1015594]
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A facile method for the transition-metal-free diarylation of isocyanates with arynes in the presence of cesium fluoride has been developed, which affords functionalized diaryl amines in moderate to excellent yields. This reaction has good functional group tolerance and provides excellent regioselectivity by utilizing a methoxy-substituted aryne precursor. (C) 2019 Elsevier Ltd. All rights reserved.
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