Journal
JOURNAL OF SOLID STATE ELECTROCHEMISTRY
Volume 23, Issue 10, Pages 2937-2950Publisher
SPRINGER
DOI: 10.1007/s10008-019-04392-5
Keywords
Ni3S4 closely packed nanosheets; Hydrothermal growth; Polyethylene glycol; Symmetric supercapacitor device; Energy density
Categories
Funding
- University Grants Commission, New Delhi through the Rajiv Gandhi National Fellowship (RGNF) [RGNF-2015-17-SC-TAM-18395]
- Department of Science and Technology, Government of India [SR/FST/PSI-199/2015(G)]
Ask authors/readers for more resources
Rich redox peaks, high surface area, good surface wettability, fast ion passage channels, high rate capability and excellent stability are some of the essential features of an electrode for the superior electrochemical performance of a material for charge storage applications. In this work, we report the synthesis of Ni3S4 nanostructures on Ni-foam at various polyethylene glycol (PEG) concentrations, via the hydrothermal route, for supercapacitor applications. The Ni3S4 nanostructures prepared with 402 mM PEG concentration (PNS3) offers a high specific capacitance of 1458 F g(-1) at 2 A g(-1) and retain 37% of rate capacitance at a high and more realistic current density of 50 A g(-1). The PNS3 nanosheets exhibit outstanding stability over 2400 repeated cycling processes. The best capacitive performance of PNS3 is owing to its high surface area, closely packed nanosheet morphology, good surface wettability, uniform growth on the substrate and effective storage of hydroxyl ions in the mesopores. A symmetric supercapacitor device (PNS3//PNS3) delivers a large energy density of 34 W h kg(-1) with a power density of 350 W kg(-1). The electrochemical results and excellent symmetric device performance recommend Ni3S4 nanosheets (PNS3) to be a promising electrode material for supercapacitor applications.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available