4.8 Article

Bio-inspired poly(3,4-ethylenedioxythiophene): Poly(styrene sulfonate)-sulfur@polyacrylonitrile electrospun nanofibers for lithium-sulfur batteries

Journal

JOURNAL OF POWER SOURCES
Volume 431, Issue -, Pages 250-258

Publisher

ELSEVIER SCIENCE BV
DOI: 10.1016/j.jpowsour.2019.05.055

Keywords

Lithium-sulfur batteries; Electrospun nanofibers; Polysulfide; PEDOT:PSS; PAN

Funding

  1. Department of Science and Technology, India [DST/TMD/MES/2k17/73]

Ask authors/readers for more resources

The drive for commercializing high energy density lithium-sulfur batteries is leading to the development of various material architectures for suppressing the notorious shuttle effect of intermediate polysulfides and improve cycle life. Inspired by the structural features of plant roots protecting soil erosion, herein, we report a novel strategy to use poly(3,4-ethylenedioxythiophene):polystyrene sulfonate-sulfur@polyacrylonitrile electrospun nanofibers as flexible additives in the cathode of lithium-sulfur batteries to trap lithium polysulfides and suppress their dissolution into liquid electrolyte. The nanofibers consist of in-situ grown sulfur particles, embedded inside porous polyacrylonitrile shell and coated with poly(3,4-ethylenedioxythiophene):polystyrene sulfonate. The electrochemical performance of lithium-sulfur batteries using poly(3,4-ethylenedioxythiophene):polystyrene sulfonatesulfur@polyacrylonitrile nanofiber incorporated sulfur hybrid cathode shows a significantly better cycle stability and excellent rate capability compared to the bare sulfur cathode owing to the adsorption effect of the nanofibers. Even after 500 cycles at a high rate of 0.5 C, the capacity retention is approximately 41% of the initial capacity with average columbic efficiency above 94%. This work offers a novel approach to fabricate viable lithium-sulfur batteries and possibly pave the way to further develop innovative flexible additives for practically applicable lithiumsulfur batteries.

Authors

I am an author on this paper
Click your name to claim this paper and add it to your profile.

Reviews

Primary Rating

4.8
Not enough ratings

Secondary Ratings

Novelty
-
Significance
-
Scientific rigor
-
Rate this paper

Recommended

Article Chemistry, Analytical

Excellent electrochemical performance of Lithium-sulfur batteries via self-standing cathode from interwoven ?-Fe2O3 integrated carbon nanofiber networks

Avinash Raulo, Amit Gupta, Rajiv Srivastava, Bhanu Nandan

Summary: This study investigates the impact of a flexible self-standing cathode on improving the electrochemical performance of Lithium-sulfur batteries by enhancing electrolyte penetration and reducing sulfur dissolution and diffusion, resulting in a high capacity retention rate during cycling.

JOURNAL OF ELECTROANALYTICAL CHEMISTRY (2021)

Article Biochemistry & Molecular Biology

The Localization Behavior of Different CNTs in PC/SAN Blends Containing a Reactive Component

Maren Gueltner, Regine Boldt, Petr Formanek, Dieter Fischer, Frank Simon, Petra Poetschke

Summary: In this study, PC, SAN, MWCNTs/SWCNTs, and RC were melt compounded in a microcompounder. The localization of MWCNTs was found to be influenced by adjusting the RC concentration, while the localization of SWCNTs in PC/SAN-RC blends depended on their types.

MOLECULES (2021)

Article Nanoscience & Nanotechnology

Designing Supertough and Ultrastretchable Liquid Metal-Embedded Natural Rubber Composites for Soft-Matter Engineering

Shib Shankar Banerjee, Subhradeep Mandal, Injamamul Arief, Rama Kanta Layek, Anik Kumar Ghosh, Ke Yang, Jayant Kumar, Petr Formanek, Andreas Fery, Gert Heinrich, Amit Das

Summary: This study presents a novel method to prepare liquid metal-embedded soft elastomeric composites, showing significant improvements in mechanical properties and enhanced thermal and dielectric performance.

ACS APPLIED MATERIALS & INTERFACES (2021)

Article Materials Science, Biomaterials

Podosome-Driven Defect Development in Lamellar Bone under the Conditions of Senile Osteoporosis Observed at the Nanometer Scale

Paul Simon, Wolfgang Pompe, Manfred Bobeth, Hartmut Worch, Ruediger Kniep, Petr Formanek, Anne Hild, Sabine Wenisch, Elena Sturm

Summary: The degradation mechanism of human trabecular bone from the central part of the femoral head in a patient with senile osteoporosis was investigated. Severe damages were observed due to osteoclasts and podosome activity, resulting in the disintegration of bone structure. Podosomes create pit marks and holes on the bone surface, leading to the formation of microcracks and a brittle, porous bone structure.

ACS BIOMATERIALS SCIENCE & ENGINEERING (2021)

Article Chemistry, Multidisciplinary

Enhanced Photoluminescence of Gold Nanoparticle-Quantum Dot Hybrids Confined in Hairy Polymer Nanofibers

Sajan Singh, Avinash Raulo, Ajeet Singh, Mona Mittal, Andriy Horechyy, Rene Huebner, Petr Formanek, Rajiv K. Srivastava, Sameer Sapra, Andreas Fery, Bhanu Nandan

Summary: In this study, the influence of gold nanoparticles (AuNPs) on the photoluminescence behavior of cadmium selenide (CdSe) quantum dots (QDs) confined in spatially separated soft nanoscale cylindrical domains was investigated. It was found that the presence of AuNPs can manipulate the photoluminescence intensity of CdSe QDs, with low fraction of AuNPs leading to enhancement and further increase causing quenching of the intensity. The interaction between energy transfer mechanisms and FRET/electron transfer processes between QDs and AuNPs could explain the observed phenomena.

CHEMNANOMAT (2021)

Article Nanoscience & Nanotechnology

Flexible Pressure Sensors Based on the Controlled Buckling of Doped Semiconducting Polymer Nanopillars

Takuya Tsuda, Soosang Chae, Mahmoud Al-Hussein, Petr Formanek, Andreas Fery

Summary: A piezoresistive pressure sensor based on doped semiconducting polymer nanopillars with controlled elastic buckling has been developed, allowing for the detection of pressure over a wide range with good sensitivity, reproducibility, and cycling stability.

ACS APPLIED MATERIALS & INTERFACES (2021)

Article Energy & Fuels

A high performance flexible and robust printed thermoelectric generator based on hybridized Te nanowires with PEDOT:PSS

George Karalis, Lazaros Tzounis, Christos K. Mytafides, Kyriaki Tsirka, Petr Formanek, Minas Stylianakis, Emmanuel Kymakis, Alkiviadis S. Paipetis

Summary: In this work, a water-based Te nanowires synthesis method and formulation of hybrid thermoelectric inks using PEDOT:PSS were demonstrated for creating high performance and flexible printed thermoelectric generators. Characterization techniques confirmed the high crystallinity of the Te nanowires, microstructural features, and carrier density and mobility of the materials. A flexible TEG with promising power output was fabricated, showcasing the potential for large-scale production and thermal energy harvesting using printed TEG devices.

APPLIED ENERGY (2021)

Article Chemistry, Physical

Feedback-Induced and Oscillating pH Regulation of a Binary Enzyme-Polymersomes System

Xueyi Wang, Silvia Moreno, Susanne Boye, Ping Wen, Kehu Zhang, Petr Formanek, Albena Lederer, Brigitte Voit, Dietmar Appelhans

Summary: The study developed an artificial organelles system with stimuli-triggered regulation ability, achieving pH regulation by triggering out-of-equilibrium state with chemical fuels, providing a new approach for constructing artificial eukaryotic cell biomimetics.

CHEMISTRY OF MATERIALS (2021)

Article Chemistry, Physical

Metal oxide heterostructure decorated carbon nanofiber as a novel redox catalyst for high performance Lithium-Sulfur batteries

Avinash Raulo, Sajan Singh, Amit Gupta, Rajiv Srivastava, Bhanu Nandan

Summary: A heterostructure composed of CoFe2O4 and SnO2 decorated on a carbon nanofiber framework is reported as a sulfur redox catalyst in lithium-sulfur batteries, which shows efficient lithium polysulfide entrapment and conversion, providing excellent cyclability and performance even at high sulfur loadings.

APPLIED SURFACE SCIENCE (2021)

Article Polymer Science

Ensuring patient safety by rational choice of color masterbatch for medical device applications-A case study investigating the properties of an ABS/SAN blend colored by different masterbatches based on styrenic polymers

Bjoern Guenther, Thomas Kremser, Markus Susoff, Petr Formanek, Andreas Fery, Sven Wiessner

Summary: This study investigated the influence of masterbatches with different carrier resins on the impact resistance and morphology of an ABS/SAN blend. It found that masterbatches based on PS led to immiscibility, while those based on ABS and SAN showed no significant impact. Theoretical calculations were in good accordance with experimental results, suggesting the potential for predicting suitable masterbatch carriers based on solubility calculations between blend partners.

JOURNAL OF APPLIED POLYMER SCIENCE (2022)

Article Nanoscience & Nanotechnology

Distribution of Carbon Nanotubes in Polycarbonate-Based Blends for Electromagnetic Interference Shielding

Kumari Sushmita, Petr Formanek, Beate Krause, Petra Poetschke, Suryasarathi Bose

Summary: This study explores the impact of functionalization and distribution of carbon nanotubes (CNTs) in polymer matrices or blends on the electromagnetic interference (EMI) shielding performance of nanocomposites. It is found that despite a decrease in electrical conductivity, ball-milled CNTs may not necessarily lead to a drastic decrease in shielding effectiveness. In addition to the compartmentalization of CNTs, the state, dispersion, and distribution of CNTs also play a significant role in determining the final properties of the composites.

ACS APPLIED NANO MATERIALS (2022)

Article Materials Science, Multidisciplinary

High Yield Synthesis of Water-Processable Donor:Acceptor Janus Nanoparticles with Tuned Internal Morphology and Highly Efficient Charge Separation/Transfer

Yixuan Du, Yue Li, Olha Aftenieva, Takuya Tsuda, Petr Formanek, Tobias A. F. Koenig, Alla Synytska

Summary: This paper reports for the first time the high-yield synthesis of water-processable donor-acceptor Janus nanoparticles (JNP) and demonstrates their high potential for optoelectronic applications. The JNPs show easily controlled Janus ratios and excellent quality, as confirmed by energy-filtered transmission electron microscopy. Compared to conventional donor-acceptor nanoparticles, the JNPs exhibit improved charge separation and transfer properties, as characterized by both steady-state and transient photoluminescence spectroscopy. The Janus character of the particles enables the combination of two materials into one composite and allows for the programming of structure morphology. Lastly, the JNP-based photovoltaic cells demonstrate outstanding performance with a 53% improvement in efficiency.

ADVANCED OPTICAL MATERIALS (2022)

Article Polymer Science

Amphiphilic tetra-PCL-b-PEG star block copolymers using benzoxazinone-based linking groups

Carolin Bunk, Hartmut Komber, Michael Lang, Nora Fribiczer, Martin Geisler, Petr Formanek, Lothar Jakisch, Sebastian Seiffert, Brigitte Voit, Frank Boehme

Summary: In this study, two well-defined amphiphilic tetra-arm star block copolymers were prepared by a hetero-complementary linking reaction. The behavior of the two copolymers was studied in water, and it was found that spherical micelles formed at elevated temperatures for the copolymer with longer PEG arms. However, the copolymer with shorter PEG arms formed cloudy suspensions in water.

POLYMER CHEMISTRY (2023)

Article Chemistry, Multidisciplinary

Cotton cloth templated in situ encapsulation of sulfur into carbon fibers for lithium-sulfur batteries

Avinash Raulo, Amit Gupta, Rajiv Srivastava, Bhanu Nandan

Summary: An in situ encapsulation strategy for embedding sulfur within carbon fibers was developed using waste cotton cloth as a fiber template. The S@C fibers showed promising electrochemical performance as a cathode material for a lithium sulfur battery, with a high sulfur content of around 71%. The S@C fibers have potential to be used as cathode materials for other sulfur-based batteries.

CHEMICAL COMMUNICATIONS (2021)

Article Chemistry, Physical

Development of a tubular direct carbon solid oxide fuel cell stack based on lanthanum gallate electrolyte

Tianyu Chen, Zhibin Lu, Guangjin Zeng, Yongmin Xie, Jie Xiao, Zhifeng Xu

Summary: The study introduces a high-performance LSGM electrolyte-supported tubular DC-SOFC stack for portable applications, which shows great potential in developing into high-performing, efficient, and environmentally friendly portable power sources for distributed applications.

JOURNAL OF POWER SOURCES (2024)

Article Chemistry, Physical

Construction of ultrastable and high-rate performance zinc anode with three-dimensional porous structure and Schottky contact

Wenbin Tong, Yili Chen, Shijie Gong, Shaokun Zhu, Jie Tian, Jiaqian Qin, Wenyong Chen, Shuanghong Chen

Summary: In this study, a three-dimensional porous NiO interface layer with enhanced anode dynamics is fabricated, forming a Schottky contact with the zinc substrate, allowing rapid and uniform zinc plating both inside and below the interface layer. The resulting NiO@Zn exhibits exceptional stability and high capacity retention.

JOURNAL OF POWER SOURCES (2024)

Article Chemistry, Physical

Flexible low-temperature zinc ion supercapacitor based on gel electrolyte with α-MnO2@rGO electrode

Yafeng Bai, Kaidi Li, Liying Wang, Yang Gao, Xuesong Li, Xijia Yang, Wei Lu

Summary: In this study, a flexible zinc ion supercapacitor with gel electrolytes, porous alpha-MnO2@reduced graphene oxide cathode, and activated carbon/carbon cloth anode was developed. The device exhibits excellent electrochemical performance and stability, even at low temperatures, with a high cycle retention rate after 5000 cycles.

JOURNAL OF POWER SOURCES (2024)

Article Chemistry, Physical

Examining the effects of silicon based additives on the long-term cycling capabilities of cylindrical cells

Anmol Jnawali, Matt D. R. Kok, Francesco Iacoviello, Daniel J. L. Brett, Paul R. Shearing

Summary: This article presents the results of a systematic study on the electrochemical performance and mechanical changes in two types of commercial batteries with different anode chemistry. The study reveals that the swelling of anode layers in batteries with silicon-based components causes deformations in the jelly roll structure, but the presence of a small percentage of silicon does not significantly impact the cycling performance of the cells within the relevant state-of-health range for electric vehicles (EVs). The research suggests that there is room for improving the cell capacities by increasing the silicon loading in composite anodes to meet the increasing demands on EVs.

JOURNAL OF POWER SOURCES (2024)

Article Chemistry, Physical

Lithium disilicate as an alternative silicate battery material. A theoretical study

Yohandys A. Zulueta, My Phuong Pham-Ho, Minh Tho Nguyen

Summary: Advanced atomistic simulations were used to study ion transport in the Na- and K-doped lithium disilicate Li2Si2O5. The results showed that Na and K doping significantly enhanced Li ion diffusion and conduction in the material.

JOURNAL OF POWER SOURCES (2024)

Article Chemistry, Physical

Novel BaO-decorated carbon-tolerant Ni-YSZ anode fabricated by an efficient phase inversion-impregnation approach

Zongying Han, Hui Dong, Yanru Yang, Hao Yu, Zhibin Yang

Summary: An efficient phase inversion-impregnation approach is developed to fabricate BaO-decorated Ni8 mol% YSZ anode-supported tubular solid oxide fuel cells (SOFCs) with anti-coking properties. BaO nanoislands are successfully introduced inside the Ni-YSZ anode, leading to higher peak power densities and improved stability in methane fuel. Density functional theory calculations suggest that the loading of BaO nanoislands facilitates carbon elimination by capturing and dissociating H2O molecules to generate OH.

JOURNAL OF POWER SOURCES (2024)

Article Chemistry, Physical

Safe and stable Li-CO2 battery with metal-organic framework derived cathode composite and solid electrolyte

Suresh Mamidi, Dan Na, Baeksang Yoon, Henu Sharma, Anil D. Pathak, Kisor Kumar Sahu, Dae Young Lee, Cheul-Ro Lee, Inseok Seo

Summary: Li-CO2 batteries, which utilize CO2 and have a high energy density, are hindered in practical applications due to slow kinetics and safety hazards. This study introduces a stable and highly conductive ceramic-based solid electrolyte and a metal-organic framework catalyst to improve the safety and performance of Li-CO2 batteries. The optimized Li-CO2 cell shows outstanding specific capacity and cycle life, and the post-cycling analysis reveals the degradation mechanism of the electrodes. First-principles calculations based on density functional theory are also performed to understand the interactions between the catalyst and the host electrode. This research demonstrates the potential of MOF cathode catalyst for stable operation in Li-CO2 batteries.

JOURNAL OF POWER SOURCES (2024)

Article Chemistry, Physical

Synergistic effect of platinum single atoms and nanoclusters for preferential oxidation of carbon monoxide in hydrogen-rich stream

Ganghua Xiang, Zhihuan Qiu, Huilong Fei, Zhigang Liu, Shuangfeng Yin, Yuen Wu

Summary: In this study, a CeFeOx-supported Pt single atoms and subnanometric clusters catalyst was developed, which exhibits enhanced catalytic activity and stability for the preferential oxidation of CO in H2-rich stream through synergistic effect.

JOURNAL OF POWER SOURCES (2024)

Article Chemistry, Physical

Towards understanding the functional mechanism and synergistic effects of LiMn2O4-LiNi0.5Mn0.3Co0.2O2 blended positive electrodes for Lithium-ion batteries

Dimitrios Chatzogiannakis, Marcus Fehse, Maria Angeles Cabanero, Natalia Romano, Ashley Black, Damien Saurel, M. Rosa Palacin, Montse Casas-Cabanas

Summary: By coupling electrochemical testing to operando synchrotron based X-ray absorption and powder diffraction experiments, blended positive electrodes consisting of LiMn2O4 spinel (LMO) and layered LiNi0.5Mn0.3Co0.2O2 (NMC) were studied to understand their redox mechanism. It was found that blending NMC with LMO can enhance energy density at high rates, with the blend containing 25% LMO showing the best performance. Testing with a special electrochemical setup revealed that the effective current load on each blend component can vary significantly from the nominal rate and also changes with SoC. Operando studies allowed monitoring of the oxidation state evolution and changes in crystal structure, in line with the expected behavior of individual components considering their electrochemical current loads.

JOURNAL OF POWER SOURCES (2024)

Article Chemistry, Physical

We may be underestimating the power capabilities of lithium-ion capacitors

Chiara Cementon, Daniel Dewar, Thrinathreddy Ramireddy, Michael Brennan, Alexey M. Glushenkov

Summary: This Perspective discusses the specific power and power density of lithium-ion capacitors, highlighting the fact that their power characteristics are often underestimated. Through analysis, it is found that lithium-ion capacitors can usually achieve power densities superior to electrochemical supercapacitors, making them excellent alternatives to supercapacitors.

JOURNAL OF POWER SOURCES (2024)

Article Chemistry, Physical

Highly concentrated solvation structure for reversible high-voltage lithium-ion battery at low temperature

Weihao Wang, Hao Yu, Li Ma, Youquan Zhang, Yuejiao Chen, Libao Chen, Guichao Kuang, Liangjun Zhou, Weifeng Wei

Summary: This study achieved an improved electrolyte with excellent low-temperature and high-voltage performance by regulating the Li+ solvation structure and highly concentrating it. The electrolyte exhibited outstanding oxidation potential and high ionic conductivity under low temperature and high voltage conditions, providing a promising approach for the practical application of high-voltage LIBs.

JOURNAL OF POWER SOURCES (2024)

Article Chemistry, Physical

Evaluation of mitigation of capacity decay in vanadium redox flow batteries for cation- and anion-exchange membrane by validated mathematical modelling

Martin Bures, Dan Gotz, Jiri Charvat, Milos Svoboda, Jaromir Pocedic, Juraj Kosek, Alexandr Zubov, Petr Mazur

Summary: Vanadium redox flow battery is a promising energy storage solution with long-term durability, non-flammability, and high overall efficiency. Researchers have developed a mathematical model to simulate the charge-discharge cycling of the battery, and found that hydraulic connection of electrolyte tanks is the most effective strategy to reduce capacity losses, achieving a 69% reduction.

JOURNAL OF POWER SOURCES (2024)

Article Chemistry, Physical

Operando analysis of the positive active mass of lead batteries by neutron diffraction

M. Rodriguez-Gomez, J. Campo, A. Orera, F. de La Fuente, J. Valenciano, H. Fricke, D. S. Hussey, Y. Chen, D. Yu, K. An, A. Larrea

Summary: In this study, we analysed the operando performance of industrial lead cells using neutron diffraction experiments. The experiments revealed the evolution of different phases in the positive electrode, showed significant inhomogeneity of phase distribution inside the electrode, and estimated the energy efficiency of the cells.

JOURNAL OF POWER SOURCES (2024)

Article Chemistry, Physical

Double Conductive Ni-pads for a kW-class micro-tubular solid oxide fuel cell stack

Jiawei Liu, Chenpeng Wang, Yue Yao, Hao Ye, Yinglong Liu, Yingli Liu, Xiaoru Xu, Zhicong Chen, Huazheng Yang, Gang Wu, Libin Lei, Chao Wang, Bo Liang

Summary: The study focuses on utilizing double conductive Ni-pads as anode collectors in micro-tubular solid oxide fuel cells. The simulation results show excellent performance and stability of DCNPs, and also highlight the potential applications in various fields.

JOURNAL OF POWER SOURCES (2024)

Article Chemistry, Physical

Ion transport regulation of polyimide separator for safe and durable Li-metal battery

Yang Wang, Kangjie Zhou, Lang Cui, Jiabing Mei, Shengnan Li, Le Li, Wei Fan, Longsheng Zhang, Tianxi Liu

Summary: This study presents a polyimide sandwiched separator (s-PIF) for improving the cycling stability of Li-metal batteries. The s-PIF separator exhibits superior mechanical property, electrolyte adsorption/retention and ion conductivity, and enables dendrite-free Li plating/stripping process.

JOURNAL OF POWER SOURCES (2024)