Journal
POLYMER TESTING
Volume 81, Issue -, Pages -Publisher
ELSEVIER SCI LTD
DOI: 10.1016/j.polymertesting.2019.106109
Keywords
Polymeric ionic liquids; CO2; Adsorption; Immobilization
Funding
- National Natural Science Foundation of China [51876150, 21808183]
- Research Institute of Shaanxi Yanchang Petroleum (Group) Co. Ltd. [YJSYZX18SKF0003]
- Special Fund for Basic Scientific Research of Central College of Chang'an University [300102319205]
Ask authors/readers for more resources
The CO2 capture materials and technology have received much attention in recent years due to the environmental deterioration caused by the greenhouse gas emissions. Several imidazolium polymeric ionic liquids (PILs) were synthesized and immobilized on mesoporous gamma-Al2O3 (MA) using ultrasonic immersion method. The prepared adsorbents were characterized by FT-IR, H-1 NMR, EA, TGA, SEM, XRD, BET and TEM, indicating the successful synthesis of the desired PILs/MA. The CO2 adsorption capacity was investigated under different loading ratios, temperatures, pressures and CO2 flow rates, whose optimal adsorption conditions were 1/1, 313 K, 5 bar and 10 mL/min, respectively. Moreover, the adsorption curves for P[VCIm]Cl/MA were coincident with pseudo-second order model, and the CO2 adsorption kinetics model was calculated and obtained. Compared with P[VRIm]Cl and P[VEIm]Cl, P[VCIm]Cl/MA demonstrated an outstanding adsorption amount of 0.562 mmol/g under the suitable conditions, and its regeneration efficiency could achieve 94.8% after 5 times cycle.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available